Robert Huggins
Professor of Materials Science and Engineering, Emeritus
Bio
Professor Huggins joined Stanford as Assistant Professor in 1954, was promoted to Associate Professor in 1958, and to Professor in 1962.
His research activities have included studies of imperfections in crystals, solid-state reaction kinetics, ferromagnetism, mechanical behavior of solids, crystal growth, and a wide variety of topics in physical metallurgy, ceramics, solid state chemistry and electrochemistry. Primary attention has recently been focused on the development of understanding of solid state ionic phenomena involving solid electrolytes and mixed ionic-electronic conducting materials containing atomic or ionic species such as lithium, sodium or oxygen with unusually high mobility, as well as their use in novel battery and fuel cell systems, electrochromic optical devices, sensors, and in enhanced heterogeneous catalysis. He was also involved in the development of the understanding of the key role played by the phase composition and oxygen stoichiometry in determining the properties of high temperature oxide superconductors.
Topics of particular recent interest have been related to energy conversion and storage, including hydrogen transport and hydride formation in metals, alloys and intermetallic compounds, and various aspects of materials and phenomena related to advanced lithium batteries.
He has over 400 professional publications, including two books; "Advanced Batteries", published by Springer in 2009, and "Energy Storage", published by Springer in 2010.
Academic Appointments
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Professor Emeritus, Materials Science and Engineering
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Affiliate, Precourt Institute for Energy
Administrative Appointments
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Director, Center for Materials Research, Stanford (1961 - 1977)
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Director for Materials Sciences, Advanced Research Projects Agency (ARPA) (1968 - 1970)
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Chief Scientist, Center for Solar Energy and Hydrogen Research, Ulm, Germany (1991 - 1995)
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Honorary Professor, University of Ulm, Germany (1994 - Present)
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Honorary Professor, University of Kiel, Germany (2000 - Present)
Honors & Awards
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Hardy Gold Medal, AIME (1957)
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Senior Postdoctoral Fellowship, National Science Foundation (1965-1966)
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Senior United States Scientist Award, Alexander von Humboldt Foundation (1977)
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23rd Annual Vincent Bendix Award, American Society for Engineering Education (1978)
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Research Award, Electrochemical Society's Battery Division (1982)
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Research Award, International Battery Association (2001)
Professional Education
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BA, Amherst College, Physics (1950)
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ScD, MIT, Metallurgy (1954)
All Publications
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Full open-framework batteries for stationary energy storage
NATURE COMMUNICATIONS
2014; 5
View details for DOI 10.1038/ncomms4007
View details for Web of Science ID 000331082900006
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Full open-framework batteries for stationary energy storage.
Nature communications
2014; 5: 3007-?
Abstract
New types of energy storage are needed in conjunction with the deployment of renewable energy sources and their integration with the electrical grid. We have recently introduced a family of cathodes involving the reversible insertion of cations into materials with the Prussian Blue open-framework crystal structure. Here we report a newly developed manganese hexacyanomanganate open-framework anode that has the same crystal structure. By combining it with the previously reported copper hexacyanoferrate cathode we demonstrate a safe, fast, inexpensive, long-cycle life aqueous electrolyte battery, which involves the insertion of sodium ions. This high rate, high efficiency cell shows a 96.7% round trip energy efficiency when cycled at a 5C rate and an 84.2% energy efficiency at a 50C rate. There is no measurable capacity loss after 1,000 deep-discharge cycles. Bulk quantities of the electrode materials can be produced by a room temperature chemical synthesis from earth-abundant precursors.
View details for DOI 10.1038/ncomms4007
View details for PubMedID 24389854
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Highly Reversible Open Framework Nanoscale Electrodes for Divalent Ion Batteries
NANO LETTERS
2013; 13 (11): 5748-5752
Abstract
The reversible insertion of monovalent ions such as lithium into electrode materials has enabled the development of rechargeable batteries with high energy density. Reversible insertion of divalent ions such as magnesium would allow the creation of new battery chemistries that are potentially safer and cheaper than lithium-based batteries. Here we report that nanomaterials in the Prussian Blue family of open framework materials, such as nickel hexacyanoferrate, allow for the reversible insertion of aqueous alkaline earth divalent ions, including Mg(2+), Ca(2+), Sr(2+), and Ba(2+). We show unprecedented long cycle life and high rate performance for divalent ion insertion. Our results represent a step forward and pave the way for future development in divalent batteries.
View details for DOI 10.1021/nl403669a
View details for Web of Science ID 000327111700118
View details for PubMedID 24147617
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Oxidation processes on conducting carbon additives for lithium-ion batteries
JOURNAL OF APPLIED ELECTROCHEMISTRY
2013; 43 (1): 1-7
View details for DOI 10.1007/s10800-012-0499-9
View details for Web of Science ID 000312209600001
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The Ferrocyanide/Stabilized Carbon System, a New Class of High Rate, Long Cycle Life, Aqueous Electrolyte Batteries
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
2013; 160 (5): A3020-A3025
View details for DOI 10.1149/2.003305jes
View details for Web of Science ID 000320202800005
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Do You Really Want an Unsafe Battery?
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
2013; 160 (5): A3001-A3005
View details for DOI 10.1149/2.001305jes
View details for Web of Science ID 000320202800003
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Cotton-templated hierarchical porous structures for high power lithium rechargeable batteries
JOURNAL OF MATERIALS CHEMISTRY A
2013; 1 (17): 5320-5325
View details for DOI 10.1039/c3ta00192j
View details for Web of Science ID 000316968000019
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A high-rate and long cycle life aqueous electrolyte battery for grid-scale energy storage
NATURE COMMUNICATIONS
2012; 3
Abstract
New types of energy storage are needed in conjunction with the deployment of solar, wind and other volatile renewable energy sources and their integration with the electric grid. No existing energy storage technology can economically provide the power, cycle life and energy efficiency needed to respond to the costly short-term transients that arise from renewables and other aspects of grid operation. Here we demonstrate a new type of safe, fast, inexpensive, long-life aqueous electrolyte battery, which relies on the insertion of potassium ions into a copper hexacyanoferrate cathode and a novel activated carbon/polypyrrole hybrid anode. The cathode reacts rapidly with very little hysteresis. The hybrid anode uses an electrochemically active additive to tune its potential. This high-rate, high-efficiency cell has a 95% round-trip energy efficiency when cycled at a 5C rate, and a 79% energy efficiency at 50C. It also has zero-capacity loss after 1,000 deep-discharge cycles.
View details for DOI 10.1038/ncomms2139
View details for Web of Science ID 000313514100059
View details for PubMedID 23093186
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Tunable Reaction Potentials in Open Framework Nanoparticle Battery Electrodes for Grid-Scale Energy Storage
ACS NANO
2012; 6 (2): 1688-1694
Abstract
The electrical energy grid has a growing need for energy storage to address short-term transients, frequency regulation, and load leveling. Though electrochemical energy storage devices such as batteries offer an attractive solution, current commercial battery technology cannot provide adequate power, and cycle life, and energy efficiency at a sufficiently low cost. Copper hexacyanoferrate and nickel hexacyanoferrate, two open framework materials with the Prussian Blue structure, were recently shown to offer ultralong cycle life and high-rate performance when operated as battery electrodes in safe, inexpensive aqueous sodium ion and potassium ion electrolytes. In this report, we demonstrate that the reaction potential of copper-nickel alloy hexacyanoferrate nanoparticles may be tuned by controlling the ratio of copper to nickel in these materials. X-ray diffraction, TEM energy dispersive X-ray spectroscopy, and galvanostatic electrochemical cycling of copper-nickel hexacyanoferrate reveal that copper and nickel form a fully miscible solution at particular sites in the framework without perturbing the structure. This allows copper-nickel hexacyanoferrate to reversibly intercalate sodium and potassium ions for over 2000 cycles with capacity retentions of 100% and 91%, respectively. The ability to precisely tune the reaction potential of copper-nickel hexacyanoferrate without sacrificing cycle life will allow the development of full cells that utilize the entire electrochemical stability window of aqueous sodium and potassium ion electrolytes.
View details for DOI 10.1021/nn204666v
View details for Web of Science ID 000300757900079
View details for PubMedID 22283739
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The Effect of Insertion Species on Nanostructured Open Framework Hexacyanoferrate Battery Electrodes
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
2012; 159 (2): A98-A103
View details for DOI 10.1149/2.060202jes
View details for Web of Science ID 000298637500005
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Nickel Hexacyanoferrate Nanoparticle Electrodes For Aqueous Sodium and Potassium Ion Batteries
NANO LETTERS
2011; 11 (12): 5421-5425
Abstract
The electrical power grid faces a growing need for large-scale energy storage over a wide range of time scales due to costly short-term transients, frequency regulation, and load balancing. The durability, high power, energy efficiency, and low cost needed for grid-scale storage pose substantial challenges for conventional battery technology. (1, 2) Here, we demonstrate insertion/extraction of sodium and potassium ions in a low-strain nickel hexacyanoferrate electrode material for at least five thousand deep cycles at high current densities in inexpensive aqueous electrolytes. Its open-framework structure allows retention of 66% of the initial capacity even at a very high (41.7C) rate. At low current densities, its round trip energy efficiency reaches 99%. This low-cost material is readily synthesized in bulk quantities. The long cycle life, high power, good energy efficiency, safety, and inexpensive production method make nickel hexacyanoferrate an attractive candidate for use in large-scale batteries to support the electrical grid.
View details for DOI 10.1021/nl203193q
View details for Web of Science ID 000297950200055
View details for PubMedID 22043814
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Copper hexacyanoferrate battery electrodes with long cycle life and high power
NATURE COMMUNICATIONS
2011; 2
Abstract
Short-term transients, including those related to wind and solar sources, present challenges to the electrical grid. Stationary energy storage systems that can operate for many cycles, at high power, with high round-trip energy efficiency, and at low cost are required. Existing energy storage technologies cannot satisfy these requirements. Here we show that crystalline nanoparticles of copper hexacyanoferrate, which has an ultra-low strain open framework structure, can be operated as a battery electrode in inexpensive aqueous electrolytes. After 40,000 deep discharge cycles at a 17?C rate, 83% of the original capacity of copper hexacyanoferrate is retained. Even at a very high cycling rate of 83?C, two thirds of its maximum discharge capacity is observed. At modest current densities, round-trip energy efficiencies of 99% can be achieved. The low-cost, scalable, room-temperature co-precipitation synthesis and excellent electrode performance of copper hexacyanoferrate make it attractive for large-scale energy storage systems.
View details for DOI 10.1038/ncomms1563
View details for Web of Science ID 000297686500037
View details for PubMedID 22109524
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Electrochemical characterization of LiCoO2 as rechargeable electrode in aqueous LiNO3 electrolyte
ELSEVIER SCIENCE BV. 2011: 289-292
View details for DOI 10.1016/j.ssi.2010.05.043
View details for Web of Science ID 000292848800062
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Recent results on aqueous electrolyte cells
JOURNAL OF POWER SOURCES
2011; 196 (5): 2884-2888
View details for DOI 10.1016/j.jpowsour.2010.10.098
View details for Web of Science ID 000286705100064
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Synthesis of Nanoscale Lithium-Ion Battery Cathode Materials Using a Porous Polymer Precursor Method
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
2011; 158 (10): A1079-A1082
View details for DOI 10.1149/1.3611428
View details for Web of Science ID 000294063000003
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Synthesis and Electrochemical Performance of a Lithium Titanium Phosphate Anode for Aqueous Lithium-Ion Batteries
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
2011; 158 (3): A352-A355
View details for DOI 10.1149/1.3536619
View details for Web of Science ID 000286677900023
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Investigations of the Electrochemical Stability of Aqueous Electrolytes for Lithium Battery Applications
ELECTROCHEMICAL AND SOLID STATE LETTERS
2010; 13 (5): A59-A61
View details for DOI 10.1149/1.3329652
View details for Web of Science ID 000275660200002
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Impedance Analysis of Silicon Nanowire Lithium Ion Battery Anodes
JOURNAL OF PHYSICAL CHEMISTRY C
2009; 113 (26): 11390-11398
View details for DOI 10.1021/jp901594g
View details for Web of Science ID 000267324600033
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Structural and electrochemical study of the reaction of lithium with silicon nanowires
ELSEVIER SCIENCE BV. 2009: 34-39
View details for DOI 10.1016/j.jpowsour.2008.12.047
View details for Web of Science ID 000265317600007
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Electrochemical behavior of LiCoO2 as aqueous lithium-ion battery electrodes
ELECTROCHEMISTRY COMMUNICATIONS
2009; 11 (2): 247-249
View details for DOI 10.1016/j.elecom.2008.11.015
View details for Web of Science ID 000263455600003
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Spinel LiMn2O4 Nanorods as Lithium Ion Battery Cathodes
NANO LETTERS
2008; 8 (11): 3948-3952
Abstract
Spinel LiMn2O4 is a low-cost, environmentally friendly, and highly abundant material for Li-ion battery cathodes. Here, we report the hydrothermal synthesis of single-crystalline beta-MnO2 nanorods and their chemical conversion into free-standing single-crystalline LiMn2O4 nanorods using a simple solid-state reaction. The LiMn2O4 nanorods have an average diameter of 130 nm and length of 1.2 microm. Galvanostatic battery testing showed that LiMn2O4 nanorods have a high charge storage capacity at high power rates compared with commercially available powders. More than 85% of the initial charge storage capacity was maintained for over 100 cycles. The structural transformation studies showed that the Li ions intercalated into the cubic phase of the LiMn2O4 with a small change of lattice parameter, followed by the coexistence of two nearly identical cubic phases in the potential range of 3.5 to 4.3 V.
View details for DOI 10.1021/nl8024328
View details for Web of Science ID 000260888600070
View details for PubMedID 18826287
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High-performance lithium battery anodes using silicon nanowires
NATURE NANOTECHNOLOGY
2008; 3 (1): 31-35
Abstract
There is great interest in developing rechargeable lithium batteries with higher energy capacity and longer cycle life for applications in portable electronic devices, electric vehicles and implantable medical devices. Silicon is an attractive anode material for lithium batteries because it has a low discharge potential and the highest known theoretical charge capacity (4,200 mAh g(-1); ref. 2). Although this is more than ten times higher than existing graphite anodes and much larger than various nitride and oxide materials, silicon anodes have limited applications because silicon's volume changes by 400% upon insertion and extraction of lithium which results in pulverization and capacity fading. Here, we show that silicon nanowire battery electrodes circumvent these issues as they can accommodate large strain without pulverization, provide good electronic contact and conduction, and display short lithium insertion distances. We achieved the theoretical charge capacity for silicon anodes and maintained a discharge capacity close to 75% of this maximum, with little fading during cycling.
View details for DOI 10.1038/nnano.2007.411
View details for Web of Science ID 000252117000012
View details for PubMedID 18654447
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Nanowire Batteries for Next Generation Electronics
IEEE INTERNATIONAL ELECTRON DEVICES MEETING 2008, TECHNICAL DIGEST
2008: 175-178
View details for Web of Science ID 000265829300039
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Reaction of lithium with FeAsS, a quaternary system
IONICS
2007; 13 (3): 107-110
View details for DOI 10.1007/s11581-007-0084-0
View details for Web of Science ID 000248879000004
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Cause of the memory effect in "nickel" electrodes
ELSEVIER SCIENCE BV. 2007: 640-645
View details for DOI 10.1016/j.jpowsour.2006.10.031
View details for Web of Science ID 000245369100021
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Decrepitation Model For Capacity Loss During Cycling of Alloys in Rechargeable Electrochemical Systems
IONICS
2000; 6 (1-2): 57-63
View details for Web of Science ID 000208028400005
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ELECTROCHEMICAL STUDIES OF KINETIC-PROPERTIES OF TITANIUM-HYDROGEN AND VANADIUM-HYDROGEN SYSTEMS AT INTERMEDIATE TEMPERATURES USING MOLTEN-SALT TECHNIQUES
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
1995; 142 (7): 2196-2203
View details for Web of Science ID A1995RJ35500023
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AN ISOPERIBOLIC CALORIMETER TO STUDY ELECTROCHEMICAL INSERTION OF DEUTERIUM INTO PALLADIUM
FUSION TECHNOLOGY
1994; 25 (4): 487-501
View details for Web of Science ID A1994NT53700013
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PARTIAL OXIDATION OF METHANE CATALYZED BY YBA2CU3OX IN A SOLID-STATE ELECTROCHEMICAL REACTOR
CATALYSIS LETTERS
1994; 23 (3-4): 387-393
View details for Web of Science ID A1994MR93400019
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HIGH-TEMPERATURE OXYGEN-TRANSPORT AND ELECTROCHEMICAL-BEHAVIOR OF YBA2CU3OX
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
1993; 140 (7): 1990-2000
View details for Web of Science ID A1993LL84200036
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A NEW CLASS OF OXYGEN SELECTIVE CHEMICALLY DRIVEN NONPOROUS CERAMIC MEMBRANES .1. A-SITE DOPED PEROVSKITES
JOURNAL OF MEMBRANE SCIENCE
1992; 75 (1-2): 151-162
View details for Web of Science ID A1992KH24800013
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INVESTIGATION OF THERMODYNAMIC PROPERTIES OF THE TI-H SYSTEM USING MOLTEN-SALT ELECTROLYTES CONTAINING HYDRIDE IONS
JOURNAL OF ALLOYS AND COMPOUNDS
1992; 189 (2): 175-186
View details for Web of Science ID A1992JX62500009
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OXYGEN CHEMICAL DIFFUSION IN STRONTIUM DOPED LANTHANUM MANGANITES
SOLID STATE IONICS
1992; 57 (3-4): 327-337
View details for Web of Science ID A1992JU17000022
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MULTINARY ALLOY ELECTRODES FOR SOLID-STATE BATTERIES .1. A PHASE-DIAGRAM APPROACH FOR THE SELECTION AND STORAGE PROPERTIES DETERMINATION OF CANDIDATE ELECTRODE MATERIALS
JOURNAL OF POWER SOURCES
1992; 38 (3): 351-362
View details for Web of Science ID A1992HZ14400013
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MULTINARY ALLOY ELECTRODES FOR SOLID-STATE BATTERIES .2. A NEW LI-SI-MG ALLOY NEGATIVE ELECTRODE MATERIAL FOR USE IN HIGH-ENERGY DENSITY RECHARGEABLE LITHIUM CELLS
JOURNAL OF POWER SOURCES
1992; 38 (3): 363-372
View details for Web of Science ID A1992HZ14400014
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PHASE-BEHAVIOR AND CONDUCTIVITY OF LI2SIS3 COMPOSITION
SOLID STATE IONICS
1991; 46 (3-4): 237-242
View details for Web of Science ID A1991FY08500008
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ELECTROCATALYTIC CONVERSION OF CARBON-DIOXIDE TO METHANE AND OXYGEN WITH AN OXYGEN ION-CONDUCTING ELECTROLYTE
JOURNAL OF CATALYSIS
1991; 129 (1): 216-224
View details for Web of Science ID A1991FG05000024
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THERMODYNAMIC AND STRUCTURAL CONSIDERATIONS OF INSERTION REACTIONS IN LITHIUM VANADIUM BRONZE STRUCTURES
SOLID STATE IONICS
1991; 45 (3-4): 323-328
View details for Web of Science ID A1991FK94600018
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INTERMEDIATE TEMPERATURE WATER-VAPOR ELECTROLYSIS
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
1991; 16 (6): 373-378
View details for Web of Science ID A1991GB16700001
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MATERIALS CONSIDERATIONS RELATED TO SODIUM-BASED RECHARGEABLE CELLS FOR USE ABOVE ROOM-TEMPERATURE
SOLID STATE IONICS
1990; 42 (1-2): 109-115
View details for Web of Science ID A1990EF05100016
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MEASUREMENT OF THE CHEMICAL DIFFUSION-COEFFICIENT OF OXYGEN IN MIXED CONDUCTORS BY A SOLID-STATE ELECTROCHEMICAL METHOD
ELSEVIER SCIENCE BV. 1990: 535-538
View details for Web of Science ID A1990EE01800004
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RECENT RESULTS ON MIXED CONDUCTORS CONTAINING HYDROGEN OR DEUTERIUM
ELSEVIER SCIENCE BV. 1990: 519-524
View details for Web of Science ID A1990EE01800001
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2 FAST MIXED-CONDUCTOR SYSTEMS - DEUTERIUM AND HYDROGEN IN PALLADIUM - THERMAL MEASUREMENTS AND EXPERIMENTAL CONSIDERATIONS
PLENUM PUBL CORP. 1990: 219-227
View details for Web of Science ID A1990EP29900016
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QUATERNARY PHASE-RELATIONS NEAR YBA2CU3O6+X AT 850-DEGREES-C IN REDUCED OXYGEN PRESSURES
PHYSICA C-SUPERCONDUCTIVITY AND ITS APPLICATIONS
1990; 167 (5-6): 529-537
View details for Web of Science ID A1990DG14500011
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PREPARATION, STRUCTURES AND CONDUCTIVITIES OF LI2SIS3 PHASES
MATERIALS RESEARCH BULLETIN
1990; 25 (3): 381-389
View details for Web of Science ID A1990DC45600015
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HIGH-TEMPERATURE PHASE-EQUILIBRIA NEAR YBA2CU3O6+X
ELSEVIER SCIENCE BV. 1989: 883-884
View details for Web of Science ID A1989CG49000017
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OXYGEN ORDERING IN Y1BA2CU3O7-X
ELSEVIER SCIENCE BV. 1989: 548-549
View details for Web of Science ID A1989CG48900259
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THERMODYNAMIC RATIONALIZATION OF MOLTEN-SALT ELECTRODEPOSITION IN OXIDE-BASED SYSTEMS
JOURNAL OF MATERIALS RESEARCH
1989; 4 (6): 1495-1504
View details for Web of Science ID A1989AY51300029
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PREPARATION AND CONDUCTIVITY OF THE LAYERED STRUCTURE J-PHASE OF ANHYDROUS CRYSTALLINE LI2ZR(PO4)2
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
1989; 136 (9): 2529-2532
View details for Web of Science ID A1989AP84900016
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OXYGEN ORDERING, PHASE-SEPARATION AND THE 60-K AND 90-K PLATEAUS IN YBA2CU3OX
NATURE
1989; 340 (6235): 619-621
View details for Web of Science ID A1989AM35700049
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HYDROGEN-TRANSPARENT METAL-SURFACES PRODUCED BY USE OF MOLTEN-SALTS WITH VERY LOW OXYGEN AND WATER ACTIVITIES
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
1989; 136 (8): 2234-2238
View details for Web of Science ID A1989AK24000018
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SYNTHESIS AND LITHIUM CONDUCTIVITIES OF LI2SIS3 AND LI4SIS4
MATERIALS RESEARCH BULLETIN
1989; 24 (7): 889-897
View details for Web of Science ID A1989AL85100016
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MATERIALS SCIENCE PRINCIPLES RELATED TO ALLOYS OF POTENTIAL USE IN RECHARGEABLE LITHIUM CELLS
JOURNAL OF POWER SOURCES
1989; 26 (1-2): 109-120
View details for Web of Science ID A1989AD34700013
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DEMONSTRATION OF A NOVEL COMPOSITE SOLID LIQUID SOLID ELECTROLYTE CONFIGURATION FOR HYDROGEN-RELATED APPLICATIONS
ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE NEUE FOLGE
1989; 164: 1533-1538
View details for Web of Science ID A1989CB56800065
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HYDROGEN-CONDUCTING ELECTROLYTE CONFIGURATIONS
SOLID STATE IONICS
1988; 28: 1084-1088
View details for Web of Science ID A1988R527600034
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CONTROLLED ELECTROLYTE ENVIRONMENTS AND THEIR USE FOR STUDYING AND MODIFYING MATERIALS PROPERTIES - POTENTIALS FOR EMPLOYMENT IN PRACTICAL DEVICES
SOLID STATE IONICS
1988; 28: 1078-1083
View details for Web of Science ID A1988R527600033
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PHASE-BEHAVIOR IN THE LI-AL-O-H SYSTEM AT INTERMEDIATE TEMPERATURES
SOLID STATE IONICS
1988; 28: 611-616
View details for Web of Science ID A1988R376300111
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THERMODYNAMIC PROPERTIES OF TITANIUM-NICKEL HYDRIDES
SOLID STATE IONICS
1988; 28: 873-878
View details for Web of Science ID A1988R376300162
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NOVEL ELECTROCHEMICAL HYDROGEN SENSORS FOR USE AT ELEVATED-TEMPERATURES
SOLID STATE IONICS
1988; 28: 1660-1663
View details for Web of Science ID A1988R527600136
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DC CONDUCTIVITY STUDIES ON LI5ALO4 AT INTERMEDIATE TEMPERATURES AND ITS POSSIBLE APPLICATION FOR THE ELECTROLYSIS OF WATER
SOLID STATE IONICS
1988; 28: 656-659
View details for Web of Science ID A1988R376300120
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STUDIES OF SUPERCONDUCTING OXIDES WITH A SOLID-STATE IONIC TECHNIQUE
PHYSICA C-SUPERCONDUCTIVITY AND ITS APPLICATIONS
1988; 153: 590-593
View details for Web of Science ID A1988P410000242
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POLYPHASE ALLOYS AS RECHARGEABLE ELECTRODES IN ADVANCED BATTERY SYSTEMS
JOURNAL OF POWER SOURCES
1988; 22 (3-4): 341-350
View details for Web of Science ID A1988N176300016
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LITHIUM INSERTION IN SEVERAL MOLYBDENUM(IV) OXIDE PHASES AT ROOM-TEMPERATURE
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
1988; 135 (2): 408-412
View details for Web of Science ID A1988M212300029
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IMPORTANCE OF ELECTRODE ZIRCONIA INTERFACE MORPHOLOGY IN HIGH-TEMPERATURE SOLID ELECTROLYTE CELLS
JOURNAL OF APPLIED ELECTROCHEMISTRY
1987; 17 (4): 800-806
View details for Web of Science ID A1987J189200018
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THERMODYNAMIC CHARACTERIZATION OF METAL HYDROGEN SYSTEMS BY ASSESSMENT OF PHASE-DIAGRAMS AND ELECTROCHEMICAL MEASUREMENTS
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
1987; 12 (2): 81-88
View details for Web of Science ID A1987F875300004
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INVESTIGATIONS OF BINARY LITHIUM-ZINC, LITHIUM-CADMIUM AND LITHIUM-LEAD ALLOYS AS NEGATIVE ELECTRODES IN ORGANIC SOLVENT-BASED ELECTROLYTE
SOLID STATE IONICS
1986; 20 (3): 185-189
View details for Web of Science ID A1986C416400002
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BEHAVIOR OF SOME BINARY LITHIUM ALLOYS AS NEGATIVE ELECTRODES IN ORGANIC SOLVENT-BASED ELECTROLYTES
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
1986; 133 (3): 457-460
View details for Web of Science ID A1986A435800001
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STABILITY OF ALKALI ION-CONDUCTING SOLID AND LIQUID ELECTROLYTES - THERMODYNAMIC ASPECTS
SOLID STATE IONICS
1986; 18-9: 1110-1114
View details for Web of Science ID A1986A161200094
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THE THERMODYNAMICS AND KINETICS OF THE GAMMA-LITHIUM VANADIUM BRONZE STRUCTURE
SOLID STATE IONICS
1986; 18-9: 828-832
View details for Web of Science ID A1986A161200047
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PROCEEDINGS OF THE 5TH INTERNATIONAL-CONFERENCE-ON-SOLID-STATE-IONICS, LAKE-TAHOE, CA, USA, AUGUST 18-24, 1985 .2. PREFACE
SOLID STATE IONICS
1986; 18-9: R9-R9
View details for Web of Science ID A1986A161200001
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THE ELECTROCHEMICAL INSERTION OF LITHIUM INTO BLEACHED POTASSIUM HEXATUNGSTATE THIN-FILMS - A NEW ELECTROCHEMICAL MATERIAL
SOLID STATE IONICS
1986; 18-9: 592-596
View details for Web of Science ID A1986A161100102
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RAPID ANISOTROPIC DIFFUSION OF LITHIUM IN ELECTROCHROMIC THIN-FILMS BASED ON THE HEXAGONAL TUNGSTEN BRONZE STRUCTURE
SOLID STATE IONICS
1985; 17 (4): 313-318
View details for Web of Science ID A1985AWZ1300006
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ELECTROCHEMICAL INVESTIGATION OF HYDROGEN STORAGE IN METAL-HYDRIDES
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
1985; 132 (1): 52-56
View details for Web of Science ID A1985TZ49400010
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PREPARATION OF HEXAGONAL POTASSIUM TUNGSTEN BRONZE THIN-FILMS BY THERMAL VACUUM EVAPORATION
MATERIALS RESEARCH BULLETIN
1985; 20 (11): 1265-1271
View details for Web of Science ID A1985AVD3300003
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NEW ELECTROCHROMIC MATERIAL BASED ON THE ELECTROCHEMICAL INSERTION OF LITHIUM INTO BLEACHED POTASSIUM HEXATUNGSTATE
MATERIALS RESEARCH BULLETIN
1985; 20 (8): 897-904
View details for Web of Science ID A1985ANY3700005
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GENERAL DISCUSSION, 2ND INTERNATIONAL MEETING ON LITHIUM BATTERIES, PARIS, APRIL 27, 1984
JOURNAL OF POWER SOURCES
1985; 14 (1-3): 259-266
View details for Web of Science ID A1985ADY5000040
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THE OXYGEN ION CONDUCTIVITY OF MULLITE PREPARED USING A WET CHEMICAL PROCESS
SOLID STATE IONICS
1984; 11 (4): 271-278
View details for Web of Science ID A1984SF75100001
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RELATIONSHIPS AMONG ELECTROCHEMICAL, THERMODYNAMIC, AND OXYGEN POTENTIAL QUANTITIES IN LITHIUM-TRANSITION METAL-OXYGEN MOLTEN-SALT CELLS
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
1984; 131 (3): 543-549
View details for Web of Science ID A1984SG56000014
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AN ELECTROCHEMICAL STUDY OF THE MIXED BETA-VANADIUM BRONZES LIYNAXV2O5 AND LIYKXV2O5
MATERIALS RESEARCH BULLETIN
1983; 18 (3): 337-346
View details for Web of Science ID A1983QN34800014
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THE KINETICS OF THE ELECTROCHEMICAL INSERTION OF LITHIUM INTO CUBIC SODIUM TUNGSTEN BRONZES
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
1983; 130 (4): 776-782
View details for Web of Science ID A1983QK64000008
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METHANE SYNTHESIS ON NICKEL BY A SOLID-STATE IONIC METHOD
SCIENCE
1983; 219 (4587): 967-969
Abstract
The feasibility of electrochemically synthesizing methane by a Fischer-Tropsch type reaction by use of a solid oxide electrolyte has been demonstrated. This solid-state ionic approach provides in situ control of the oxygen activity at the gascatalyst interface by imposing a suitable voltage drop across an oxygen-conducting solid electrolyte from an external source. Methanation rates for hydrogen-carbon monoxide and hydrogen-carbon dioxide synthesis gas mixtures upon nickel electrodes showed substantial enhancement with the use of this technique, reaching values nearly two orders of magnitude higher than their intrinsic rates.
View details for Web of Science ID A1983QC05000026
View details for PubMedID 17817934
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A NEW CHEMICAL METHOD FOR PREPARATION OF BOTH PURE AND DOPED MULLITE
MATERIALS RESEARCH BULLETIN
1983; 18 (5): 581-588
View details for Web of Science ID A1983QT10800009
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THE TRANSIENT ELECTRICAL RESPONSE OF ELECTROCHEMICAL SYSTEMS CONTAINING INSERTION REACTION ELECTRODES
SOLID STATE IONICS
1982; 7 (3): 213-218
View details for Web of Science ID A1982PS79600003
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ELECTROCATALYTIC SYNTHESIS OF METHANE ON STABILIZED ZIRCONIA FROM H2-CO2 MIXTURES
SOLID STATE IONICS
1981; 5 (OCT): 563-566
View details for Web of Science ID A1981MR25900133
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ANION DISORDER OF BETA-PBF2 IN SUPERIONIC STATE BY X-RAY-DIFFRACTION
SOLID STATE IONICS
1981; 3-4 (AUG): 381-384
View details for Web of Science ID A1981ML07700073
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THERMODYNAMIC STUDY OF THE LITHIUM-TIN SYSTEM
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
1981; 128 (6): 1181-1187
View details for Web of Science ID A1981LS41800002
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THERMODYNAMICS AND KINETICS OF THE ELECTROCHEMICAL INSERTION OF LITHIUM INTO TUNGSTEN BRONZES
SOLID STATE IONICS
1981; 5 (OCT): 351-354
View details for Web of Science ID A1981MR25900081
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ELECTROCHEMICAL INVESTIGATION OF THE LITHIUM-GALLIUM SYSTEM
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
1981; 128 (8): 1636-1641
View details for Web of Science ID A1981MB16200002
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ALL-SOLID LITHIUM ELECTRODES WITH MIXED-CONDUCTOR MATRIX
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
1981; 128 (4): 725-729
View details for Web of Science ID A1981LK27600002
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CHEMICAL DIFFUSION IN INTERMEDIATE PHASES IN THE LITHIUM-SILICON SYSTEM
JOURNAL OF SOLID STATE CHEMISTRY
1981; 37 (3): 271-278
View details for Web of Science ID A1981LS00100002
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SOME NON-BATTERY APPLICATIONS OF SOLID ELECTROLYTES AND MIXED CONDUCTORS
SOLID STATE IONICS
1981; 5 (OCT): 15-20
View details for Web of Science ID A1981MR25900004
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STEADY-STATE DC POLARIZATION CHARACTERISTICS OF THE O2, PT-STABILIZED ZIRCONIA INTERFACE
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
1980; 127 (12): 2620-2628
View details for Web of Science ID A1980KM09800017
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THERMODYNAMIC AND MASS-TRANSPORT PROPERTIES OF LIIN
MATERIALS RESEARCH BULLETIN
1980; 15 (9): 1225-1234
View details for Web of Science ID A1980KK02400004
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ELECTROCHEMICAL INVESTIGATION OF SOLUBILITY AND CHEMICAL DIFFUSION OF LITHIUM IN ALUMINUM
METALLURGICAL TRANSACTIONS B-PROCESS METALLURGY
1980; 11 (1): 131-137
View details for Web of Science ID A1980JL95000017
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THERMODYNAMIC INVESTIGATIONS OF TERNARY LITHIUM-TRANSITION METAL-OXYGEN CATHODE MATERIALS
MATERIALS RESEARCH BULLETIN
1980; 15 (5): 561-570
View details for Web of Science ID A1980JS35700003
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CHEMICAL DIFFUSION IN INTERMEDIATE PHASES IN THE LITHIUM-TIN SYSTEM
JOURNAL OF SOLID STATE CHEMISTRY
1980; 35 (3): 376-384
View details for Web of Science ID A1980LF71800011
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SILVER IONIC AND ELECTRONIC CONDUCTIVITY IN AG9GAS6, AG9AIS6, AGGAS2, AGAIS2, AND AGAL5S8
JOURNAL OF SOLID STATE CHEMISTRY
1980; 35 (2): 207-214
View details for Web of Science ID A1980KX68300011
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APPLICATION OF AC TECHNIQUES TO THE STUDY OF LITHIUM DIFFUSION IN TUNGSTEN TRIOXIDE THIN-FILMS
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
1980; 127 (2): 343-350
View details for Web of Science ID A1980JE21500019
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IONIC-CONDUCTIVITY OF 8MOL.-PERCENTSC2O3-ZRO2 MEASURED BY USE OF BOTH AC AND DC TECHNIQUES
MATERIALS SCIENCE AND ENGINEERING
1980; 46 (1): 53-62
View details for Web of Science ID A1980KV23500004
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STUDY OF THE SYSTEMS LI2S-AL2S3, NA2S-AL2S3, K2S-AL2S3 - PREPARATION, PHASE STUDY AND ELECTRICAL-CONDUCTIVITY
MATERIALS RESEARCH BULLETIN
1979; 14 (7): 881-889
View details for Web of Science ID A1979HE19500006
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DECOMPOSITION OF NITRIC-OXIDE ON ZIRCONIA IN A SOLID-STATE ELECTROCHEMICAL-CELL
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
1979; 126 (6): 1067-1075
View details for Web of Science ID A1979GX87400042
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THERMODYNAMIC AND MASS-TRANSPORT PROPERTIES OF LIAL
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
1979; 126 (12): 2258-2266
View details for Web of Science ID A1979JM04200042
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IONIC-CONDUCTIVITY IN LITHIUM IMIDE
PHYSICS LETTERS A
1979; 72 (6): 464-466
View details for Web of Science ID A1979HG10700022
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PREPARATION OF ALUMINUM SULFIDE
MATERIALS RESEARCH BULLETIN
1979; 14 (1): 127-132
View details for Web of Science ID A1979GG43700018
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THERMODYNAMIC PROPERTIES OF INTERMETALLIC SYSTEMS LITHIUM-ANTIMONY AND LITHIUM-BISMUTH
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
1978; 125 (1): 7-14
View details for Web of Science ID A1978EG03000002
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ELECTROCHEMICAL METHODS FOR DETERMINING KINETIC-PROPERTIES OF SOLIDS
ANNUAL REVIEW OF MATERIALS SCIENCE
1978; 8: 269-311
View details for Web of Science ID A1978FK12600010
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FAST IONIC-CONDUCTIVITY IN LITHIUM NITRIDE
MATERIALS RESEARCH BULLETIN
1978; 13 (1): 23-32
View details for Web of Science ID A1978EJ22500004
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IONIC-CONDUCTIVITY OF SOLID AND LIQUID LIALCL4
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
1977; 124 (1): 35-38
View details for Web of Science ID A1977CR18100006
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IONIC-CONDUCTIVITY OF SOME LITHIUM SILICATES AND ALUMINOSILICATES
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
1977; 124 (6): 871-873
View details for Web of Science ID A1977DH28600020
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MORPHOLOGICAL STABILITY OF A PLANE INTERFACE DURING ELECTROCRYSTALLIZATION FROM MOLTEN-SALTS
JOURNAL OF CRYSTAL GROWTH
1977; 37 (2): 159-162
View details for Web of Science ID A1977DB55100010
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RECENT RESULTS ON LITHIUM ION CONDUCTORS
ELECTROCHIMICA ACTA
1977; 22 (7): 773-781
View details for Web of Science ID A1977DN67800019
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STRUCTURAL ASPECTS OF SOME MIXED METAL FERROCYANIDES
JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY
1977; 39 (10): 1779-1783
View details for Web of Science ID A1977DZ40300011
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DETERMINATION OF KINETIC-PARAMETERS OF MIXED-CONDUCTING ELECTRODES AND APPLICATION TO SYSTEM LI3SB
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
1977; 124 (10): 1569-1578
View details for Web of Science ID A1977DW32500020
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ELECTROCHEMICAL INVESTIGATION OF CHEMICAL DIFFUSION, PARTIAL IONIC CONDUCTIVITIES, AND OTHER KINETIC-PARAMETERS IN LI3SB AND LI3BI
JOURNAL OF SOLID STATE CHEMISTRY
1977; 22 (3): 297-308
View details for Web of Science ID A1977DZ95500006
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ELECTROCHEMICAL STUDIES OF PARABOLIC REACTION-RATES AND THERMODYNAMIC PROPERTIES
ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-FRANKFURT
1977; 108 (1): 105-122
View details for Web of Science ID A1977FP02100009
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IONIC-CONDUCTIVITY AND ELECTRODE EFFECTS ON BETA-PBF2
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
1977; 77 (3): 319-337
View details for Web of Science ID A1977DC24200005
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IONIC-CONDUCTIVITY OF LITHIUM ORTHOSILICATE - LITHIUM PHOSPHATE SOLID-SOLUTIONS
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
1977; 124 (8): 1240-1242
View details for Web of Science ID A1977DQ55000022
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CONDITIONS FOR ENHANCED CHEMICAL DIFFUSION OF IONS IN POLYMERS - REVIEW
MACROMOLECULES
1977; 10 (5): 889-892
View details for Web of Science ID A1977DX21600002
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DC RESISTANCES IN ELECTROLYTIC CRYSTALLIZATION FROM MOLTEN-SALTS
JOURNAL OF CRYSTAL GROWTH
1976; 33 (2): 232-238
View details for Web of Science ID A1976BR03400005
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REACTION OF ANTIMONY PENTAFLUORIDE WITH POLY (CARBON MONOFLUORIDE)
MATERIALS RESEARCH BULLETIN
1976; 11 (6): 615-620
View details for Web of Science ID A1976BV09300003
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IONIC-CONDUCTIVITY OF LI-4GEO-4, LI-2GEO-3 AND LI-2GE-7O-15
MATERIALS RESEARCH BULLETIN
1976; 11 (5): 533-538
View details for Web of Science ID A1976BP83400013
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BASIC RESEARCH IN MATERIALS
SCIENCE
1976; 191 (4228): 647-650
View details for Web of Science ID A1976BE89600005
View details for PubMedID 17754155
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LITHIUM ION CONDUCTIVITY IN LITHIUM NITRIDE
PHYSICS LETTERS A
1976; 58 (4): 231-233
View details for Web of Science ID A1976CE49200011
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IONIC-CONDUCTIVITY OF ALKALI-METAL CHLOROALUMINATES
PHYSICS LETTERS A
1976; 58 (4): 245-248
View details for Web of Science ID A1976CE49200016
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GROWTH OF LANTHANUM HEXABORIDE SINGLE-CRYSTALS BY MOLTEN-SALT ELECTROLYSIS
JOURNAL OF CRYSTAL GROWTH
1976; 34 (1): 85-91
View details for Web of Science ID A1976BV81600010
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ELECTRICAL-PROPERTIES OF UNDOPED AND DOPED POTASSIUM TETRAFLUOALUMINATE - KA1F-4
JOURNAL OF SOLID STATE CHEMISTRY
1976; 16 (3-4): 413-422
View details for Web of Science ID A1976BJ05300023
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ELECTRICAL-PROPERTIES OF K2FECL5.H2O AND K2ALF5
JOURNAL OF SOLID STATE CHEMISTRY
1976; 18 (4): 325-328
View details for Web of Science ID A1976CD60800004
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CALCULATION OF MOTIONAL ACTIVATION-ENERGIES FOR INTERSTITIAL IONS IN RUTILE STRUCTURE USING A MINIMUM ENERGY PATH MODEL
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS
1976; 37 (2): 167-172
View details for Web of Science ID A1976AY86900006
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IONIC-CONDUCTIVITY OF LITHIUM PHOSPHATE DOPED LITHIUM ORTHOSILICATE
MATERIALS RESEARCH BULLETIN
1976; 11 (10): 1227-1230
View details for Web of Science ID A1976CL70100004
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CRYSTAL-GROWTH BY ELECTROCHEMICAL CZOCHRALSKI TECHNIQUE (ECT)
JOURNAL OF CRYSTAL GROWTH
1976; 34 (1): 1-10
View details for Web of Science ID A1976BV81600001
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IONIC-CONDUCTIVITY OF SOME LITHIUM SILICATES AND ALUMINOSILICATES
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
1976; 123 (10): 1469-1476
View details for Web of Science ID A1976CE23500010
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IONIC MOTION IN BETA-PBF2
JOURNAL OF APPLIED PHYSICS
1975; 46 (7): 2873-2876
View details for Web of Science ID A1975AG27300011
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SURFACE-STRUCTURE AND ELECTROLYTIC GROWTH STABILITY OF LAB6 CRYSTALS
JOURNAL OF CRYSTAL GROWTH
1975; 29 (1): 65-68
View details for Web of Science ID A1975AH69600010
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PHASES IN SYSTEM NAALO2-AL2O3
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
1975; 58 (11-1): 497-500
View details for Web of Science ID A1975AZ89600008
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COMPOSITION DEPENDENCE OF IONIC-CONDUCTIVITY
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS
1975; 36 (7-8): 815-817
View details for Web of Science ID A1975AD67000027
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CATALYTIC DECOMPOSITION OF NITRIC-OXIDE ON ZIRCONIA BY ELECTROLYTIC REMOVAL OF OXYGEN
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
1975; 122 (7): 869-875
View details for Web of Science ID A1975AG81000006
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NATURE OF CHROMIUM TRIOXIDE INTERCALATION IN GRAPHITE
CARBON
1974; 12 (2): 199-208
View details for Web of Science ID A1974T147000010
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WIDE LINE NUCLEAR MAGNETIC-RESONANCE OF F-19 IN GRAPHITE ANTIMONY PENTAFLUORIDE - EVIDENCE FOR RAPID MOTION OF INTERCALATED SPECIES
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS
1974: 924-925
View details for Web of Science ID A1974U720500007
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CARBON MONOFLUORIDE - EVIDENCE FOR A STRUCTURE CONTAINING AN INFINITE ARRAY OF CYCLOHEXANE BOATS
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
1974; 96 (25): 7841-7842
View details for Web of Science ID A1974U969200054
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MECHANISM AND KINETICS OF NICKEL CHROMITE FORMATION
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
1973; 120 (6): 825-833
View details for Web of Science ID A1973P748100025