Rodney Ewing
Frank Stanton Professor in Nuclear Security and Senior Fellow at the Freeman Spogli Institute for International Studies
Geological Sciences
Bio
Rod Ewing is the Frank Stanton Professor in Nuclear Security in the Center for International Security and Cooperation in the Freeman Spogli Institute for International Studies and a Professor in the Department of Geological and Environmental Sciences in the School of Earth Sciences at Stanford University. He is also the Edward H. Kraus Distinguished University Professor Emeritus at the University of Michigan, where he as in three Departments: Earth & Environmental Sciences, Nuclear Engineering & Radiological Sciences, and Materials Science and Engineering. He is also a Regents' Emeritus Professor at the University of New Mexico.
Ewing received a B.S. degree in geology from Texas Christian University (1968, summa cum laude) and M.S. (l972) and Ph.D. (l974, with distinction) degrees from Stanford University where he held an NSF Fellowship. His graduate studies focused on an esoteric group of minerals, metamict Nb-Ta-Ti oxides, which are unusual because they have become amorphous due to radiation damage caused by the presence of radioactive elements. Over the past thirty years, the early study of these unusual minerals has blossomed into a broadly based research program on radiation effects in complex ceramic materials. This has led to the development of techniques to predict the long-term behavior of materials, such as those used in radioactive waste disposal. He is the author or co-author of over 700 research publications and the editor or co-editor of 18 monographs, proceedings volumes or special issues of journals. He has published widely in mineralogy, geochemistry, materials science, nuclear materials, physics and chemistry in over 100 different ISI journals. He has been granted a patent for the development of a highly durable material for the immobilization of excess weapons plutonium. He is a founding Editor of the magazine, Elements, which is now supported by 17 earth science societies.
Ewing has received the Hawley Medal of the Mineralogical Association of Canada in 1997 and 2002, a Guggenheim Fellowship in 2002, the Dana Medal of the Mineralogical Society of America in 2006, the Lomonosov Gold Medal of the Russian Academy of Sciences in 2006, a Honorary Doctorate from the Université Pierre et Marie Curie in 2007 and is a foreign Fellow of the Royal Society of Canada. He is also a fellow of the Geological Society of America, Mineralogical Society of America, American Geophysical Union, Geochemical Society, American Ceramic Society, the American Association for the Advancement of Science and the Materials Research Society. He has been president of the Mineralogical Society of America (2002) and the International Union of Materials Research Societies (1997-1998). Ewing serves on the Board of Directors of the Geochemical Society, the Board of Governors of the Gemological Institute of America and is a member of the Science and Security Board of the Bulletin of the Atomic Scientists.
Professor Ewing is co-editor of and a contributing author of Radioactive Waste Forms for the Future (North-Holland Physics, Amsterdam, 1988) and Uncertainty Underground – Yucca Mountain and the Nation’s High-Level Nuclear Waste (MIT Press, 2006). He has served on eleven National Research Council committees for the National Academy of Sciences that have reviewed issues related to nuclear waste and nuclear weapons. In 2012, he was appointed by President Obama to Chair the Nuclear Waste Technical Review Board.
Academic Appointments
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Professor, Geological Sciences
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Senior Fellow, Freeman Spogli Institute for International Studies
Honors & Awards
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Election, National Academy of Engineering (2017)
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Grandey Distinguished Lecture, Colorado School of Mines (2017)
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Baldwin Frontiers in Geology Distinguished Lecture, University of Miami Ohio (2016)
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Director's Distinguished Lecture, Pacific Northwest National Laboratory (2016)
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IMA Medal for Excellence in Mineralogical Research, International Mineralogical Association (2015)
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Ian Campbell Medal for Superlative Service to the Geosciences, American Geoscience Institute (2015)
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Roebling Medal, Mineralogical Society of America (2015)
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Edward H. Kraus Distinguished University Professor Emeritus, University of Michigan (2014 - present)
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Honorary Fellow, Mineralogical Society of Great Britain and Ireland (2013)
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Ida Beam Distinguished Visiting Professorship, University of Iowa (2013)
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Hallimond Lecture, Mineralogical Society of Great Britain and Ireland (2010)
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Edward H. Kraus Distinguished University Professor, University of Michigan (2009 - 2013)
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Fellow, Geochemical Society and the European Association for Geochemistry (2009)
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Foreign Fellow, Royal Society of Canada (2009)
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Fellow, American Ceramic Society (2008)
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Fellow, Materials Research Society (2008)
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Docteur Honoris Causa, Université Pierre et Marie Curie, Paris VII (2007)
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Fellow, American Geophysical Union (2007)
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Hamilton Visiting Scholar, Southern Methodist University (2007)
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Dana Medal, Mineralogical Society of America (2006)
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Lomonosov Great Gold Medal, Russian Academy of Sciences (2006)
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Michel T. Halbouty Distinguished Lecturer, Geological Society of America (2006)
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Umbgrove Lecture, Universiteit Utrecht, The Netherlands (2006)
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Zussman Lecture, University of Manchester (2005)
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Distinguished Lecturer, Mineralogical Society of America (2004 - 2005)
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Fellow, American Association for the Advancement of Science (2004)
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Fellowship, Guggenheim Foundation (2002)
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Hawley Medal, Mineralogical Association of Canada (2002)
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Regents' Professor Emeritus, University of New Mexico (1997 - present)
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Fellowship, Yamada Foundation, University of Tokyo (1997)
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Hawley Medal, Mineralogical Association of Canada (1997)
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Regents' Professor, University of New Mexico (1993 - 1997)
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Fellow, Geological Society of America (1985)
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Fellow, Mineralogical Society of America (1983)
Boards, Advisory Committees, Professional Organizations
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Executive Editor, Geochemical Perspectives Letters (2014 - Present)
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Member, Editorial Board of Applied Physics Letters (2014 - Present)
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Member, Science and Security Board of the Bulletin of Atomic Scientists (2013 - Present)
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Director, Board of Directors of the Geochemical Society (2012 - 2015)
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Chairman, Nuclear Waste Technical Review Board (2011 - Present)
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Principal Editor, Nano LIFE (2010 - Present)
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Governor, Board of Governors of the Gemological Institute of America (2006 - 2015)
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Founding Editor, Elements magazine (2003 - 2004)
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President, Mineralogical Society of America (2002 - 2003)
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President, International Union of Materials Research Societies (1997 - 1998)
Professional Education
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Ph.D., Stanford University, Mineralogy (1974)
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M.S., Stanford University, Mineralogy (1972)
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B.S., Texas Christian University, Geology (1968)
Patents
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Rodney Ewing, Werner Lutze, William J. Weer. "United States Patent 5,545,797 Method of immobilizing weapons plutonium to provide a durable, disposal waste product", University of New Mexico, Sep 13, 1996
2016-17 Courses
- Earthquake 9.0: The Heritage of Fukushima Daiichi 6 Years Later
GS 59N (Spr) - Managing Nuclear Waste: Technical, Political and Organizational Challenges
GS 266, IPS 266 (Win) -
Independent Studies (9)
- Advanced Projects
GS 399 (Aut, Win, Spr) - Directed Reading with Geological Sciences Faculty
GS 292 (Aut, Win, Spr) - Field Research
GS 299 (Aut, Win, Spr) - Graduate Research
GS 400 (Aut, Win, Spr, Sum) - Honors Program
GS 199 (Win, Spr) - Practical Experience in the Geosciences
GS 385 (Aut, Win, Spr) - Senior Thesis
GS 197 (Aut, Win, Spr) - Special Problems in Geological Sciences
GS 198 (Aut, Win, Spr) - Undergraduate Research in Geological Sciences
GS 192 (Aut, Win, Spr, Sum)
- Advanced Projects
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Prior Year Courses
2015-16 Courses
- Environmental Impact of Energy Systems: What are the Risks?
EARTHSYS 46Q, GS 46Q (Win) - The Legacy of Fukushima Daiichi
GS 59N (Spr)
2014-15 Courses
- Managing Nuclear Waste: Technical, Political and Organizational Challenges
GES 266, IPS 266 (Win)
- Environmental Impact of Energy Systems: What are the Risks?
Stanford Advisees
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Doctoral (Program)
Dylan Rittman, Katlyn Turner -
Postdoctoral Faculty Sponsor
Chien-Hung Chen, Chenxu Wang -
Postdoctoral Research Mentor
Cameron Tracy, Eva Uribe
All Publications
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In-vitro depth-dependent hyperthermia of human mammary gland adenocarcinoma
MATERIALS SCIENCE & ENGINEERING C-MATERIALS FOR BIOLOGICAL APPLICATIONS
2016; 69: 12-16
Abstract
Nanoparticle mediated photothermal ablation of cancerous tissue shows promising results and applicability as a highly efficacious treatment method. As a majority of the photothermal work has been conducted with minimal attenuation of the laser before reaching the nanoparticles within surface seeded tumors in-vivo or through buffered media in-vitro, it is important to understand the effects of greater laser attenuation on photothermal efficacy mediated by changes in the scattering and absorption of the laser. Photothermal efficacy using a near infrared (NIR) 785nm laser irradiating polystyrene (PS) stabilized magnetite (Fe3O4) nanoparticles (PS-Fe3O4) is examined on MDA-MB-231 human mammary gland adenocarcinoma in-vitro. Agarose gel columns of various heights were created to simulate soft tissue and subsequently used for NIR laser attenuation. Polystyrene was found to significantly improve magnetite nanoparticle stability in serum containing media and modified Hank's Balanced Salt Solution and was able to induce significant hyperthermic ablation at mass concentrations which also did not elicit significant innate toxicity. Furthermore it was found that the polystyrene coating significantly reduced innate toxicity over 48h compared to uncoated magnetite. Agar gel layers provided similar optical attenuation in the NIR region to skin and prostate.
View details for DOI 10.1016/j.msec.2016.06.026
View details for Web of Science ID 000383930900002
View details for PubMedID 27612683
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Energetics of a Uranothorite (Th1-xUxSiO4) Solid Solution
CHEMISTRY OF MATERIALS
2016; 28 (19): 7117-7124
View details for DOI 10.1021/acs.chemmater.6b03346
View details for Web of Science ID 000385336500037
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Anisotropic mechanical properties of zircon and the effect of radiation damage
PHYSICS AND CHEMISTRY OF MINERALS
2016; 43 (9): 627-638
View details for DOI 10.1007/s00269-016-0822-9
View details for Web of Science ID 000385197800002
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Structural response of titanate pyrochlores to swift heavy ion irradiation
ACTA MATERIALIA
2016; 117: 207-215
View details for DOI 10.1016/j.actamat.2016.07.017
View details for Web of Science ID 000383005300020
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Role of composition, bond covalency, and short-range order in the disordering of stannate pyrochlores by swift heavy ion irradiation
PHYSICAL REVIEW B
2016; 94 (6)
View details for DOI 10.1103/PhysRevB.94.064102
View details for Web of Science ID 000380950400002
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Geological Disposal of Nuclear Waste: a Primer
ELEMENTS
2016; 12 (4): 233-237
View details for DOI 10.2113/gselements.12.4.233
View details for Web of Science ID 000384909000003
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Stability of fluorite-type La2Ce2O7 under extreme conditions
JOURNAL OF ALLOYS AND COMPOUNDS
2016; 674: 168-173
View details for DOI 10.1016/j.jallcom.2016.03.002
View details for Web of Science ID 000373612500024
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First experimental determination of the solubility constant of coffinite
GEOCHIMICA ET COSMOCHIMICA ACTA
2016; 181: 36-53
View details for DOI 10.1016/j.gca.2016.02.010
View details for Web of Science ID 000373618200003
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Anisotropic expansion and amorphization of Ga2O3 irradiated with 946 MeV Au ions
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS
2016; 374: 40-44
View details for DOI 10.1016/j.nimb.2015.08.059
View details for Web of Science ID 000375819500009
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Radioactive Cs in the estuary sediments near Fukushima Daiichi Nuclear Power Plant
SCIENCE OF THE TOTAL ENVIRONMENT
2016; 551: 155-162
View details for DOI 10.1016/j.scitotenv.2016.01.155
View details for Web of Science ID 000372589800019
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Probing disorder in isometric pyrochlore and related complex oxides
NATURE MATERIALS
2016; 15 (5): 507-?
Abstract
There has been an increased focus on understanding the energetics of structures with unconventional ordering (for example, correlated disorder that is heterogeneous across different length scales). In particular, compounds with the isometric pyrochlore structure, A2B2O7, can adopt a disordered, isometric fluorite-type structure, (A, B)4O7, under extreme conditions. Despite the importance of the disordering process there exists only a limited understanding of the role of local ordering on the energy landscape. We have used neutron total scattering to show that disordered fluorite (induced intrinsically by composition/stoichiometry or at far-from-equilibrium conditions produced by high-energy radiation) consists of a local orthorhombic structural unit that is repeated by a pseudo-translational symmetry, such that orthorhombic and isometric arrays coexist at different length scales. We also show that inversion in isometric spinel occurs by a similar process. This insight provides a new basis for understanding order-to-disorder transformations important for applications such as plutonium immobilization, fast ion conduction, and thermal barrier coatings.
View details for DOI 10.1038/NMAT4581
View details for Web of Science ID 000374763500010
View details for PubMedID 26928636
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Phase transition and water incorporation into Eu2Sn2O7 pyrochlore at high pressure
CHEMICAL PHYSICS LETTERS
2016; 650: 138-143
View details for DOI 10.1016/j.cplett.2016.03.016
View details for Web of Science ID 000374966900027
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Mechanical properties of natural radiation-damaged titanite and temperature-induced structural reorganization: A nanoindentation and Raman spectroscopic study
AMERICAN MINERALOGIST
2016; 101 (1-2): 399-406
View details for DOI 10.2138/am-2016-5433
View details for Web of Science ID 000370213500037
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Study on structural recovery of graphite irradiated with swift heavy ions at high temperature
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS
2015; 235: 522-524
View details for DOI 10.1016/j.nimb.2015.09.007
View details for Web of Science ID 000366787000015
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Phase transformations in Ln(2)O(3) materials irradiated with swift heavy ions
PHYSICAL REVIEW B
2015; 92 (17)
View details for DOI 10.1103/PhysRevB.92.174101
View details for Web of Science ID 000364013100001
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Radiation Stability of Spark-Plasma-Sintered Lead Vanadate Iodoapatite
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
2015; 98 (10): 3361-3366
View details for DOI 10.1111/jace.13738
View details for Web of Science ID 000362599000054
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C-60 and U ion irradiation of Gd2TixZr2-xO7 pyrochlore
JOURNAL OF MATERIALS RESEARCH
2015; 30 (16): 2456-2466
View details for DOI 10.1557/jmr.2015.230
View details for Web of Science ID 000360650200008
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Coffinite, USiO4, Is Abundant in Nature: So Why Is It So Difficult To Synthesize?
INORGANIC CHEMISTRY
2015; 54 (14): 6687-6696
Abstract
Coffinite, USiO4, is the second most abundant U(4+) mineral on Earth, and its formation by the alteration of the UO2 in spent nuclear fuel in a geologic repository may control the release of radionuclides to the environment. Despite its abundance in nature, the synthesis and characterization of coffinite have eluded researchers for decades. On the basis of the recent synthesis of USiO4, we can now define the experimental conditions under which coffinite is most efficiently formed. Optimal formation conditions are defined for four parameters: pH, T, heating time, and U/Si molar ratio. The adjustment of pH between 10 and 12 leads probably to the formation of a uranium(IV) hydroxo-silicate complex that acts as a precursor of uranium(IV) silicate colloids and then of coffinite. Moreover, in this pH range, the largest yield of coffinite formation (as compared with those of the two competing byproduct phases, nanometer-scale UO2 and amorphous SiO2) is obtained for 250 °C, 7 days, and 100% excess silica.
View details for DOI 10.1021/ic502808n
View details for Web of Science ID 000358549300005
View details for PubMedID 26145720
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Response of Gd2Ti2O7 and La2Ti2O7 to swift-heavy ion irradiation and annealing
ACTA MATERIALIA
2015; 93: 1-11
View details for DOI 10.1016/j.actamat.2015.04.010
View details for Web of Science ID 000356207500001
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In situ defect annealing of swift heavy ion irradiated CeO2 and ThO2 using synchrotron X-ray diffraction and a hydrothermal diamond anvil cell
JOURNAL OF APPLIED CRYSTALLOGRAPHY
2015; 48: 711-717
View details for DOI 10.1107/S160057671500477X
View details for Web of Science ID 000355562000011
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Thermodynamics of formation of coffinite, USiO4
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA
2015; 112 (21): 6551-6555
Abstract
Coffinite, USiO4, is an important U(IV) mineral, but its thermodynamic properties are not well-constrained. In this work, two different coffinite samples were synthesized under hydrothermal conditions and purified from a mixture of products. The enthalpy of formation was obtained by high-temperature oxide melt solution calorimetry. Coffinite is energetically metastable with respect to a mixture of UO2 (uraninite) and SiO2 (quartz) by 25.6 ± 3.9 kJ/mol. Its standard enthalpy of formation from the elements at 25 °C is -1,970.0 ± 4.2 kJ/mol. Decomposition of the two samples was characterized by X-ray diffraction and by thermogravimetry and differential scanning calorimetry coupled with mass spectrometric analysis of evolved gases. Coffinite slowly decomposes to U3O8 and SiO2 starting around 450 °C in air and thus has poor thermal stability in the ambient environment. The energetic metastability explains why coffinite cannot be synthesized directly from uraninite and quartz but can be made by low-temperature precipitation in aqueous and hydrothermal environments. These thermochemical constraints are in accord with observations of the occurrence of coffinite in nature and are relevant to spent nuclear fuel corrosion.
View details for DOI 10.1073/pnas.1507441112
View details for Web of Science ID 000355213200029
View details for PubMedID 25964321
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Characterization of ion-induced radiation effects in nuclear materials using synchrotron x-ray techniques
JOURNAL OF MATERIALS RESEARCH
2015; 30 (9): 1366-1379
View details for DOI 10.1557/jmr.2015.6
View details for Web of Science ID 000355283500016
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Ion-beam irradiation and Cm-244-doping investigations of the radiation response of actinide-bearing crystalline waste forms
JOURNAL OF MATERIALS RESEARCH
2015; 30 (9): 1516-1528
View details for DOI 10.1557/jmr.2015.23
View details for Web of Science ID 000355283500029
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Atomic disorder in Gd2Zr2O7 pyrochlore
APPLIED PHYSICS LETTERS
2015; 106 (19)
View details for DOI 10.1063/1.4921268
View details for Web of Science ID 000355008100012
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Uranium reduction on magnetite: Probing for pentavalent uranium using electrochemical methods
GEOCHIMICA ET COSMOCHIMICA ACTA
2015; 156: 194-206
View details for DOI 10.1016/j.gca.2015.02.014
View details for Web of Science ID 000352192100011
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Ultrafast laser and swift heavy ion irradiation: Response of Gd2O3 and ZrO2 to intense electronic excitation
APPLIED PHYSICS LETTERS
2015; 106 (17)
View details for DOI 10.1063/1.4919720
View details for Web of Science ID 000353839100029
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Constraints on Hf and Zr mobility in high-sulfidation epithermal systems: formation of kosnarite, KZr2(PO4)(3), in the Chaquicocha gold deposit, Yanacocha district, Peru
MINERALIUM DEPOSITA
2015; 50 (4): 429-436
View details for DOI 10.1007/s00126-015-0586-z
View details for Web of Science ID 000354403500002
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Thermodynamic mixing properties of the UO2-HfO2 solid solution: Density functional theory and Monte Carlo simulations
JOURNAL OF NUCLEAR MATERIALS
2015; 458: 296-303
View details for DOI 10.1016/j.jnucmat.2014.12.039
View details for Web of Science ID 000349169600036
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The behavior of rare-earth pyrochlores and perovskites under ion irradiation
DOKLADY EARTH SCIENCES
2015; 461 (1): 247-253
View details for DOI 10.1134/S1028334X15030071
View details for Web of Science ID 000353235800010
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Long-term storage of spent nuclear fuel.
Nature materials
2015; 14 (3): 252-257
View details for DOI 10.1038/nmat4226
View details for PubMedID 25698421
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Role of vein-phases in nanoscale sequestration of U, Nb, Ti, and Pb during the alteration of pyrochlore
GEOCHIMICA ET COSMOCHIMICA ACTA
2015; 150: 226-252
View details for DOI 10.1016/j.gca.2014.11.024
View details for Web of Science ID 000348511300014
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Redox response of actinide materials to highly ionizing radiation
NATURE COMMUNICATIONS
2015; 6
Abstract
Energetic radiation can cause dramatic changes in the physical and chemical properties of actinide materials, degrading their performance in fission-based energy systems. As advanced nuclear fuels and wasteforms are developed, fundamental understanding of the processes controlling radiation damage accumulation is necessary. Here we report oxidation state reduction of actinide and analogue elements caused by high-energy, heavy ion irradiation and demonstrate coupling of this redox behaviour with structural modifications. ThO2, in which thorium is stable only in a tetravalent state, exhibits damage accumulation processes distinct from those of multivalent cation compounds CeO2 (Ce(3+) and Ce(4+)) and UO3 (U(4+), U(5+) and U(6+)). The radiation tolerance of these materials depends on the efficiency of this redox reaction, such that damage can be inhibited by altering grain size and cation valence variability. Thus, the redox behaviour of actinide materials is important for the design of nuclear fuels and the prediction of their performance.
View details for DOI 10.1038/ncomms7133
View details for Web of Science ID 000348832300004
View details for PubMedID 25626111
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Photothermal effects and toxicity of Fe3O4 nanoparticles via near infrared laser irradiation for cancer therapy
MATERIALS SCIENCE & ENGINEERING C-MATERIALS FOR BIOLOGICAL APPLICATIONS
2015; 46: 97-102
Abstract
The photothermal effect of magnetite (Fe3O4) nanoparticles was characterized by photonic absorption in the near-infrared (NIR) region. Upon laser irradiation at 785 nm, the Fe3O4 nanoparticles generate localized hyperthermia in tumorous lesions, which is an effective strategy for cancer therapy; however, uncoated magnetite possesses an innate toxicity which can lead to drawbacks in the clinical setting. To reduce innate toxicity, a poly(acrylic acid) (PAA) coating on the nanoparticles was investigated in order to determine the alterations to stability and the degree of toxicity in an attempt to create a higher utility vector. It was found that the PAA coating significantly reduced the innate toxicity of the uncoated magnetite. Furthermore, the efficacy of PAA-coated magnetite nanoparticles (PAA-Fe3O4) was investigated for treating MDA-MB-231 (human mammary gland adenocarcinoma) cultures in viable concentration ranges (0.1-0.5mg/ml). An appropriate PAA-Fe3O4 concentration range was then established for inducing significant cell death by hyperthermic ablation, but not through innate toxicity.
View details for DOI 10.1016/j.msec.2014.09.043
View details for Web of Science ID 000347757100012
View details for PubMedID 25491964
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Carbonate orientational order and superlattice structure in vaterite
JOURNAL OF CRYSTAL GROWTH
2014; 407: 78-86
View details for DOI 10.1016/j.jcrysgro.2014.08.028
View details for Web of Science ID 000343093500015
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Incorporation of uranium in pyrochlore oxides and pressure-induced phase transitions
JOURNAL OF SOLID STATE CHEMISTRY
2014; 219: 49-54
View details for DOI 10.1016/j.jssc.2014.07.011
View details for Web of Science ID 000342336100007
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Thermodynamics of thorium substitution in yttrium iron garnet: comparison of experimental and theoretical results
JOURNAL OF MATERIALS CHEMISTRY A
2014; 2 (40): 16945-16954
View details for DOI 10.1039/c4ta03683b
View details for Web of Science ID 000343072300019
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Swift heavy ion track formation in Gd2Zr2-xTixO7 pyrochlore: Effect of electronic energy loss
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS
2014; 336: 102-115
View details for DOI 10.1016/j.nimb.2014.06.019
View details for Web of Science ID 000341550200015
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Effect of spatial confinement on magnetic hyperthermia via dipolar interactions in Fe3O4 nanoparticles for biomedical applications.
Materials science & engineering. C, Materials for biological applications
2014; 42: 52-63
Abstract
In this work, the effect of nanoparticle confinement on the magnetic relaxation of iron oxide (Fe3O4) nanoparticles (NP) was investigated by measuring the hyperthermia heating behavior in high frequency alternating magnetic field. Three different Fe3O4 nanoparticle systems having distinct nanoparticle configurations were studied in terms of magnetic hyperthermia heating rate and DC magnetization. All magnetic nanoparticle (MNP) systems were constructed using equivalent ~10nm diameter NP that were structured differently in terms of configuration, physical confinement, and interparticle spacing. The spatial confinement was achieved by embedding the Fe3O4 nanoparticles in the matrices of the polystyrene spheres of 100nm, while the unconfined was the free Fe3O4 nanoparticles well-dispersed in the liquid via PAA surface coating. Assuming the identical core MNPs in each system, the heating behavior was analyzed in terms of particle freedom (or confinement), interparticle spacing, and magnetic coupling (or dipole-dipole interaction). DC magnetization data were correlated to the heating behavior with different material properties. Analysis of DC magnetization measurements showed deviation from classical Langevin behavior near saturation due to dipole interaction modification of the MNPs resulting in a high magnetic anisotropy. It was found that the Specific Absorption Rate (SAR) of the unconfined nanoparticle systems were significantly higher than those of confined (the MNPs embedded in the polystyrene matrix). This increase of SAR was found to be attributable to high Néel relaxation rate and hysteresis loss of the unconfined MNPs. It was also found that the dipole-dipole interactions can significantly reduce the global magnetic response of the MNPs and thereby decrease the SAR of the nanoparticle systems.
View details for DOI 10.1016/j.msec.2014.04.064
View details for PubMedID 25063092
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Defect formation energy in pyrochlore: the effect of crystal size
MATERIALS RESEARCH EXPRESS
2014; 1 (3)
View details for DOI 10.1088/2053-1591/1/3/035501
View details for Web of Science ID 000209665200064
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Photoluminescence and photothermal effect of Fe3O4 nanoparticles for medical imaging and therapy
APPLIED PHYSICS LETTERS
2014; 105 (9)
View details for DOI 10.1063/1.4895133
View details for Web of Science ID 000342749800017
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The coupled geochemistry of Au and As in pyrite from hydrothermal ore deposits
GEOCHIMICA ET COSMOCHIMICA ACTA
2014; 140: 644-670
View details for DOI 10.1016/j.gca.2014.05.045
View details for Web of Science ID 000341925300039
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Dipole-interaction mediated hyperthermia heating mechanism of nanostructured Fe3O4 composites
MATERIALS LETTERS
2014; 129: 57-60
View details for DOI 10.1016/j.matlet.2014.05.001
View details for Web of Science ID 000338818800016
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Bulk Iodoapatite Ceramic Densified by Spark Plasma Sintering with Exceptional Thermal Stability
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
2014; 97 (8): 2409-2412
View details for DOI 10.1111/jace.13101
View details for Web of Science ID 000340529200017
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Effect of orientation on ion track formation in apatite and zircon
AMERICAN MINERALOGIST
2014; 99 (5-6): 1127-1132
View details for DOI 10.2138/am.2014.4669
View details for Web of Science ID 000335633900024
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Presentation of the Distinguished Public Service Award for 2013 of the Mineralogical Society of America to Pierrette Tremblay
AMERICAN MINERALOGIST
2014; 99 (5-6): 1185-1185
View details for DOI 10.2138/am.2014.637
View details for Web of Science ID 000335633900035
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The shape of ion tracks in natural apatite
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS
2014; 326: 117-120
View details for DOI 10.1016/j.nimb.2013.10.071
View details for Web of Science ID 000335631300029
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Swift heavy ion-induced phase transformation in Gd2O3
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS
2014; 326: 121-125
View details for DOI 10.1016/j.nimb.2013.10.073
View details for Web of Science ID 000335631300030
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High-pressure U3O8 with the fluorite-type structure
JOURNAL OF SOLID STATE CHEMISTRY
2014; 213: 110-115
View details for DOI 10.1016/j.jssc.2014.02.012
View details for Web of Science ID 000334654500017
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Defect accumulation in ThO2 irradiated with swift heavy ions
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS
2014; 326: 169-173
View details for DOI 10.1016/j.nimb.2013.08.070
View details for Web of Science ID 000335631300040
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SAXS and TEM investigation of ion tracks in neodymium-doped yttrium aluminium garnet
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS
2014; 326: 150-153
View details for DOI 10.1016/j.nimb.2013.10.076
View details for Web of Science ID 000335631300036
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Annealing behaviour of ion tracks in olivine, apatite and britholite
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS
2014; 326: 126-130
View details for DOI 10.1016/j.nimb.2013.10.072
View details for Web of Science ID 000335631300031
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Swift heavy ion irradiation-induced amorphization of La2Ti2O7
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS
2014; 326: 145-149
View details for DOI 10.1016/j.nimb.2013.10.088
View details for Web of Science ID 000335631300035
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Average structure and local configuration of excess oxygen in UO2+x
SCIENTIFIC REPORTS
2014; 4
Abstract
Determination of the local configuration of interacting defects in a crystalline, periodic solid is problematic because defects typically do not have a long-range periodicity. Uranium dioxide, the primary fuel for fission reactors, exists in hyperstoichiometric form, UO(2+x). Those excess oxygen atoms occur as interstitial defects, and these defects are not random but rather partially ordered. The widely-accepted model to date, the Willis cluster based on neutron diffraction, cannot be reconciled with the first-principles molecular dynamics simulations present here. We demonstrate that the Willis cluster is a fair representation of the numerical ratio of different interstitial O atoms; however, the model does not represent the actual local configuration. The simulations show that the average structure of UO(2+x) involves a combination of defect structures including split di-interstitial, di-interstitial, mono-interstitial, and the Willis cluster, and the latter is a transition state that provides for the fast diffusion of the defect cluster. The results provide new insights in differentiating the average structure from the local configuration of defects in a solid and the transport properties of UO(2+x).
View details for DOI 10.1038/srep04216
View details for Web of Science ID 000333017000001
View details for PubMedID 24642875
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Three New Silver Uranyl Diphosphonates: Structures and Properties
INORGANIC CHEMISTRY
2014; 53 (6): 2787-2796
Abstract
The hydrothermal reaction of uranium trioxide and methylenediphosphonic acid in the presence of silver nitrate resulted in the formation of three new uranyl coordination polymers: AgUO2[CH2(PO3)(PO3H)] (Ag-1), [Ag2(H2O)1.5]{(UO2)2[CH2(PO3)2]F2}·(H2O)0.5 (Ag-2), and Ag2UO2[CH2(PO3)2] (Ag-3). All consist of uranyl pentagonal bipyramids that form two-dimensional layered structures. Ag-1 and Ag-3 possess the same structural building unit, but the structures are different; Ag-3 is formed through edge-sharing of F atoms to form UO5F2 dimers. The pH and silver cation have significant effects on the structure that is synthesized. Raman spectra of single crystals of Ag-1, Ag-2, and Ag-3 reveal v1 UO2(2+) symmetric stretches of 816 and 829, 822, and 802 cm(-1), respectively. Electronic structure calculations were performed using the projector augmented wave (PAW) method with density functional theory (DFT) to gain insight into the nature of bonding and electronic characteristics of the synthesized compounds. Herein, we report the syntheses, crystal structures, Raman spectroscopy, and luminescent behavior of these three compounds.
View details for DOI 10.1021/ic401897n
View details for Web of Science ID 000333142800008
View details for PubMedID 24524249
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Molten salts activated by high-energy milling: A useful, low-temperature route for the synthesis of multiferroic compounds
JOURNAL OF ALLOYS AND COMPOUNDS
2014; 584: 93-100
View details for DOI 10.1016/j.jallcom.2013.09.003
View details for Web of Science ID 000327135400014
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Nano-porosity in GaSb induced by swift heavy ion irradiation
APPLIED PHYSICS LETTERS
2014; 104 (2)
View details for DOI 10.1063/1.4861747
View details for Web of Science ID 000330431000093
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Facile low temperature solid state synthesis of iodoapatite by high-energy ball milling
RSC ADVANCES
2014; 4 (73): 38718-38725
View details for DOI 10.1039/c4ra05320f
View details for Web of Science ID 000341776900031
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Electronic structure and thermodynamic stability of uranium-doped yttrium iron garnet
JOURNAL OF PHYSICS-CONDENSED MATTER
2013; 25 (49)
Abstract
The electronic and thermodynamic properties of yttrium iron garnet (Y3Fe5O12, YIG), as a possible uranium-bearing phase, have been investigated using first-principles and semi-empirical methods. The electronic structures of pure and U-doped YIG were calculated and compared in order to obtain a fundamental understanding of the incorporation mechanism and stability of U in a YIG matrix. Uranium at the A-site is in 4 + oxidation state, acting as a single donor and introducing a localized defect state in the band gap. The ionic relaxations show U at the A-site is an off-center impurity. At the B-site, uranium is in 5 + oxidation state giving rise to two localized defect states in the middle of the band gap. At thermodynamic equilibrium the incorporation of U is limited by (i) the relatively narrow stability domain of the host YIG and (ii) the precipitation of uranium oxides as secondary phases. Under Y-rich growth conditions, YIG is unstable with respect to competing phases such as the iron oxides, Y2O3 and YFeO3. Under O-rich conditions, the incorporation U is obstructed by the formation of uranium-oxide precipitates. Under Fe-rich growth conditions, the formation energies of UY (U at the A-site) and UFe (U at the B-site) become negative for 0 ≤ EF ≤ 0.62 eV and 0 ≤ EF ≤ 0.77 eV, respectively, indicating that U might be incorporated in p-type YIG.
View details for DOI 10.1088/0953-8984/25/49/495502
View details for Web of Science ID 000327181400007
View details for PubMedID 24184778
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Temperature dependence of ion track formation in quartz and apatite
JOURNAL OF APPLIED CRYSTALLOGRAPHY
2013; 46: 1558-1563
View details for DOI 10.1107/S0021889813022802
View details for Web of Science ID 000327070000004
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A self-consistent model describing the thermodynamics of Eu(III) adsorption onto hematite
GEOCHIMICA ET COSMOCHIMICA ACTA
2013; 122: 430-447
View details for DOI 10.1016/j.gca.2013.08.023
View details for Web of Science ID 000326269800024
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Structure and properties of rare earth silicates with the apatite structure at high pressure
PHYSICS AND CHEMISTRY OF MINERALS
2013; 40 (10): 817-825
View details for DOI 10.1007/s00269-013-0616-2
View details for Web of Science ID 000326056500007
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The energetics and kinetics of uranyl reduction on pyrite, hematite, and magnetite surfaces: A powder microelectrode study
GEOCHIMICA ET COSMOCHIMICA ACTA
2013; 118: 56-71
View details for DOI 10.1016/j.gca.2013.04.019
View details for Web of Science ID 000324035800004
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Sb2Se3 under pressure
SCIENTIFIC REPORTS
2013; 3
Abstract
Selected members of the A₂B₃ (A = Sb, Bi; B = Se, Te) family are topological insulators. The Sb₂Se₃ compound does not exhibit any topological properties at ambient conditions; a recent high-pressure study, however, indicated that pressure transforms Sb₂Se₃ from a band insulator into a topological insulator above ~2 GPa; in addition, three structural transitions were proposed to occur up to 25 GPa. Partly motivated by these results, we have performed x-ray diffraction and Raman spectroscopy investigations on Sb₂Se₃ under pressure up to 65 GPa. We have identified only one reversible structural transition: the initial Pnma structure transforms into a disordered cubic bcc alloy above 51 GPa. On the other hand, our high-pressure Raman study did not reproduce the previous results; we attribute the discrepancies to the effects of the different pressure transmitting media used in the high-pressure experiments. We discuss the structural behavior of Sb₂Se₃ within the A₂B₃ (A = Sb, Bi; B = Se, Te) series.
View details for DOI 10.1038/srep02665
View details for Web of Science ID 000324536400001
View details for PubMedID 24045363
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The CRAPome: a contaminant repository for affinity purification-mass spectrometry data
NATURE METHODS
2013; 10 (8): 730-?
Abstract
Affinity purification coupled with mass spectrometry (AP-MS) is a widely used approach for the identification of protein-protein interactions. However, for any given protein of interest, determining which of the identified polypeptides represent bona fide interactors versus those that are background contaminants (for example, proteins that interact with the solid-phase support, affinity reagent or epitope tag) is a challenging task. The standard approach is to identify nonspecific interactions using one or more negative-control purifications, but many small-scale AP-MS studies do not capture a complete, accurate background protein set when available controls are limited. Fortunately, negative controls are largely bait independent. Hence, aggregating negative controls from multiple AP-MS studies can increase coverage and improve the characterization of background associated with a given experimental protocol. Here we present the contaminant repository for affinity purification (the CRAPome) and describe its use for scoring protein-protein interactions. The repository (currently available for Homo sapiens and Saccharomyces cerevisiae) and computational tools are freely accessible at http://www.crapome.org/.
View details for DOI 10.1038/nmeth.2557
View details for Web of Science ID 000322453600019
View details for PubMedID 23921808
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Electronic structure and stability of hyperstoichiometric UO2+x under pressure
PHYSICAL REVIEW B
2013; 88 (2)
View details for DOI 10.1103/PhysRevB.88.024109
View details for Web of Science ID 000321838400002
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Dual Surface-Functionalized Janus Nanocomposites of Polystyrene/Fe3O4@SiO2 for Simultaneous Tumor Cell Targeting and Stimulus-Induced Drug Release
ADVANCED MATERIALS
2013; 25 (25): 3485-3489
View details for DOI 10.1002/adma.201301376
View details for Web of Science ID 000322568400016
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Ion-irradiation-induced structural transitions in orthorhombic Ln(2)TiO(5)
ACTA MATERIALIA
2013; 61 (11): 4191-4199
View details for DOI 10.1016/j.actamat.2013.03.045
View details for Web of Science ID 000320296300027
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Ferric garnet matrices for immobilization of actinides
JOURNAL OF NUCLEAR MATERIALS
2013; 436 (1-3): 1-7
View details for DOI 10.1016/j.jnucmat.2013.01.290
View details for Web of Science ID 000318391400001
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Size dependence of radiation-induced amorphization and recrystallization of synthetic nanostructured CePO4 monazite
ACTA MATERIALIA
2013; 61 (8): 2984-2992
View details for DOI 10.1016/j.actamat.2013.01.058
View details for Web of Science ID 000317797700024
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Effect of doping on the radiation response of conductive Nb-SrTiO3
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS
2013; 302: 40-47
View details for DOI 10.1016/j.nimb.2013.03.010
View details for Web of Science ID 000319956500007
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Multi-scale simulation of structural heterogeneity of swift-heavy ion tracks in complex oxides
JOURNAL OF PHYSICS-CONDENSED MATTER
2013; 25 (13)
View details for DOI 10.1088/0953-8984/25/13/135001
View details for Web of Science ID 000315992900002
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Hydrogen incorporation in crystalline zircon: Insight from ab initio calculations
AMERICAN MINERALOGIST
2013; 98 (4): 745-751
View details for DOI 10.2138/am.2013.4306
View details for Web of Science ID 000317373200025
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Np-incorporation into uranyl phases: A quantum-mechanical evaluation
JOURNAL OF NUCLEAR MATERIALS
2013; 434 (1-3): 440-450
View details for DOI 10.1016/j.jnucmat.2011.04.016
View details for Web of Science ID 000315752000057
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Charge distribution and oxygen diffusion in hyperstoichiometric uranium dioxide UO2+x (x <= 0.25)
JOURNAL OF NUCLEAR MATERIALS
2013; 434 (1-3): 422-433
View details for DOI 10.1016/j.jnucmat.2011.09.003
View details for Web of Science ID 000315752000055
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A Versatile Multicomponent Assembly via -cyclodextrin HostGuest Chemistry on Graphene for Biomedical Applications
SMALL
2013; 9 (3): 446-456
Abstract
A multi-component nanosystem based on graphene and comprising individual cyclodextrins at its surface is assembled, creating hybrid structures enabling new and important functionalities: optical imaging, drug storage, and cell targeting for medical diagnosis and treatment. These nanohybrids are part of a universal system of interchangeable units, capable of mutilple functionalities. The surface components, made of individual β-cyclodextrin molecules, are the "hosts" for functional units, which may be used as imaging agents, for anti-cancer drug delivery, and as tumor-specific ligands. Specifically, individual β-cyclodextrin (β-CD), with a known capability to host various molecules, is considered a module unit that is assembled onto graphene nanosheet (GNS). The cyclodextrin-functionalized graphene nanosheet (GNS/β-CD) enables "host-guest" chemistry between the nanohybrid and functional "payloads". The structure, composition, and morphology of the graphene nanosheet hybrid have been investigated. The nanohybrid, GNS/β-CD, is highly dispersive in various physiological solutions, reflecting the high biostability of cyclodextrin. Regarding the host capability, the nanohybrid is fully capable of selectively accommodating various biological and functional agents in a controlled fashion, including the antivirus drug amantadine, fluorescent dye [5(6)-carboxyfluorescein], and Arg-Gly-Asp (RGD) peptide-targeting ligands assisted by an adamantine linker. The loading ratio of 5(6)-carboxyfluorescein is as high as 110% with a drug concentration of 0.45 mg mL(-1). The cyclic RGD-functionalized nanohybrid exhibits remarkable targeting for HeLa cells.
View details for DOI 10.1002/smll.201201003
View details for Web of Science ID 000314547200016
View details for PubMedID 23047287
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Hydroxylation-induced surface stability of AnO(2) (An = U, Np, Pu) from first-principles
SURFACE SCIENCE
2013; 608: 180-187
View details for DOI 10.1016/j.susc.2012.10.002
View details for Web of Science ID 000312615500025
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Uranium diphosphonates templated by interlayer organic amines
JOURNAL OF SOLID STATE CHEMISTRY
2013; 198: 270-278
View details for DOI 10.1016/j.jssc.2012.10.008
View details for Web of Science ID 000314320800041
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Multilayered YSZ/GZO films with greatly enhanced ionic conduction for low temperature solid oxide fuel cells
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
2013; 15 (4): 1296-1301
View details for DOI 10.1039/c2cp42964k
View details for Web of Science ID 000312462400029
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Atomistic calculations of the thermodynamic properties of mixing for tetravalent metal dioxide solid solutions: (Zr, Th, Ce)O-2
JOURNAL OF SOLID STATE CHEMISTRY
2013; 197: 550-559
View details for DOI 10.1016/j.jssc.2012.08.033
View details for Web of Science ID 000312281000077
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Tailoring the radiation tolerance of vanadate-phosphate fluorapatites by chemical composition control
RSC ADVANCES
2013; 3 (35): 15178-15184
View details for DOI 10.1039/c3ra42246a
View details for Web of Science ID 000323132100040
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He diffusion and closure temperatures in apatite and zircon: A density functional theory investigation (vol 86, pg 228, 2012)
GEOCHIMICA ET COSMOCHIMICA ACTA
2012; 98: 202-202
View details for DOI 10.1016/j.gca.2012.08.009
View details for Web of Science ID 000311211500014
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Enhanced Energy Metabolism Contributes to the Extended Life Span of Calorie-restricted Caenorhabditis elegans
JOURNAL OF BIOLOGICAL CHEMISTRY
2012; 287 (37): 31414-31426
Abstract
Caloric restriction (CR) markedly extends life span and improves the health of a broad number of species. Energy metabolism fundamentally contributes to the beneficial effects of CR, but the underlying mechanisms that are responsible for this effect remain enigmatic. A multidisciplinary approach that involves quantitative proteomics, immunochemistry, metabolic quantification, and life span analysis was used to determine how CR, which occurs in the Caenorhabditis elegans eat-2 mutants, modifies energy metabolism of the worm, and whether the observed modifications contribute to the CR-mediated physiological responses. A switch to fatty acid metabolism as an energy source and an enhanced rate of energy metabolism by eat-2 mutant nematodes were detected. Life span analyses validated the important role of these previously unknown alterations of energy metabolism in the CR-mediated longevity of nematodes. As observed in mice, the overexpression of the gene for the nematode analog of the cytosolic form of phosphoenolpyruvate carboxykinase caused a marked extension of the life span in C. elegans, presumably by enhancing energy metabolism via an altered rate of cataplerosis of tricarboxylic acid cycle anions. We conclude that an increase, not a decrease in fuel consumption, via an accelerated oxidation of fuels in the TCA cycle is involved in life span regulation; this mechanism may be conserved across phylogeny.
View details for DOI 10.1074/jbc.M112.377275
View details for Web of Science ID 000308791300052
View details for PubMedID 22810224
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Swift heavy ion irradiation of diamond powder
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS
2012; 286: 262-265
View details for DOI 10.1016/j.nimb.2011.11.035
View details for Web of Science ID 000309488300050
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Swift heavy ion-induced amorphization of CaZrO3 perovskite
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS
2012; 286: 271-276
View details for DOI 10.1016/j.nimb.2011.12.028
View details for Web of Science ID 000309488300052
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SAXS study of ion tracks in San Carlos olivine and Durango apatite
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS
2012; 286: 243-246
View details for DOI 10.1016/j.nimb.2012.03.007
View details for Web of Science ID 000309488300046
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First principles investigation of structural, electronic, elastic and thermal properties of rare-earth-doped titanate Ln(2)TiO(5)
AIP ADVANCES
2012; 2 (3)
View details for DOI 10.1063/1.4739276
View details for Web of Science ID 000309388800014
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ZrSi formation at ZrN/Si interface induced by ballistic and ionizing radiations
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS
2012; 286: 266-270
View details for DOI 10.1016/j.nimb.2012.01.023
View details for Web of Science ID 000309488300051
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Barium uranyl diphosphonates
JOURNAL OF SOLID STATE CHEMISTRY
2012; 192: 153-160
View details for DOI 10.1016/j.jssc.2012.04.002
View details for Web of Science ID 000307028300024
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Displacive radiation-induced structural contraction in nanocrystalline ZrN
APPLIED PHYSICS LETTERS
2012; 101 (4)
View details for DOI 10.1063/1.4738772
View details for Web of Science ID 000306944700027
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Lead in zircon at the atomic scale
AMERICAN MINERALOGIST
2012; 97 (7): 1094-1102
View details for DOI 10.2138/am.2012.3993
View details for Web of Science ID 000306150600008
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Phase transition and abnormal compressibility of lanthanide silicate with the apatite structure
PHYSICAL REVIEW B
2012; 85 (21)
View details for DOI 10.1103/PhysRevB.85.214116
View details for Web of Science ID 000305529700001
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Human Biomarker Discovery and Predictive Models for Disease Progression for Idiopathic Pneumonia Syndrome Following Allogeneic Stem Cell Transplantation
MOLECULAR & CELLULAR PROTEOMICS
2012; 11 (6)
Abstract
Allogeneic hematopoietic stem cell transplantation (SCT) is the only curative therapy for many malignant and nonmalignant conditions. Idiopathic pneumonia syndrome (IPS) is a frequently fatal complication that limits successful outcomes. Preclinical models suggest that IPS represents an immune mediated attack on the lung involving elements of both the adaptive and the innate immune system. However, the etiology of IPS in humans is less well understood. To explore the disease pathway and uncover potential biomarkers of disease, we performed two separate label-free, proteomics experiments defining the plasma protein profiles of allogeneic SCT patients with IPS. Samples obtained from SCT recipients without complications served as controls. The initial discovery study, intended to explore the disease pathway in humans, identified a set of 81 IPS-associated proteins. These data revealed similarities between the known IPS pathways in mice and the condition in humans, in particular in the acute phase response. In addition, pattern recognition pathways were judged to be significant as a function of development of IPS, and from this pathway we chose the lipopolysaccaharide-binding protein (LBP) protein as a candidate molecular diagnostic for IPS, and verified its increase as a function of disease using an ELISA assay. In a separately designed study, we identified protein-based classifiers that could predict, at day 0 of SCT, patients who: 1) progress to IPS and 2) respond to cytokine neutralization therapy. Using cross-validation strategies, we built highly predictive classifier models of both disease progression and therapeutic response. In sum, data generated in this report confirm previous clinical and experimental findings, provide new insights into the pathophysiology of IPS, identify potential molecular classifiers of the condition, and uncover a set of markers potentially of interest for patient stratification as a basis for individualized therapy.
View details for DOI 10.1074/mcp.M111.015479
View details for Web of Science ID 000306408500033
View details for PubMedID 22337588
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Fukushima Daiichi: More Than One Year Later
ELEMENTS
2012; 8 (3): 181-182
View details for DOI 10.2113/gselements.8.3.181
View details for Web of Science ID 000305503300013
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He diffusion and closure temperatures in apatite and zircon: A density functional theory investigation
GEOCHIMICA ET COSMOCHIMICA ACTA
2012; 86: 228-238
View details for DOI 10.1016/j.gca.2012.03.004
View details for Web of Science ID 000303677400015
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Structural response of A(2)TiO(5) (A = La, Nd, Sm, Gd) to swift heavy ion irradiation
ACTA MATERIALIA
2012; 60 (11): 4477-4486
View details for DOI 10.1016/j.actamat.2012.05.005
View details for Web of Science ID 000306621300012
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Time to bury plutonium
NATURE
2012; 485 (7397): 167-168
View details for Web of Science ID 000303799800015
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Effect of interstitial atoms on the stability and electronic structure of Re3Zn alloy: First-principles calculations
INTERMETALLICS
2012; 24: 95-98
View details for DOI 10.1016/j.intermet.2012.01.024
View details for Web of Science ID 000302432800015
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Is nuclear fission a sustainable source of energy?
MRS BULLETIN
2012; 37 (4): 417-424
View details for DOI 10.1557/mrs.2012.6
View details for Web of Science ID 000302472500015
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Formation of nanoscale Th-coffinite
AMERICAN MINERALOGIST
2012; 97 (4): 681-693
View details for DOI 10.2138/am.2012.3951
View details for Web of Science ID 000302204400021
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Phase composition and radiation stability of matrices for isolation of REE-actinide waste
DOKLADY EARTH SCIENCES
2012; 443 (2): 526-531
View details for DOI 10.1134/S1028334X12040216
View details for Web of Science ID 000303681600021
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Unusual rigidity and ideal strength of CrB4 and MnB4
APPLIED PHYSICS LETTERS
2012; 100 (11)
View details for DOI 10.1063/1.3692777
View details for Web of Science ID 000302204900030
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Nuclear Fuel in a Reactor Accident
SCIENCE
2012; 335 (6073): 1184-1188
Abstract
Nuclear accidents that lead to melting of a reactor core create heterogeneous materials containing hundreds of radionuclides, many with short half-lives. The long-lived fission products and transuranium elements within damaged fuel remain a concern for millennia. Currently, accurate fundamental models for the prediction of release rates of radionuclides from fuel, especially in contact with water, after an accident remain limited. Relatively little is known about fuel corrosion and radionuclide release under the extreme chemical, radiation, and thermal conditions during and subsequent to a nuclear accident. We review the current understanding of nuclear fuel interactions with the environment, including studies over the relatively narrow range of geochemical, hydrological, and radiation environments relevant to geological repository performance, and discuss priorities for research needed to develop future predictive models.
View details for DOI 10.1126/science.1211285
View details for Web of Science ID 000301225100034
View details for PubMedID 22403382
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Thermal annealing of unetched fission tracks in apatite
EARTH AND PLANETARY SCIENCE LETTERS
2012; 321: 121-127
View details for DOI 10.1016/j.epsl.2012.01.008
View details for Web of Science ID 000301909200013
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Origin of the rigidity in tetragonal MB (M = Cr, Mo and W) and softening of defective WB: First-principles investigations
COMPUTATIONAL MATERIALS SCIENCE
2012; 53 (1): 460-463
View details for DOI 10.1016/j.commatsci.2011.08.033
View details for Web of Science ID 000300722900062
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Controlling the Structure and Size of Au Nanocrystals by Annealing and Ion Sputtering
LANGMUIR
2012; 28 (1): 51-55
Abstract
In situ thermal annealing was used for the first time to observe directly that Au nanoparticles, which were originally fully embedded in the near-surface region of TiO(2), can be tailored into hemispheres exposed at the surface at elevated temperature. Precise control of the size of the Au hemispheres was achieved by subsequent low-energy ion sputtering. This method can be used to control the structure and size of a wide variety of nanoparticles in a matrix where surface structure and particle size are required to obtain specific material properties.
View details for DOI 10.1012/la204016v
View details for Web of Science ID 000298904900011
View details for PubMedID 22142251
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In situ AFM and XPS Investigation of U6+ Reduction by Fe2+ on Hematite and Pyrite
ACTINIDES AND NUCLEAR ENERGY MATERIALS
2012; 1444: 243-248
View details for DOI 10.1557/opl.2012.949
View details for Web of Science ID 000310366000033
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Morphology and annealing kinetics of ion tracks in minerals
HEAVY ION ACCELERATOR SYMPOSIUM ON FUNDAMENTAL AND APPLIED SCIENCE 2012
2012; 35
View details for DOI 10.1051/epjconf/20123503003
View details for Web of Science ID 000326393700012
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Amorphization of nanocrystalline monoclinic ZrO2 by swift heavy ion irradiation
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
2012; 14 (35): 12295-12300
Abstract
Bulk ZrO(2) polymorphs generally have an extremely high amorphization tolerance upon low energy ion and swift heavy ion irradiation in which ballistic interaction and ionization radiation dominate the ion-solid interaction, respectively. However, under very high-energy irradiation by 1.33 GeV U-238, nanocrystalline (40-50 nm) monoclinic ZrO(2) can be amorphized. A computational simulation based on a thermal spike model reveals that the strong ionizing radiation from swift heavy ions with a very high electronic energy loss of 52.2 keV nm(-1) can induce transient zones with temperatures well above the ZrO(2) melting point. The extreme electronic energy loss, coupled with the high energy state of the nanostructured materials and a high thermal confinement due to the less effective heat transport within the transient hot zone, may eventually be responsible for the ionizing radiation-induced amorphization without transforming to the tetragonal polymorph. The amorphization of nanocrystalline zirconia was also confirmed by 1.69 GeV Au ion irradiation with the electronic energy loss of 40 keV nm(-1). These results suggest that highly radiation tolerant materials in bulk forms, such as ZrO(2), may be radiation sensitive with the reduced length scale down to the nano-metered regime upon irradiation above a threshold value of electronic energy loss.
View details for DOI 10.1039/c2cp41553d
View details for Web of Science ID 000307648700031
View details for PubMedID 22858872
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Nanosized Rutile (TiO2) Thin Film upon Ion Irradiation and Thermal Annealing
JOURNAL OF PHYSICAL CHEMISTRY C
2011; 115 (46): 22755-22760
View details for DOI 10.1021/jp2056283
View details for Web of Science ID 000297001000009
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Electronic structure and energetics of tetragonal SrCuO2 and its high-pressure superstructure phase
JOURNAL OF PHYSICS-CONDENSED MATTER
2011; 23 (46)
Abstract
First-principles calculations have been used to investigate the electronic structure and energetics of the simple tetragonal SrCuO₂ (P4=mmm) and its high-pressure tetragonal superstructure (P4=mmm). Based on the calculations, the high-pressure phase is metastable as compared with the low pressure tetragonal phase, with an energy difference of 0.13 eV per SrCuO₂ formula unit. The energy barrier to the transition from the superstructure to the simple tetragonal structure is 0.24 eV at 7 GPa; thus, high temperatures are required to synthesize the latter. Among the possible structural configurations resulting from the partially occupied oxygen site in the superstructure phase, the most stable structure has a space group PN4m2, reduced from that of the simple tetragonal structure P4=mmm. The detailed analysis of the electronic band structures of the simple tetragonal and superstructure phases suggests that the out-of-plane buckling of the O atoms in the superstructure leads to significant decrease in the O p-Cu d orbital overlap, allowing the energy of the system to be lowered, which is necessary for the structural stability. An understanding of the electronic structure and energetics of the high-pressure superstructure phase and its relation to the simple tetragonal phase provides a basis for exploring the physical properties of the infinite layer, high-TC superconductor.
View details for DOI 10.1088/0953-8984/23/46/465503
View details for Web of Science ID 000296795400013
View details for PubMedID 22056857
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Phase stability of some actinides with brannerite structure at high pressures
JOURNAL OF SOLID STATE CHEMISTRY
2011; 184 (11): 2834-2839
View details for DOI 10.1016/j.jssc.2011.08.022
View details for Web of Science ID 000296404200002
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Trace metal nanoparticles in pyrite
ORE GEOLOGY REVIEWS
2011; 42 (1): 32-46
View details for DOI 10.1016/j.oregeorev.2011.03.003
View details for Web of Science ID 000297781900003
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Role of iron in the incorporation of uranium in ferric garnet matrices
PHYSICAL REVIEW B
2011; 84 (15)
View details for DOI 10.1103/PhysRevB.84.155128
View details for Web of Science ID 000296290000005
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Structural changes of (K,Gd)(2)Ta2O7 pyrochlore at high pressure
JOURNAL OF SOLID STATE CHEMISTRY
2011; 184 (9): 2329-2332
View details for DOI 10.1016/j.jssc.2011.06.040
View details for Web of Science ID 000294835700003
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Actinides and radiation effects: impact on the back-end of the nuclear fuel cycle
MINERALOGICAL MAGAZINE
2011; 75 (4): 2359-2377
View details for DOI 10.1180/minmag.2011.075.4.2359
View details for Web of Science ID 000295214200002
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Thermodynamic properties of ThxU1-xO2 (0 < x < 1) based on quantum-mechanical calculations and Monte-Carlo simulations
JOURNAL OF NUCLEAR MATERIALS
2011; 412 (1): 13-21
View details for DOI 10.1016/j.jnucmat.2011.01.017
View details for Web of Science ID 000291171400003
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First-principles investigation of Ca-3(Ti, Zr, Hf, Sn)(2)Fe2SiO12 garnet structure for incorporation of actinides
PHYSICAL REVIEW B
2011; 83 (15)
View details for DOI 10.1103/PhysRevB.83.155123
View details for Web of Science ID 000292150800002
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Phase Transformation of Nanosized ZrO2 upon Thermal Annealing and Intense Radiation
JOURNAL OF PHYSICAL CHEMISTRY C
2011; 115 (15): 7193-7201
View details for DOI 10.1021/jp109558s
View details for Web of Science ID 000289403200006
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Effects of Ionizing Radiation and Temperature on Uranyl Silicates: Soddyite (UO2)(2)(SiO4)(H2O)(2) and Uranophane Ca(UO2)(2)(SiO3OH)(2)center dot 5H(2)O
ENVIRONMENTAL SCIENCE & TECHNOLOGY
2011; 45 (6): 2510-2515
Abstract
The stability of soddyite under electron irradiation has been studied over the temperature range of 25-300 °C. At room temperature, soddyite undergoes a crystalline-to-amorphous transformation (amorphization) at a total dose of 6.38 × 10(8) Gy. The electron beam irradiation results suggest that the soddyite structure is susceptible to radiation-induced nanocrystallization of UO(2). The temperature dependence of amorphization dose increases linearly up to 300 °C. A thermogravimetric and calorimetric analysis (TGA-DSC) combined with X-ray diffraction (XRD) indicates that soddyite retains its water groups up to 400 °C, followed by the collapse of the structure. Based on thermal analysis of uranophane, the removal of some water groups at relatively low temperatures provokes the collapse of the uranophane structure. This structural change appears to be the reason for the increase of amorphization dose at 140 °C. According to the results obtained, radiation field of a nuclear waste repository, rather than temperature effects, may cause changes in the crystallinity of soddyite and affect its stability during long-term storage.
View details for DOI 10.1021/es1041496
View details for Web of Science ID 000288146200067
View details for PubMedID 21319815
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Annealing kinetics of latent particle tracks in Durango apatite
PHYSICAL REVIEW B
2011; 83 (6)
View details for DOI 10.1103/PhysRevB.83.064116
View details for Web of Science ID 000287796000009
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Energetic stability, structural transition, and thermodynamic properties of ZnSnO3
APPLIED PHYSICS LETTERS
2011; 98 (9)
View details for DOI 10.1063/1.3562013
View details for Web of Science ID 000288026700026
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Thermal annealing mechanisms of latent fission tracks: Apatite vs. zircon
EARTH AND PLANETARY SCIENCE LETTERS
2011; 302 (1-2): 227-235
View details for DOI 10.1016/j.epsl.2010.12.016
View details for Web of Science ID 000287555800021
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Energetics and concentration of defects in Gd2Ti2O7 and Gd2Zr2O7 pyrochlore at high pressure
ACTA MATERIALIA
2011; 59 (4): 1607-1618
View details for DOI 10.1016/j.actamat.2010.11.025
View details for Web of Science ID 000287265100029
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Safe management of actinides in the nuclear fuel cycle: Role of mineralogy
COMPTES RENDUS GEOSCIENCE
2011; 343 (2-3): 219-229
View details for DOI 10.1016/j.crte.2010.09.003
View details for Web of Science ID 000289880800012
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Role of arsenian pyrite in hydrothermal ore deposits: A history and update
GREAT BASIN EVOLUTION AND METALLOGENY, VOLS I AND II
2011: 233-245
View details for Web of Science ID 000293810500013
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Irradiation of synthetic garnet by heavy ions and alpha-decay of Cm-244
JOURNAL OF NUCLEAR MATERIALS
2010; 407 (3): 137-142
View details for DOI 10.1016/j.jnucmat.2010.09.051
View details for Web of Science ID 000285859200001
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OH species, U ions, and CO/CO2 in thermally annealed metamict zircon (ZrSiO4)
AMERICAN MINERALOGIST
2010; 95 (11-12): 1717-1724
View details for DOI 10.2138/am.2010.3567
View details for Web of Science ID 000284195100015
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Pressure-induced structural transformations in lanthanide titanates: La2TiO5 and Nd2TiO5
JOURNAL OF SOLID STATE CHEMISTRY
2010; 183 (11): 2636-2643
View details for DOI 10.1016/j.jssc.2010.09.014
View details for Web of Science ID 000284179800020
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The Association Between Community Physical Activity Settings and Youth Physical Activity, Obesity, and Body Mass Index
JOURNAL OF ADOLESCENT HEALTH
2010; 47 (5): 496-503
Abstract
This study examined the association between the level of physical activity (PA) friendliness of the built environment and adolescent PA and body mass index using a national sample of youth and data collected from the communities where they reside.Data on height, weight, and PA were taken from annual nationally representative cross-sectional Monitoring the Future surveys of 8th and 10th graders in schools, from 2001 through 2003. Measures of safety, outdoor and commercial PA settings, and urban sprawl were constructed using data collected from the communities in which the students reside. Multilevel models were run and controlled for youth and community demographic and socioeconomic characteristics.Increased levels of physical disorder were associated with decreased PA and higher weight. A greater number of commercial PA facilities was associated with increased PA. More compact communities were associated with lower weight and less sports participation.It is important to explore these associations to help guide future development patterns and land use policies to create more active neighborhoods.
View details for DOI 10.1016/j.jadohealth.2010.03.017
View details for Web of Science ID 000283263100012
View details for PubMedID 20970085
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Time-response relationship of nano and micro particle induced lung inflammation. Quartz as reference compound
HUMAN & EXPERIMENTAL TOXICOLOGY
2010; 29 (11): 915-933
Abstract
An increasing number of engineered particles, including nanoparticles, are being manufactured, increasing the need for simple low-dose toxicological screening methods. This study aimed to investigate the kinetics of biomarkers related to acute and sub-chronic particle-induced lung inflammation of quartz. Mice were intratracheal instilled with 50 µg of microsized or nanosized quartz. Acute inflammation was assessed 1, 2, 4, 8, 16 or 48 hours post exposure, whereas sub-chronic inflammation was investigated 3 months after exposure. Markers of acute inflammation in the bronchoalveolar lavage fluid (BALF) were neutrophils (PMN), tumor necrosis factor-alpha (TNF-α), interleukin (IL)-1β, macrophage inflammatory protein-2 (MIP-2), keratinocyte derived chemokine (KC) and total protein, which were all close to maximum 16 hours post instillation. No major differences were seen in the time-response profiles of nano- and micro-sized particles. The potency of the two samples cannot be compared; during the milling process, a substantial part of the quartz was converted to amorphous silica and contaminated with corundum. For screening, BALF PMN, either TNF-α or IL-1β at 16 hours post instillation may be useful. At 3 months post instillation, KC, PMN and macrophages were elevated. Histology showed no interstitial inflammation three months post instillation. For screening of sub-chronic effects, KC, PMN, macrophages and histopathology is considered sufficient.
View details for DOI 10.1177/0960327110363329
View details for Web of Science ID 000283054100003
View details for PubMedID 20237177
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Environmental impact of the nuclear fuel cycle: Fate of actinides
MRS BULLETIN
2010; 35 (11): 859-866
View details for Web of Science ID 000284861500011
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Porous fission fragment tracks in fluorapatite
PHYSICAL REVIEW B
2010; 82 (14)
View details for DOI 10.1103/PhysRevB.82.144109
View details for Web of Science ID 000283048800004
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Review of A(2)B(2)O(7) pyrochlore response to irradiation and pressure
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS
2010; 268 (19): 2951-2959
View details for DOI 10.1016/j.nimb.2010.05.016
View details for Web of Science ID 000282301100024
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Fluorescent, Superparamagnetic Nanospheres for Drug Storage, Targeting, and Imaging: A Multifunctional Nanocarrier System for Cancer Diagnosis and Treatment
ACS NANO
2010; 4 (9): 5398-5404
Abstract
For early cancer diagnosis and treatment, a nanocarrier system is designed and developed with key components uniquely structured at nanoscale according to medical requirements. For imaging, quantum dots with emissions in the near-infrared range (∼800 nm) are conjugated onto the surface of a nanocomposite consisting of a spherical polystyrene matrix (∼150 nm) and the internally embedded, high fraction of superparamagnetic Fe(3)O(4) nanoparticles (∼10 nm). For drug storage, the chemotherapeutic agent paclitaxel (PTX) is loaded onto the surfaces of these composite multifunctional nanocarriers by using a layer of biodegradable poly(lactic-co-glycolic acid) (PLGA). A cell-based cytotoxicity assay is employed to verify successful loading of pharmacologically active drug. Cell viability of human, metastatic PC3mm2 prostate cancer cells is assessed in the presence and absence of various multifunctional nanocarrier populations using the MTT assay. PTX-loaded composite nanocarriers are synthesized by conjugating anti-prostate specific membrane antigen (anti-PSMA) for targeting. Specific detection studies of anti-PSMA-conjugated nanocarrier binding activity in LNCaP prostate cancer cells are carried out. LNCaP cells are targeted successfully in vitro by the conjugation of anti-PSMA on the nanocarrier surfaces. To further explore targeting, the nanocarriers conjugated with anti-PSMA are intravenously injected into tumor-bearing nude mice. Substantial differences in fluorescent signals are observed ex vivo between tumor regions treated with the targeted nanocarrier system and the nontargeted nanocarrier system, indicating considerable targeting effects due to anti-PSMA functionalization of the nanocarriers.
View details for DOI 10.1021/nn101000e
View details for Web of Science ID 000282121000055
View details for PubMedID 20707381
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Quantum-mechanical evaluation of Np-incorporation into studtite
AMERICAN MINERALOGIST
2010; 95 (8-9): 1151-1160
View details for DOI 10.2138/am.2010.3493
View details for Web of Science ID 000281220900004
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Amorphization of rare earth aluminate garnets under ion irradiation and decay of Cm-244 admixture
GEOLOGY OF ORE DEPOSITS
2010; 52 (4): 267-278
View details for DOI 10.1134/S1075701510040021
View details for Web of Science ID 000281396300002
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Intrinsic Structural Disorder and Radiation Response of Nanocrystalline Gd-2(Ti0.65Zr0.35)(2)O-7 Pyrochlore
JOURNAL OF PHYSICAL CHEMISTRY C
2010; 114 (27): 11810-11815
View details for DOI 10.1021/jp103371j
View details for Web of Science ID 000279507900019
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Nanoscale phase transitions under extreme conditions within an ion track
JOURNAL OF MATERIALS RESEARCH
2010; 25 (7): 1344-1351
View details for DOI 10.1557/JMR.2010.0180
View details for Web of Science ID 000279475500018
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Pressure-Induced Disordering and Anomalous Lattice Expansion in La2Zr2O7 Pyrochlore
PHYSICAL REVIEW LETTERS
2010; 105 (1)
Abstract
Pressure-induced cation and anion disordering in La2Zr2O7 pyrochlore is quantitatively analyzed by Rietveld refinement of in situ x-ray diffraction patterns, Raman, and infrared measurements. An anomalous lattice expansion and obvious change of the pressure dependence of the vibrational modes occur at ∼10 GPa. The pressure-induced water incorporation in the La2Zr2O7 pyrochlore structure may be related to a previously noted photoelectrochemical effect.
View details for DOI 10.1103/PhysRevLett.105.015503
View details for Web of Science ID 000279392600001
View details for PubMedID 20867461
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Trace-metal nanoparticles in pyrite
GEOCHIMICA ET COSMOCHIMICA ACTA
2010; 74 (12): A216-A216
View details for Web of Science ID 000283941400681
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The influence of muscovite and orthoclase on the precipitation of CaCO3 polymorphs
GEOCHIMICA ET COSMOCHIMICA ACTA
2010; 74 (12): A424-A424
View details for Web of Science ID 000283941401223
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Pb-incorporation into synthetic Pb-doped zircon
GEOCHIMICA ET COSMOCHIMICA ACTA
2010; 74 (12): A526-A526
View details for Web of Science ID 000283941401622
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Electronic structure of Ti, Zr, Hf and Sn containing garnets - Materials for immobilization of actinides
GEOCHIMICA ET COSMOCHIMICA ACTA
2010; 74 (12): A845-A845
View details for Web of Science ID 000283941402394
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Critical processes in the release and transport of radionuclides in the near-field
GEOCHIMICA ET COSMOCHIMICA ACTA
2010; 74 (12): A274-A274
View details for Web of Science ID 000283941400798
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Ab initio calculations of He diffusion in apatite
GEOCHIMICA ET COSMOCHIMICA ACTA
2010; 74 (12): A77-A77
View details for Web of Science ID 000283941401336
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U and Th mineral evolution
GEOCHIMICA ET COSMOCHIMICA ACTA
2010; 74 (12): A389-A389
View details for Web of Science ID 000283941401154
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Increased stability of nanocrystals of Gd-2(Ti0.65Zr0.35)(2)O-7 pyrochlore at high pressure
JOURNAL OF ALLOYS AND COMPOUNDS
2010; 494 (1-2): 34-39
View details for DOI 10.1016/j.jallcom.2010.01.036
View details for Web of Science ID 000276532300013
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Precipitation and alteration of coffinite (USiO4 center dot nH(2)O) in the presence of apatite
EUROPEAN JOURNAL OF MINERALOGY
2010; 22 (1): 75-88
View details for DOI 10.1127/0935-1221/2010/0022-1990
View details for Web of Science ID 000275598900008
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Simulation of thermodynamic mixing properties of actinide-containing zircon solid solutions
AMERICAN MINERALOGIST
2010; 95 (2-3): 229-241
View details for DOI 10.2138/am.2010.3318
View details for Web of Science ID 000274509000003
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Synthetic Minerals with the Pyrochlore and Garnet Structures for Immobilization of Actinide-Containing Wastes
GEOCHEMISTRY INTERNATIONAL
2010; 48 (1): 1-14
View details for DOI 10.1134/S0016702910010015
View details for Web of Science ID 000275527600001
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FLUORESCENT SUPER PARAMAGNETIC NANOPARTICLES FOR MEDICAL DIAGNOSIS AND TREATMENT
INEC: 2010 3RD INTERNATIONAL NANOELECTRONICS CONFERENCE, VOLS 1 AND 2
2010: 350-351
View details for Web of Science ID 000282026500176
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Zirconate pyrochlores under high pressure
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
2010; 12 (39): 12472-12477
Abstract
Ab initio total-energy calculations and X-ray diffraction measurements have been combined to study the phase stability of zirconate pyrochlores (A(2)Zr(2)O(7); A = La, Nd and Sm) under pressures up to 50 GPa. Phase transformations to the defect-cotunnite structure are theoretically predicted at pressures of 22, 20 and 18 GPa, in excellent agreement with the experimentally determined values of 21, 22 and 18 GPa for La(2)Zr(2)O(7), Nd(2)Zr(2)O(7) and Sm(2)Zr(2)O(7), respectively. Analysis of the elastic properties indicates that elastic anisotropy may be one of the driving forces for the pressure-induced cubic-to-noncubic phase transformation.
View details for DOI 10.1039/c0cp00278j
View details for Web of Science ID 000282643900015
View details for PubMedID 20721363
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Political Pressure's Effect on Repository Sites Response
SCIENCE
2009; 326 (5959): 1480-1480
View details for Web of Science ID 000272623600015
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ELEMENTS' FIFTH ANNIVERSARY
ELEMENTS
2009; 5 (6): 343-343
View details for Web of Science ID 000273415400002
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Conjugation of quantum dots and Fe3O4 on carbon nanotubes for medical diagnosis and treatment
APPLIED PHYSICS LETTERS
2009; 95 (22)
View details for DOI 10.1063/1.3268469
View details for Web of Science ID 000272627600083
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High-pressure phase transitions of ScPO4 and YPO4
PHYSICAL REVIEW B
2009; 80 (18)
View details for DOI 10.1103/PhysRevB.80.184114
View details for Web of Science ID 000272310900049
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Combined high pressure and heavy-ion irradiation: a novel approach
JOURNAL OF SYNCHROTRON RADIATION
2009; 16: 773-777
Abstract
Swift heavy-ion irradiations of a wide variety of materials have been used to modify and manipulate the properties of solids at the nanoscale. Recently, these high-energy irradiations have been successfully combined with high-pressure experiments. Based on results obtained for zircon (ZrSiO(4)), this paper introduces this new experimental approach involving diamond anvil cells and large ion-accelerator facilities. This technique provides a wide spectrum of geoscience applications from nanoscale simulations of fission-track formation under crustal conditions to phase transitions of radiation-damaged minerals resulting from meteorite impact.
View details for DOI 10.1107/S0909049509034384
View details for Web of Science ID 000271091000013
View details for PubMedID 19844013
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Chemical and structural characterization of As immobilization by nanoparticles of mackinawite (FeSm)
CHEMICAL GEOLOGY
2009; 268 (1-2): 116-125
View details for DOI 10.1016/j.chemgeo.2009.08.003
View details for Web of Science ID 000271367200014
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Nanoscale manipulation of the properties of solids at high pressure with relativistic heavy ions
NATURE MATERIALS
2009; 8 (10): 793-797
Abstract
High-pressure and high-temperature phases show unusual physical and chemical properties, but they are often difficult to 'quench' to ambient conditions. Here, we present a new approach, using bombardment with very high-energy, heavy ions accelerated to relativistic velocities, to stabilize a high-pressure phase. In this case, Gd(2)Zr(2)O(7), pressurized in a diamond-anvil cell up to 40 GPa, was irradiated with 20 GeV xenon or 45 GeV uranium ions, and the (previously unquenchable) cubic high-pressure phase was recovered after release of pressure. Transmission electron microscopy revealed a radiation-induced, nanocrystalline texture. Quantum-mechanical calculations confirm that the surface energy at the nanoscale is the cause of the remarkable stabilization of the high-pressure phase. The combined use of high pressure and high-energy ion irradiation provides a new means for manipulating and stabilizing new materials to ambient conditions that otherwise could not be recovered.
View details for DOI 10.1038/NMAT2528
View details for Web of Science ID 000270075600012
View details for PubMedID 19734884
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Evolution of uranium and thorium minerals
AMERICAN MINERALOGIST
2009; 94 (10): 1293-1311
View details for DOI 10.2138/am.2009.3208
View details for Web of Science ID 000270599200001
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Synthesis and characterization of coffinite
JOURNAL OF NUCLEAR MATERIALS
2009; 393 (3): 449-458
View details for DOI 10.1016/j.jnucmat.2009.06.030
View details for Web of Science ID 000270626500008
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Response of synthetic coffinite to energetic ion beam irradiation
JOURNAL OF NUCLEAR MATERIALS
2009; 393 (3): 481-486
View details for DOI 10.1016/j.jnucmat.2009.07.005
View details for Web of Science ID 000270626500012
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High-Pressure Response of Zirconia Nanoparticles with an Alumina Shell
JOURNAL OF PHYSICAL CHEMISTRY C
2009; 113 (33): 14658-14662
View details for DOI 10.1021/jp904144y
View details for Web of Science ID 000268907500014
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Decoupled geochemical behavior of As and Cu in hydrothermal systems
GEOLOGY
2009; 37 (8): 707-710
View details for DOI 10.1130/G25781A.1
View details for Web of Science ID 000268498600009
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Propagation of ripples on pyrochlore induced by ion beam bombardment
PHYSICAL REVIEW B
2009; 80 (8)
View details for DOI 10.1103/PhysRevB.80.085413
View details for Web of Science ID 000269639300092
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Nuclear Waste Management in the United States-Starting Over
SCIENCE
2009; 325 (5937): 151-152
View details for DOI 10.1126/science.1174594
View details for Web of Science ID 000267802000028
View details for PubMedID 19589986
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Radiation Response of Nanocrystalline Rutile (TiO2)
MICROSCOPY AND MICROANALYSIS
2009; 15: 1366-1367
View details for DOI 10.1017/S1431927609092939
View details for Web of Science ID 000208119100674
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Effects of electron and ion irradiation on the annealing behavior of fission tracks and the microstructure of fluorapatite
MICROSCOPY AND MICROANALYSIS
2009; 15: 1354-1355
View details for DOI 10.1017/S1431927609092186
View details for Web of Science ID 000208119100668
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Radiation Response of Nanostructured Pyrochlore and Zirconia
MICROSCOPY AND MICROANALYSIS
2009; 15: 1338-1339
View details for DOI 10.1017/S1431927609093222
View details for Web of Science ID 000208119100660
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Structural transitions and electron transfer in coffinite, USiO4, at high pressure
AMERICAN MINERALOGIST
2009; 94 (7): 916-920
View details for DOI 10.2138/am.2009.3111
View details for Web of Science ID 000268149400006
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Ion beam-induced amorphous-to-tetragonal phase transformation and grain growth of nanocrystalline zirconia
NANOTECHNOLOGY
2009; 20 (24)
Abstract
Nanocrystalline zirconia has recently attracted extensive research interest due to its unique mechanical, thermal and electrical properties as compared with bulk zirconia counterparts, and it is of particular importance for controlling the phase stability of different polymorphs (amorphous, cubic, tetragonal and monoclinic phases) in different size regimes. In this work, we performed ion beam bombardments on bilayers (amorphous and cubic) of nano-zirconia using 1 MeV Kr2+ irradiation. Transmission electron microscopy (TEM) analysis reveals that amorphous zirconia transforms to a tetragonal structure under irradiation at room temperature, suggesting that the tetragonal phase is more energetically favorable under these conditions. The final grain size of the tetragonal zirconia can be controlled by irradiation conditions. A slower kinetics in the grain growth from cubic nanocrystalline zirconia was found as compared with that for the tetragonal grains recrystallized from the amorphous layer. The radiation-induced nanograins of tetragonal ZrO2 are stable at ambient conditions and maintain their physical integrity over a long period of time after irradiation. These results demonstrated that ion beam methods provide the means to control the phase stability and structure of zirconia polymorphs.
View details for DOI 10.1088/0957-4484/20/24/245303
View details for Web of Science ID 000266436500009
View details for PubMedID 19468161
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Enhanced radiation resistance of nanocrystalline pyrochlore Gd-2(Ti0.65Zr0.35)(2)O-7
APPLIED PHYSICS LETTERS
2009; 94 (24)
View details for DOI 10.1063/1.3155855
View details for Web of Science ID 000267166600067
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Fluorescent Polystyrene-Fe3O4 Composite Nanospheres for In Vivo Imaging and Hyperthermia
ADVANCED MATERIALS
2009; 21 (21): 2170-?
View details for DOI 10.1002/adma.200803159
View details for Web of Science ID 000267308800006
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Groundwater nanoparticles in the far-field at the Nevada Test Site
GEOCHIMICA ET COSMOCHIMICA ACTA
2009; 73 (13): A1362-A1362
View details for Web of Science ID 000267229903412
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Single-ion tracks in Gd2Zr2-xTixO7 pyrochlores irradiated with swift heavy ions
PHYSICAL REVIEW B
2009; 79 (22)
View details for DOI 10.1103/PhysRevB.79.224105
View details for Web of Science ID 000267699300030
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Liquid-like phase formation in Gd2Zr2O7 by extremely ionizing irradiation
JOURNAL OF APPLIED PHYSICS
2009; 105 (11)
View details for DOI 10.1063/1.3124370
View details for Web of Science ID 000267053200043
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MgO-pyrochlore composite as an inert matrix fuel: Neutronic and thermal characteristics
JOURNAL OF NUCLEAR MATERIALS
2009; 389 (3): 341-350
View details for DOI 10.1016/j.jnucmat.2009.01.241
View details for Web of Science ID 000266510900001
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Response of strontium titanate to ion and electron irradiation
JOURNAL OF NUCLEAR MATERIALS
2009; 389 (2): 303-310
View details for DOI 10.1016/j.jnucmat.2009.02.014
View details for Web of Science ID 000266510200016
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Crystal chemistry and radiation-induced amorphization of P-coffinite from the natural fission reactor at Bangombe, Gabon
AMERICAN MINERALOGIST
2009; 94 (5-6): 827-836
View details for DOI 10.2138/am.2009.3114
View details for Web of Science ID 000266078400020
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Pb+ irradiation of synthetic zircon (ZrSiO4): Infrared spectroscopic investigation-Reply
AMERICAN MINERALOGIST
2009; 94 (5-6): 856-858
View details for DOI 10.2138/am.2009.542
View details for Web of Science ID 000266078400026
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Structural modifications of Gd2Zr2-xTixO7 pyrochlore induced by swift heavy ions: Disordering and amorphization
JOURNAL OF MATERIALS RESEARCH
2009; 24 (4): 1322-1334
View details for DOI 10.1557/JMR.2009.0151
View details for Web of Science ID 000267207700004
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Source-to-receptor pathways of anthropogenic PM2.5 in Detroit, Michigan: Comparison of two inhalation exposure studies
ATMOSPHERIC ENVIRONMENT
2009; 43 (10): 1805-1813
View details for DOI 10.1016/j.atmosenv.2008.12.035
View details for Web of Science ID 000264348500012
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Groundwater Nanoparticles in the Far-Field at the Nevada Test Site: Mechanism for Radionuclide Transport
ENVIRONMENTAL SCIENCE & TECHNOLOGY
2009; 43 (5): 1293-1298
Abstract
Colloid-like nanoparticles in groundwater have been shown to facilitate migration of several radionuclides: (239,240)Pu, 137Cs, (152,154, 155)Eu, and 60Co. However, the exact type of nanoparticle and the speciation of the associated radionuclides has remained unknown. We have investigated nanoparticles sampled from the far-field at the Nevada Test Site, Nevada, utilizing advanced electron microscopytechniques, including high-angle annular dark-field scanning TEM (HAADF-STEM). Fissiogenic elements: Cs, rare earth elements (REE), activation elements: Co; and actinides: U and Th, were detected. Cesium is associated with U-forming cesium uranate with a Cs/U atomic ratio of approximately 0.12. Light REEs and Th are associated with phosphates, silicates, or apatite. Cobalt occurs as a metallic aggregate, associated with Cr, Fe, Ni, and +/-Mo. Uranyl minerals; Na-boltwoodite and oxide hydrates are also present as colloids. Because of these chemical associations with nanoscale particles, in the size range <100 nm, these particles may facilitate transport, and a variety of trace nanoscale phases may be responsible for the migration of fissiogenic and actinide elements in groundwater. To accurately model the transport of these contaminants, predictive transport models should include consideration of nanoparticle-facilitated transport.
View details for DOI 10.1021/es802181t
View details for Web of Science ID 000263758600013
View details for PubMedID 19350893
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In Situ TEM of Radiation Effects in Complex Ceramics
MICROSCOPY RESEARCH AND TECHNIQUE
2009; 72 (3): 165-181
Abstract
In situ transmission electron microscopy (TEM) has been extensively applied to study radiation effects in a wide variety of materials, such as metals, ceramics and semiconductors and is an indispensable tool in obtaining a fundamental understanding of energetic beam-matter interactions, damage events, and materials' behavior under intense radiation environments. In this article, in situ TEM observations of radiation effects in complex ceramics (e.g., oxides, silicates, and phosphates) subjected to energetic ion and electron irradiations have been summarized with a focus on irradiation-induced microstructural evolution, changes in microchemistry, and the formation of nanostructures. New results for in situ TEM observation of radiation effects in pyrochlore, A(2)B(2)O(7), and zircon, ZrSiO(4), subjected to multiple beam irradiations are presented, and the effects of simultaneous irradiations of alpha-decay and beta-decay on the microstructural evolution of potential nuclear waste forms are discussed. Furthermore, in situ TEM results of radiation effects in a sodium borosilicate glass subjected to electron-beam exposure are introduced to highlight the important applications of advanced analytical TEM techniques, including Z-contrast imaging, energy filtered TEM (EFTEM), and electron energy loss spectroscopy (EELS), in studying radiation effects in materials microstructural evolution and microchemical changes. By combining ex situ TEM and advanced analytical TEM techniques with in situ TEM observations under energetic beam irradiations, one can obtain invaluable information on the phase stability and response behaviors of materials under a wide range of irradiation conditions.
View details for DOI 10.1002/jemt.20669
View details for Web of Science ID 000264238500006
View details for PubMedID 19130508
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UO2 corrosion in an iron waste package
JOURNAL OF NUCLEAR MATERIALS
2009; 384 (2): 130-139
View details for DOI 10.1016/j.jnucmat.2008.11.007
View details for Web of Science ID 000263665300008
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Surface charge induced Stark effect on luminescence of quantum dots conjugated on functionalized carbon nanotubes
CHEMICAL PHYSICS LETTERS
2009; 469 (1-3): 149-152
View details for DOI 10.1016/j.cplett.2008.12.065
View details for Web of Science ID 000262801400030
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Stability of uranium (VI) peroxide hydrates under ionizing radiation
AMERICAN MINERALOGIST
2009; 94 (2-3): 229-235
View details for DOI 10.2138/am.2009.2908
View details for Web of Science ID 000263490300004
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Nanoscale "liquid" inclusions of As-Fe-S in arsenian pyrite
AMERICAN MINERALOGIST
2009; 94 (2-3): 391-394
View details for DOI 10.2138/am.2009.3116
View details for Web of Science ID 000263490300023
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LOST IN TRANSLATION
ELEMENTS
2009; 5 (1): 5-6
View details for Web of Science ID 000264469200005
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Thermodynamic Properties of Actinide-Oxide Solid-Solutions
MATERIALS FOR FUTURE FUSION AND FISSION TECHNOLOGIES
2009; 1125: 95-100
View details for Web of Science ID 000271830900015
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UO2 Corrosion in an Iron Waste Package
SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XXXII
2009; 1124: 105-110
View details for Web of Science ID 000270898900010
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Radiation-Stability of Smectite
ENVIRONMENTAL SCIENCE & TECHNOLOGY
2008; 42 (22): 8407-8411
Abstract
The safety assessment of geological repositories for high-level nuclear waste and spent nuclear fuel requires an understanding of the response of materials to high temperatures and intense radiation fields. Clays, such as smectite, have been proposed as backfill material around waste packages, but their response to intense radiation from short-lived fission products and alpha decay of sorbed actinides remains poorly understood. Cumulative doses may amorphize clays and may alter their properties of sorption, swelling, or water retention. We describe the amorphization of smectites induced by electron and heavy ion irradiations to simulate ionizing radiation and alpha recoil nuclei, respectively. A new "bell-shaped" evolution of the amorphization dose with temperature has been determined. The maximum dose for amorphization occurs at about 300-400 degrees C, showing that temperature-induced dehydroxylation enhances amorphization. The exact shape of the bell-shaped curves depends on the interlayer cation. At ambient temperature, ionizing radiation and alpha-decay events do not show the same efficiency. The former results in amorphization at doses between 10(10)-10(11) Gy which are greater than the total radiation dose expected for radioactive waste over 10(6) years. In contrast, alpha-decay events amorphize clays at doses as low as 0.13-0.16 displacements per atom, i.e. doses consistent with nuclear waste accumulated over approximately 1000 yrs. However, the limited penetration of alpha particles and recoil nuclei, in the 100 nm - 20 microm range, will minimize damage. Clays will not be amorphized unless the waste package is breached and released actinides are heavily sorbed onto the clay overpack.
View details for DOI 10.1021/es800766b
View details for Web of Science ID 000260921400038
View details for PubMedID 19068825
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Fission tracks simulated by swift heavy ions at crustal pressures and temperatures
EARTH AND PLANETARY SCIENCE LETTERS
2008; 274 (3-4): 355-358
View details for DOI 10.1016/j.epsl.2008.07.039
View details for Web of Science ID 000262153200009
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Enhanced thermal stability of carbon nanotubes by plasma surface modification in Al2O3 composites
JOURNAL OF APPLIED PHYSICS
2008; 104 (7)
View details for DOI 10.1063/1.2985915
View details for Web of Science ID 000260125500120
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Pressure-induced zircon-type to scheelite-type phase transitions in YbPO4 and LuPO4
JOURNAL OF SOLID STATE CHEMISTRY
2008; 181 (10): 2633-2638
View details for DOI 10.1016/j.jssc.2008.06.042
View details for Web of Science ID 000260441000012
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In vivo imaging and drug storage by quantum-dot-conjugated carbon nanotubes
ADVANCED FUNCTIONAL MATERIALS
2008; 18 (17): 2489-2497
View details for DOI 10.1002/adfm.200800406
View details for Web of Science ID 000259521600005
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Pb+ irradiation of synthetic zircon (ZrSiO4): Infrared spectroscopic investigation
AMERICAN MINERALOGIST
2008; 93 (8-9): 1418-1423
View details for DOI 10.2138/am.2008.2733
View details for Web of Science ID 000258589100023
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Museums are not attics
ELEMENTS
2008; 4 (4): 221-222
View details for Web of Science ID 000259746300002
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Structural phase transitions of cubic Gd2O3 at high pressures
PHYSICAL REVIEW B
2008; 78 (6)
View details for DOI 10.1103/PhysRevB.78.064114
View details for Web of Science ID 000259264900029
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Coffinite and ningyoite from the natural nuclear reactor at Bangombe, Gabon
GEOCHIMICA ET COSMOCHIMICA ACTA
2008; 72 (12): A968-A968
View details for Web of Science ID 000257301602461
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Actinide adsorption onto hematite (001) surface
GEOCHIMICA ET COSMOCHIMICA ACTA
2008; 72 (12): A864-A864
View details for Web of Science ID 000257301602253
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Decoupling of Cu and As in magmatic-hydrothermal systems: Evidence from the pueblo viejo Au-Ag deposit, Dominican republic
GEOCHIMICA ET COSMOCHIMICA ACTA
2008; 72 (12): A206-A206
View details for Web of Science ID 000257301600419
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Radiation effects in zircon and apatite
GEOCHIMICA ET COSMOCHIMICA ACTA
2008; 72 (12): A248-A248
View details for Web of Science ID 000257301600503
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Gold deposition onto arsenian pyrite
GEOCHIMICA ET COSMOCHIMICA ACTA
2008; 72 (12): A788-A788
View details for Web of Science ID 000257301602100
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Horizontally aligned Cu5Si polycrystalline nanorods on Si
APPLIED PHYSICS LETTERS
2008; 92 (25)
View details for DOI 10.1063/1.2952770
View details for Web of Science ID 000257231200064
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A proposed new type of arsenian pyrite: Composition, nanostructure and geological significance
GEOCHIMICA ET COSMOCHIMICA ACTA
2008; 72 (12): 2919-2933
View details for DOI 10.1016/j.gca.2008.03.014
View details for Web of Science ID 000256674800013
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The chemical stability of coffinite, USiO4 center dot nH(2)O; 0 < n < 2, associated with organic matter: A case study from Grants uranium region, New Mexico, USA
CHEMICAL GEOLOGY
2008; 251 (1-4): 33-49
View details for DOI 10.1016/j.chemgeo.2008.02.009
View details for Web of Science ID 000257011700004
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Fabrication of nano-/micro-patterns on iron phosphate glass surfaces by focused energetic beams
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS
2008; 266 (12-13): 3133-3137
View details for DOI 10.1016/j.nimb.2008.03.173
View details for Web of Science ID 000257721300101
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Structural and bonding properties of stannate pyrochlores: A density functional theory investigation
COMPUTATIONAL MATERIALS SCIENCE
2008; 42 (4): 653-658
View details for DOI 10.1016/j.commatsci.2007.09.019
View details for Web of Science ID 000256777300016
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Irradiation-induced stabilization of zircon (ZrSiO4) at high pressure
EARTH AND PLANETARY SCIENCE LETTERS
2008; 269 (1-2): 291-295
View details for DOI 10.1016/j.epsl.2008.02.027
View details for Web of Science ID 000256705300026
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Self-assembly of well-aligned 3C-SiC ripples by focused ion beam
APPLIED PHYSICS LETTERS
2008; 92 (19)
View details for DOI 10.1063/1.2927473
View details for Web of Science ID 000256564200078
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Corrosion of UO2 and ThO2: A quantum-mechanical investigation
JOURNAL OF NUCLEAR MATERIALS
2008; 375 (3): 290-310
View details for DOI 10.1016/j.jnucmat.2007.12.007
View details for Web of Science ID 000256327400002
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Quantum dot conjugated hydroxylapatite nanoparticles for in vivo imaging
NANOTECHNOLOGY
2008; 19 (17)
Abstract
Hydroxylapatite (HA) nanoparticles were conjugated with quantum dots (QDs) for in vivo imaging. The surface structures of HA nanoparticles with conjugated quantum dots (HA-QD) were studied by transmission electron microscopy (TEM) and laser fluorescent spectroscopy. The TEM data showed that the quantum dots were well conjugated on the HA nanoparticle surfaces. The laser fluorescent spectroscopy results indicated that the HA-QD exhibited promising luminescent emission in vitro. The initial in vivo experiments revealed clear images of HA-QD from the hypodermic injected area at the emission of 600 nm. Furthermore, the optimized in vivo images of HA-QD with near-infrared emission at 800 nm were visualized after intravenous injection. These luminescent HA-QD nanoparticles may find important applications as biodegradable substrates for biomarkers and in drug delivery.
View details for DOI 10.1088/0957-4484/19/17/175102
View details for Web of Science ID 000254329700002
View details for PubMedID 21825660
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Nuclear fuel cycle: Environmental impact
MRS BULLETIN
2008; 33 (4): 338-340
View details for Web of Science ID 000254373000016
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Micro-Raman and micro-infrared spectroscopic studies of Pb- and Au-irradiated ZrSiO4: Optical properties, structural damage, and amorphization
PHYSICAL REVIEW B
2008; 77 (14)
View details for DOI 10.1103/PhysRevB.77.144110
View details for Web of Science ID 000255457300020
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Phase stability and pressure dependence of defect formation in Gd2Ti2O7 and Gd2Zr2O7 pyrochlores
PHYSICAL REVIEW LETTERS
2008; 100 (4)
Abstract
We report dramatically different behaviors between isostructural Gd2Ti2O7 and Gd2Zr2O7 pyrochlore at pressures up to 44 GPa, in which the substitution of Ti for Zr significantly increases structural stability. Upon release of pressure, the Gd2Ti2O7 becomes amorphous. In contrast, the high-pressure phase of Gd2Zr2O7 transforms to a disordered defect-fluorite structure. First-principle calculations for both compositions revealed that the response of pyrochlore to high pressure is controlled by the intrinsic energetics of defect formation.
View details for DOI 10.1103/PhysRevLett.100.045503
View details for Web of Science ID 000252863400055
View details for PubMedID 18352296
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Spectroscopic ellipsometry characterization of the optical properties and thermal stability of ZrO2 films made by ion-beam assisted deposition
APPLIED PHYSICS LETTERS
2008; 92 (1)
View details for DOI 10.1063/1.2811955
View details for Web of Science ID 000252284200055
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High pressure phase transitions and compressibilities of Er2Zr2O7 and Ho2Zr2O7
APPLIED PHYSICS LETTERS
2008; 92 (1)
View details for DOI 10.1063/1.2830832
View details for Web of Science ID 000252284200047
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Np-incorporation into K-boltwoodite
SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XXXI
2008; 1107: 455-463
View details for Web of Science ID 000257618800054
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Effects of ionizing radiation on the hollandite structure-type: Ba0.85Cs0.26Al1.35Fe0.77Ti5.90O16
AMERICAN MINERALOGIST
2008; 93 (1): 241-247
View details for DOI 10.2138/am.2008.2563
View details for Web of Science ID 000252377400028
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Waste package corrosion studies using small mockup experiments
SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XXXI
2008; 1107: 519-526
View details for Web of Science ID 000257618800061
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Effects of plasma surface modification on interfacial behaviors and mechanical properties of carbon nanotube-Al2O3 nanocomposites
APPLIED PHYSICS LETTERS
2007; 91 (26)
View details for DOI 10.1063/1.2824865
View details for Web of Science ID 000251987400011
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High-pressure structural changes in the Gd2Zr2O7 pyrochlore
PHYSICAL REVIEW B
2007; 76 (21)
View details for DOI 10.1103/PhysRevB.76.214104
View details for Web of Science ID 000251986100025
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Quantum-dot-activated luminescent carbon nanotubes via a nano scale surface functionalization for in vivo imaging
ADVANCED MATERIALS
2007; 19 (22): 4033-?
View details for DOI 10.1002/adma.200700035
View details for Web of Science ID 000251383900050
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Dissolution of radiation-damaged zircon in lateritic soils
AMERICAN MINERALOGIST
2007; 92 (11-12): 1978-1989
View details for DOI 10.2138/am.2007.2514
View details for Web of Science ID 000251101000023
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Fate of trace elements during alteration of uraninite in a hydrothermal vein-type U-deposit from Marshall Pass, Colorado, USA
GEOCHIMICA ET COSMOCHIMICA ACTA
2007; 71 (20): 4954-4973
View details for DOI 10.1016/i.gca.2007.08.008
View details for Web of Science ID 000250948100010
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Alteration of UO2+x under oxidizing conditions, Marshall Pass, Colorado, USA
JOURNAL OF ALLOYS AND COMPOUNDS
2007; 444: 584-589
View details for DOI 10.1016/j.jallcom.2007.02.095
View details for Web of Science ID 000249996400114
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Ion beam irradiation of U-, Th- and Ce-doped pyrochlores
JOURNAL OF ALLOYS AND COMPOUNDS
2007; 444: 429-433
View details for DOI 10.1016/j.jallcom.2006.10.133
View details for Web of Science ID 000249996400083
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First-principles study of electronic properties of La2Hf2O7 and Gd2Hf2O7
JOURNAL OF APPLIED PHYSICS
2007; 102 (6)
View details for DOI 10.1063/1.2779262
View details for Web of Science ID 000249787200057
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Theoretical investigation of structural, energetic and electronic properties of titanate pyrochlores
JOURNAL OF PHYSICS-CONDENSED MATTER
2007; 19 (34)
View details for DOI 10.1088/0953-8984/19/34/346203
View details for Web of Science ID 000248186000005
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Arsenic uptake and release on sulfide nanoparticles
GEOCHIMICA ET COSMOCHIMICA ACTA
2007; 71 (15): A833-A833
View details for Web of Science ID 000248789902038
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Adsorption energy trends on UO2 and ThO2 surfaces
GEOCHIMICA ET COSMOCHIMICA ACTA
2007; 71 (15): A945-A945
View details for Web of Science ID 000248789902262
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Structural distortions and phase transformations in Sm2Zr2O7 pyrochlore at high pressures
CHEMICAL PHYSICS LETTERS
2007; 441 (4-6): 216-220
View details for DOI 10.1016/j.cplett.2007.05.018
View details for Web of Science ID 000247985400010
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Low-temperature anisotropic diffusion of helium in zircon: Implications for zircon (U-Th)/He thermochronometry
GEOCHIMICA ET COSMOCHIMICA ACTA
2007; 71 (12): 3119-3130
View details for DOI 10.1016/j.gca.2007.03.033
View details for Web of Science ID 000247216400015
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A science-based approach to understanding waste form durability in open and closed nuclear fuel cycles
JOURNAL OF NUCLEAR MATERIALS
2007; 362 (2-3): 395-401
View details for DOI 10.1016/j.jnucmat.2007.01.085
View details for Web of Science ID 000246895400036
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Nuclear materials and materials for fusion - Proceedings of the E-MRS 2006 Spring Meeting: Symposium N on Nuclear Materials and Materials for Fusion - Nice, France - 29 May-2 June 2006 - Editorial note
JOURNAL OF NUCLEAR MATERIALS
2007; 362 (2-3): VII-VIII
View details for DOI 10.1016/j.jnucmat.2007.01.016
View details for Web of Science ID 000246895400001
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Ion beam irradiation of lanthanum and thorium-doped yttrium titanates
JOURNAL OF NUCLEAR MATERIALS
2007; 362 (2-3): 438-444
View details for DOI 10.1016/j.jnucmat.2007.01.097
View details for Web of Science ID 000246895400042
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Behavior of implanted strontium in yttria-stabilized zirconia
APPLIED PHYSICS LETTERS
2007; 90 (17)
View details for DOI 10.1063/1.2713127
View details for Web of Science ID 000246568600040
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Growth and surface characterization of sputter-deposited molybdenum oxide thin films
APPLIED SURFACE SCIENCE
2007; 253 (12): 5368-5374
View details for DOI 10.1016/j.apsusc.2006.12.012
View details for Web of Science ID 000246092900031
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Low-energy Ar+ ion-beam-induced amorphization and chemical modification of potassium titanyl arsenate (001) crystal surfaces
JOURNAL OF PHYSICAL CHEMISTRY C
2007; 111 (6): 2702-2708
View details for DOI 10.1021/jp0671392
View details for Web of Science ID 000245005700050
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Structural change of layered perovskite La2Ti2O7 at high pressures
JOURNAL OF SOLID STATE CHEMISTRY
2007; 180 (2): 571-576
View details for DOI 10.1016/j.jssc.2006.11.022
View details for Web of Science ID 000244280700022
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Summertime carbonaceous aerosols collected in the marine boundary layer of the Arctic Ocean
JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES
2007; 112 (D2)
View details for DOI 10.1029/2006JD007247
View details for Web of Science ID 000243876100002
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Enhancement of paramagnetic defects in yttria stabilized zirconia implanted by Cs ion irradiation
JOURNAL OF ALLOYS AND COMPOUNDS
2007; 429 (1-2): 25-28
View details for DOI 10.1016/j.jallcom.2006.03.089
View details for Web of Science ID 000244673100005
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Behavior of Si and C atoms in ion amorphized SiC
JOURNAL OF APPLIED PHYSICS
2007; 101 (2)
View details for DOI 10.1063/1.2431941
View details for Web of Science ID 000243890800050
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Radiation damage and alteration of zircon from a 3.3 Ga porphyritic granite from the Jack Hills, Western Australia
CHEMICAL GEOLOGY
2007; 236 (1-2): 92-111
View details for DOI 10.1016/j.chemgeo.2006.09.003
View details for Web of Science ID 000243678100007
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Materials science - Displaced by radiation
NATURE
2007; 445 (7124): 161-162
View details for DOI 10.1038/445161a
View details for Web of Science ID 000243384300039
View details for PubMedID 17215837
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Trace element immobilization by uranyl minerals in granite-hosted uranium ores: Evidences from the Xiazhuang ore field of Guangdong province, China
RADIOCHIMICA ACTA
2007; 95 (1): 25-32
View details for DOI 10.1524/ract.2007.95.1.25
View details for Web of Science ID 000243786700004
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A science-based approach to understanding waste form durability in open and closed nuclear fuel cycles
SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XXX
2007; 985: 227-234
View details for Web of Science ID 000250805600035
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Np incorporation into uranyl alteration phases: A quantum mechanical approach
SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XXX
2007; 985: 407-412
View details for Web of Science ID 000250805600061
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Perrhenate and pertechnetate Behavior on iron and sulfur-bearing compounds
SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XXX
2007; 985: 425-430
View details for Web of Science ID 000250805600064
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Ceramic matrices for plutonium disposition
PROGRESS IN NUCLEAR ENERGY
2007; 49 (8): 635-643
View details for DOI 10.1016/j.pnucene.2007.02.003
View details for Web of Science ID 000252419200010
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Computational investigation of the formation of hyperstoichiometric uranium dioxide (UO2+x)
SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XXX
2007; 985: 89-94
View details for Web of Science ID 000250805600014
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A modular model of the crystal structure of the pyrochlore-murataite polysomatic series
CRYSTALLOGRAPHY REPORTS
2007; 52 (1): 37-46
View details for DOI 10.1134/S1063774507010051
View details for Web of Science ID 000243863400005
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Alteration of coffinite (USiO4) under reducing and oxidizing conditions
SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XXX
2007; 985: 47-52
View details for Web of Science ID 000250805600007
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Surface modification of a Ti-Al-Zr alloy by niobium ion implantation
SURFACE & COATINGS TECHNOLOGY
2006; 201 (6): 3756-3760
View details for DOI 10.1016/j.surfcoat.2006.09.042
View details for Web of Science ID 000244831800218
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The crystal structure of dehydrated wyartite, Ca(CO3)[U5+(U6+O2)(2)O-4(OH)] (H2O)(3)
CANADIAN MINERALOGIST
2006; 44: 1379-1385
View details for Web of Science ID 000244165400007
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Thermal behavior of metal nanoparticles in geologic materials
GEOLOGY
2006; 34 (12): 1033-1036
View details for Web of Science ID 000242630000011
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Spent nuclear fuel
ELEMENTS
2006; 2 (6): 343-349
View details for Web of Science ID 000243253500005
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The nuclear fuel cycle: A role for mineralogy and geochemistry
ELEMENTS
2006; 2 (6): 331-334
View details for Web of Science ID 000243253500003
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Quantum mechanical vs. empirical potential modeling of uranium dioxide (UO2) surfaces: (111), (110), and (100)
AMERICAN MINERALOGIST
2006; 91 (11-12): 1761-1772
View details for DOI 10.2138/am.2006.2180
View details for Web of Science ID 000242318100005
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Pressure-induced structural transitions and phase decomposition in the Cd2Nb2O7 pyrochlore
PHYSICAL REVIEW B
2006; 74 (17)
View details for DOI 10.1103/PhysRevB.74.174116
View details for Web of Science ID 000242409000054
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Luminescent hydroxylapatite nanoparticles by surface functionalization
APPLIED PHYSICS LETTERS
2006; 89 (18)
View details for DOI 10.1063/1.2374687
View details for Web of Science ID 000241757500098
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Colloid transport of plutonium in the far-field of the Mayak Production Association, Russia
SCIENCE
2006; 314 (5799): 638-641
Abstract
Sorption of actinides, particularly plutonium, onto submicrometer-sized colloids increases their mobility, but these plutonium colloids are difficult to detect in the far-field. We identified actinides on colloids in the groundwater from the Mayak Production Association, Urals, Russia; at the source, the plutonium activity is approximately 1000 becquerels per liter. Plutonium activities are still 0.16 becquerels per liter at a distance of 3 kilometers, where 70 to 90 mole percent of the plutonium is sorbed onto colloids, confirming that colloids are responsible for the long-distance transport of plutonium. Nano-secondary ion mass spectrometry elemental maps reveal that amorphous iron oxide colloids adsorb Pu(IV) hydroxides or carbonates along with uranium carbonates.
View details for DOI 10.1126/science.1131307
View details for Web of Science ID 000241557800044
View details for PubMedID 17068260
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Refinement of the crystal structure of billietite, Ba [(UO2)(6) O-4 (OH)(6)] (H2O)(8)
CANADIAN MINERALOGIST
2006; 44: 1197-1205
View details for Web of Science ID 000241882100016
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Acceptance of the Dana Medal of the Mineralogical Society of America for 2006
AMERICAN MINERALOGIST
2006; 91 (10): 1712-1713
View details for DOI 10.2138/am.2006.472
View details for Web of Science ID 000241312700028
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Radiation-induced effects in pyrochlores and nanoscale materials engineering
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS
2006; 250: 128-136
View details for DOI 10.1016/j.nimb.2006.04.157
View details for Web of Science ID 000239883500026
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XPS and optical studies of Xe+-implanted and annealed YSZ single crystals
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS
2006; 250: 382-385
View details for DOI 10.1016/j.nimb.2006.04.142
View details for Web of Science ID 000239883500077
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Irradiation-induced nanostructures in cadmium niobate pyrochlores
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS
2006; 250: 188-191
View details for DOI 10.1016/j.nimb.2006.04.106
View details for Web of Science ID 000239883500037
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Perrhenate and pertechnetate behavior on iron and sulfur-bearing compounds
GEOCHIMICA ET COSMOCHIMICA ACTA
2006; 70 (18): A16-A16
View details for DOI 10.1016/j.gca.2006.06.045
View details for Web of Science ID 000241374200043
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Adsorbed U(VI) surface species on muscovite identified by laser fluorescence spectroscopy and transmission electron microscopy
ENVIRONMENTAL SCIENCE & TECHNOLOGY
2006; 40 (15): 4646-4652
Abstract
Time-resolved laser-induced fluorescence spectroscopy (TRLFS) and high-angle annular dark-field scanning transmission electron microscopy (HAADF-STEM) were applied to investigate the species of uranyl(VI) adsorbed onto muscovite platelets and muscovite suspensions (grain size: 63-200 microm). TRLFS provided evidence for the presence of two adsorbed uranium(VI) surface species on edge-surfaces of muscovite. The two species showed different positions of the fluorescence emission bands and different fluorescence lifetimes indicating a different coordination environment for the two species. HAADF-STEM revealed that nanoclusters of an amorphous uranium phase were attached to the edge-surfaces of muscovite powder during batch sorption experiments. These U-nanoclusters were not observed on {00/} cleavage planes of the muscovite. The surface species with the shorter fluorescence lifetimes are interpreted as truly adsorbed bidentate surface complexes, in which the U(VI) binds to aluminol groups of edge-surfaces. The surface species with the longer fluorescence lifetimes are interpreted to be an amorphous U(VI) condensate or nanosized clusters of polynuclear uranyl(VI) surface species with a particle diameter of 1 to 2 nm. Depending on the size of these clusters the fluorescence lifetimes vary; i.e., the larger the nanosized clusters, the longer is the fluorescence lifetime.
View details for DOI 10.1021/es0525071
View details for Web of Science ID 000239437600026
View details for PubMedID 16913119
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The mechanisms of reduction of hexavalent chromium by green rust sodium sulphate: Formation of Cr-goethite
GEOCHIMICA ET COSMOCHIMICA ACTA
2006; 70 (14): 3582-3592
View details for DOI 10.1016/j.gca.2006.02.017
View details for Web of Science ID 000239252200006
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Direct evidence of N aggregation and diffusion in Au+ irradiated GaN
APPLIED PHYSICS LETTERS
2006; 89 (2)
View details for DOI 10.1063/1.2219418
View details for Web of Science ID 000239793100021
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Two planets - Which future?
ELEMENTS
2006; 2 (3): 131-131
View details for Web of Science ID 000238244000001
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Structural stability and phase transitions in WO3 thin films
JOURNAL OF PHYSICAL CHEMISTRY B
2006; 110 (21): 10430-10435
Abstract
Tungsten oxide (WO3) thin films have been produced by KrF excimer laser (lambda = 248 nm) ablation of bulk ceramic WO3 targets. The crystal structure, surface morphology, chemical composition, and structural stability of the WO3 thin films have been studied in detail. Characterization of freshly grown WO3 thin films has been performed using X-ray diffraction (XRD), atomic force microscopy (AFM), energy-dispersive X-ray spectroscopy (EDX), Raman spectroscopy (RS), transmission electron microscopy (TEM), and selected area electron diffraction (SAED) measurements. The results indicate that the freshly grown WO3 thin films are nearly stoichiometric and well crystallized as monoclinic WO3. The surface morphology of the resulting WO3 thin film has grains of approximately 60 nm in size with a root-mean-square (rms) surface roughness of 10 nm. The phase transformations in the WO3 thin films were investigated by annealing in the TEM column at 30-500 degrees C. The phase transitions in the WO3 thin films occur in sequence as the temperature is increased: monoclinic --> orthorhombic --> hexagonal. Distortion and tilting of the WO6 octahedra occurs with the phase transitions and significantly affects the electronic properties and, hence, the electrochemical device applications of WO3.
View details for DOI 10.1021/jp056664i
View details for Web of Science ID 000237844900034
View details for PubMedID 16722749
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Patterning metallic nanostructures by ion-beam-induced dewetting and Rayleigh instability
NANO LETTERS
2006; 6 (5): 1047-1052
View details for DOI 10.1021/nl060492z
View details for Web of Science ID 000237592900031
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Deposition of ultrathin rare-earth doped Y2O3 phosphor films on alumina nanoparticles
NANOTECHNOLOGY
2006; 17 (5): 1351-1354
View details for DOI 10.1088/0957-4484/17/5/030
View details for Web of Science ID 000236496400038
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Simultaneous formation of surface ripples and metallic nanodots induced by phase decomposition and focused ion beam patterning
APPLIED PHYSICS LETTERS
2006; 88 (9)
View details for DOI 10.1063/1.2181203
View details for Web of Science ID 000235736300078
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Effect of structure and thermodynamic stability on the response of lanthanide stannate-pyrochlores to ion beam irradiation
JOURNAL OF PHYSICAL CHEMISTRY B
2006; 110 (5): 2343-2350
Abstract
The lanthanide stannates, Ln2Sn2O7, Ln=La-Lu and Y, have the isometric pyrochlore structure, A2B2O7, and their structural properties have been refined by Rietveld analysis of powder neutron and synchrotron X-ray diffraction data. In this study, the enthalpies of formation of selected stannate pyrochlores, Ln=La, Nd, Sm, Eu, Dy, and Yb, were measured by high-temperature oxide melt solution calorimetry. Their radiation response was determined by 1 MeV Kr2+ ion irradiation combined with in situ TEM observation over the temperature range of 25 to 1000 K. The enthalpy of formation from binary oxides of stannate pyrochlores became more endothermic (from -145 to -40 kJ/mol) as the size of the lanthanide in the A-site decreases. A more exothermic trend of the enthalpy of formation was observed in stannate pyrochlores with larger lanthanide ions, particularly La, possibly as a result of increased covalency in the Sn-O bond. In contrast to lanthanide titanate pyrochlores, Ln2Ti2O7, that are generally susceptible to radiation-induced amorphization and zirconate pyrochlores, Ln2Zr2O7, that are generally resistant to radiation-induced amorphization, the lanthanide stannate pyrochlores show a much greater variation in their response to ion irradiation. La, Nd, and Gd stannates experience the radiation-induced transformation to the aperiodic state, and the critical amorphization temperatures are approximately 960, 700, and 350 K, respectively. Y and Er stannate pyrochlores cannot be amorphized by ion beam irradiation, even at 25 K, and instead disorder to a defect fluorite structure. Comparison of the calorimetric and ion irradiation data for titanate, zirconate, and stannate pyrochlores reveals a strong correlation among subtle changes in crystal structure with changing composition, the energetics of the disordering process, and the temperature above which the material can no longer be amorphized. In summary, as the structure approaches the ideal, ordered pyrochlore structure, radiation-induced amorphization is more easily attained. This is consistent with an increasingly exothermic trend in the enthalpies of formation of pyrochlores from the oxides, that is, the greater the thermochemical stability of the pyrochlore structure, the more likely it will be amorphized upon radiation damage rather than recover to a disordered fluorite structure.
View details for DOI 10.1021/jp055266c
View details for Web of Science ID 000235284300057
View details for PubMedID 16471823
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Luminescent carbon nanotubes by surface functionalization
ADVANCED MATERIALS
2006; 18 (2): 189-?
View details for DOI 10.1002/adma.200501680
View details for Web of Science ID 000234993700008
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Formation of V2O3 nanocrystals by thermal reduction of V2O5 thin films
SOLID STATE COMMUNICATIONS
2006; 137 (12): 645-649
View details for DOI 10.1016/j.ssc.2006.01.026
View details for Web of Science ID 000236570000003
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The fate of the epsilon phase (Mo-Ru-Pd-Tc-Rh) in the UO2 of the Oklo natural fission reactors
RADIOCHIMICA ACTA
2006; 94 (9-11): 749-753
View details for DOI 10.1524/ract.2006.94.9.749
View details for Web of Science ID 000245133700038
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TEM characterization of Au nano-particles in TiO2 single crystals by ion implantation
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS
2006; 242 (1-2): 152-156
View details for DOI 10.1016/j.nimb.2005.08.115
View details for Web of Science ID 000236225200041
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Ion-beam implantation and cross-sectional TEM characterization of Gd2Ti2O7 pyrochlore
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS
2006; 242 (1-2): 448-451
View details for DOI 10.1016/j.nimb.2005.08.060
View details for Web of Science ID 000236225200122
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Radiation-induced decomposition of U(VI) alteration phases of UO2
SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XXIX
2006; 932: 465-472
View details for Web of Science ID 000239003700054
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How does surface modification aid in the dispersion of carbon nanofibers?
JOURNAL OF PHYSICAL CHEMISTRY B
2005; 109 (49): 23351-23357
Abstract
Small-angle light scattering is used to assess the dispersion behavior of vapor-grown carbon nanofibers suspended in water. These data provide the first insights into the mechanism by which surface treatment promotes dispersion. Both acid-treated and untreated nanofibers exhibit hierarchical morphology consisting of small-scale aggregates (small bundles) that agglomerate to form fractal clusters that eventually precipitate. Although the morphology of the aggregates and agglomerates is nearly independent of surface treatment, their time evolution is quite different. The time evolution of the small-scale bundles is studied by extracting the size distribution from the angle-dependence of the scattered intensity, using the maximum entropy method in conjunction with a simplified tube form factor. The bundles consist of multiple tubes possibly aggregated side-by-side. Acid oxidation has little effect on this bundle morphology. Rather acid treatment inhibits agglomeration of the bundles. The time evolution of agglomeration is followed by fitting the scattering data to a generalized fractal model. Agglomerates appear immediately after cessation of sonication for untreated fibers but only after hours for treated fibers. Eventually, however, both systems precipitate.
View details for DOI 10.1021/jp055129f
View details for Web of Science ID 000233864300040
View details for PubMedID 16375306
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Ion beam implantation and cross-sectional TEM studies of lanthanide titanate pyrochlore single crystals
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS
2005; 241 (1-4): 365-371
View details for DOI 10.1016/j.nimb.2005.07.043
View details for Web of Science ID 000234260000079
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Radiation-induced decomposition of U(VI) phases to nanocrystals of UO2
EARTH AND PLANETARY SCIENCE LETTERS
2005; 240 (2): 521-528
View details for DOI 10.1016/j.epsl.2005.09.034
View details for Web of Science ID 000234470100026
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The nuclear fuel cycle versus the carbon cycle
CANADIAN MINERALOGIST
2005; 43: 2099-2116
View details for Web of Science ID 000236090800012
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The application of HRTEM techniques and nanosims to chemically and isotopically characterize Geobacter sulfurreducens surfaces
CANADIAN MINERALOGIST
2005; 43: 1631-1641
View details for Web of Science ID 000235226100016
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Ion-induced damage accumulation and electron-beam-enhanced recrystallization in SrTiO3
PHYSICAL REVIEW B
2005; 72 (9)
View details for DOI 10.1103/PhysRevB.72.094112
View details for Web of Science ID 000232228500041
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Electron microscopy investigation of structural transformations in tungsten oxide (WO3) thin films
PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE
2005; 202 (10): R108-R110
View details for DOI 10.1002/pssa.200521076
View details for Web of Science ID 000231512100003
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Cadmium nanowire formation induced by ion irradiation
ADVANCED MATERIALS
2005; 17 (13): 1602-?
View details for DOI 10.1002/adma.200500118
View details for Web of Science ID 000230368300004
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Solubility of gold in arsenian pyrite
GEOCHIMICA ET COSMOCHIMICA ACTA
2005; 69 (11): 2781-2796
View details for DOI 10.1016/j.gca.2005.01.011
View details for Web of Science ID 000229759400007
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Ion-beam-induced amorphization and order-disorder transition in the murataite structure
JOURNAL OF APPLIED PHYSICS
2005; 97 (11)
View details for DOI 10.1063/1.1926394
View details for Web of Science ID 000229804700052
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In situ observation of thermodynamic size effects on melting of natural gold nanoparticles
GEOCHIMICA ET COSMOCHIMICA ACTA
2005; 69 (10): A513-A513
View details for Web of Science ID 000229399701408
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The corrosion of UO2 versus ThO2: A quantum mechanical investigation
GEOCHIMICA ET COSMOCHIMICA ACTA
2005; 69 (10): A411-A411
View details for Web of Science ID 000229399701208
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The epsilon phase in the UO2 of the Oklo natural reactors
GEOCHIMICA ET COSMOCHIMICA ACTA
2005; 69 (10): A477-A477
View details for Web of Science ID 000229399701339
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Natural uranium getters in near surface environments at the Nopal I deposit, Pena Blanca, Mexico
GEOCHIMICA ET COSMOCHIMICA ACTA
2005; 69 (10): A474-A474
View details for Web of Science ID 000229399701332
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Characterization of Nd, Te and U isotope ratios in UO2 using SIMS
GEOCHIMICA ET COSMOCHIMICA ACTA
2005; 69 (10): A378-A378
View details for Web of Science ID 000229399701144
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Spent nuclear fuel: Research needs
GEOCHIMICA ET COSMOCHIMICA ACTA
2005; 69 (10): A473-A473
View details for Web of Science ID 000229399701331
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Uraninite recrystallization and Pb loss in the Oklo and Bangombe natural fission reactors, Gabon
GEOCHIMICA ET COSMOCHIMICA ACTA
2005; 69 (6): 1589-1606
View details for DOI 10.1016/j.gca.2004.07.013
View details for Web of Science ID 000228126900016
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Magnetic alignment of carbon nanofibers in polymer composites and anisotropy of mechanical properties
JOURNAL OF APPLIED PHYSICS
2005; 97 (6)
View details for DOI 10.1063/1.1861143
View details for Web of Science ID 000227767700079
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Geochemical fixation of rare earth elements into secondary minerals in sandstones beneath a natural fission reactor at Bangombe, Gabon
GEOCHIMICA ET COSMOCHIMICA ACTA
2005; 69 (3): 685-694
View details for DOI 10.1016/j.gca.2004.07.019
View details for Web of Science ID 000226680300014
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Radiation effects in ferrate garnet
JOURNAL OF NUCLEAR MATERIALS
2005; 336 (2-3): 251-260
View details for DOI 10.1016/j.nucmat.2004.09.020
View details for Web of Science ID 000226817700016
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Effects of electron irradiation in nuclear waste glasses
PHILOSOPHICAL MAGAZINE
2005; 85 (4-7): 597-608
View details for DOI 10.1080/02678370412331320080
View details for Web of Science ID 000226689800020
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Plasma deposition of thin carbonfluorine films on aligned carbon nanotube
APPLIED PHYSICS LETTERS
2005; 86 (4)
View details for DOI 10.1063/1.1846957
View details for Web of Science ID 000226761400065
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Plutonium and "minor' actinides: safe sequestration
EARTH AND PLANETARY SCIENCE LETTERS
2005; 229 (3-4): 165-181
View details for DOI 10.1016/j.epsl.2004.11.017
View details for Web of Science ID 000226571200001
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Electron irradiation induced transformation of (Pb5Ca5)(VO4)(6)F-2 apatite to CaVO3 perovskite
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
2005; 88 (1): 184-190
View details for DOI 10.1111/j.1551-2916.2004.00002.x
View details for Web of Science ID 000227158100030
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Microscale characterization of uranium(VI) silicate solids and associated neptunium(V)
RADIOCHIMICA ACTA
2005; 93 (5): 265-272
View details for Web of Science ID 000229784100003
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Thermally induced phase decomposition and nanocrystal formation in murataite ceramics
JOURNAL OF MATERIALS CHEMISTRY
2005; 15 (6): 709-714
View details for DOI 10.1039/b411845f
View details for Web of Science ID 000226703500012
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Radiation and thermal effects on porous and layer structured materials as getters of radionuclides
CURRENT OPINION IN SOLID STATE & MATERIALS SCIENCE
2004; 8 (6): 405-418
View details for DOI 10.1016/j.cossms.2005.04.002
View details for Web of Science ID 000233470700004
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Comment on "Probabilistic risk analysis for a high-level radioactive waste repository" by B. L. Cohen in Risk analysis, volume 23, 909-915
RISK ANALYSIS
2004; 24 (6): 1417-1419
View details for Web of Science ID 000226235800001
View details for PubMedID 15660599
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Nanoscale occurrence of Pb in an Archean zircon
GEOCHIMICA ET COSMOCHIMICA ACTA
2004; 68 (22): 4679-4686
View details for DOI 10.1016/j.gca.2004.04.018
View details for Web of Science ID 000224980000012
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TEM observation of oxide scale formed on a Ti-Al-Zr alloy oxidized at 360 degrees C in alkaline steam
PHILOSOPHICAL MAGAZINE LETTERS
2004; 84 (11): 705-712
View details for DOI 10.1080/09500830500040163
View details for Web of Science ID 000228432300005
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"Invisible" gold revealed: Direct imaging of gold nanoparticles in a Carlin-type deposit
AMERICAN MINERALOGIST
2004; 89 (10): 1359-1366
View details for Web of Science ID 000224509500002
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Probing cation antisite disorder in Gd2Ti2O7 pyrochlore by site-specific near-edge x-ray-absorption fine structure and x-ray photoelectron spectroscopy
PHYSICAL REVIEW B
2004; 70 (10)
View details for DOI 10.1103/PhysRevB.70.100101
View details for Web of Science ID 000224209300001
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Applications of near-infrared FT-Raman spectroscopy in metamict and annealed zircon: oxidation state of U ions
PHYSICS AND CHEMISTRY OF MINERALS
2004; 31 (7): 405-414
View details for DOI 10.1007/s00269-004-0399-6
View details for Web of Science ID 000224527500002
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First-principles calculation of defect-formation energies in the Y-2(Ti,Sn,Zr)(2)O-7 pyrochlore
PHYSICAL REVIEW B
2004; 70 (5)
View details for DOI 10.1103/PhysRevB.70.054110
View details for Web of Science ID 000223716100037
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Microstructural evolution and nanocrystal formation in Pb+-implanted ZrSiO4 single crystals (vol 94, pg 5695, 2003)
JOURNAL OF APPLIED PHYSICS
2004; 96 (1): 937-937
View details for DOI 10.1063/1.1753069
View details for Web of Science ID 000222093300151
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Nuclear waste disposal-pyrochlore (A(2)B(2)O(7)): Nuclear waste form for the immobilization of plutonium and "minor" actinides
JOURNAL OF APPLIED PHYSICS
2004; 95 (11): 5949-5971
View details for DOI 10.1063/1.1707213
View details for Web of Science ID 000221657300001
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Cr(VI) reduction by green rust
GEOCHIMICA ET COSMOCHIMICA ACTA
2004; 68 (11): A138-A138
View details for Web of Science ID 000221923400220
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Quantum mechanical versus empirical potential modeling of UO2 surface-water interactions
GEOCHIMICA ET COSMOCHIMICA ACTA
2004; 68 (11): A119-A119
View details for Web of Science ID 000221923400181
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The environmental impact of the nuclear fuel cycle: Climate change, nuclear waste & nuclear weapons
GEOCHIMICA ET COSMOCHIMICA ACTA
2004; 68 (11): A13-A13
View details for Web of Science ID 000221923400005
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Ion beam irradiation in La2Zr2O7-Ce2Zr2O7 pyrochlore
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS
2004; 218: 236-243
View details for DOI 10.1016/j.nimb.2004.01.007
View details for Web of Science ID 000221561000040
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Electron irradiation induced phase separation in a sodium borosilicate glass
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS
2004; 218: 368-374
View details for DOI 10.1016/j.nimb.2003.12.022
View details for Web of Science ID 000221561000061
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Formation enthalpies of rare earth titanate pyrochlores
JOURNAL OF SOLID STATE CHEMISTRY
2004; 177 (6): 1858-1866
View details for DOI 10.1016/j.jssc.2004.01.009
View details for Web of Science ID 000221769300011
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Ion-beam irradiation of Gd2Sn2O7 and Gd2Hf2O7 pyrochlore: Bond-type effect
JOURNAL OF MATERIALS RESEARCH
2004; 19 (5): 1575-1580
View details for DOI 10.1557/JMR.2004.0178
View details for Web of Science ID 000222316500041
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Direct identification of trace metals in fine and ultrafine particles in the Detroit urban atmosphere
ENVIRONMENTAL SCIENCE & TECHNOLOGY
2004; 38 (8): 2289-2297
Abstract
Exposure to airborne particulates containing low concentrations of heavy metals, such as Pb, As, and Se, may have serious health effects. However, little is known about the speciation and particle size of these airborne metals. Fine- and ultrafine particles with heavy metals in aerosol samples from the Detroit urban area, Michigan, were examined in detail to investigate metal concentrations and speciation. The characterization of individual particles was completed using high-angle annular dark-field scanning transmission electron microscopy (HAADF-STEM) combined with conventional high-resolution TEM techniques. The trace elements, Pb, As, La, Ce, Sr, Zn, Cr, Se, Sn, Y, Zr, Au, and Ag, were detected, and the elemental distributions were mapped in situ atthe nanoscale. The crystal structures of the particles containing Pb, Sr, Zn, and Au were determined from their electron diffraction patterns. Based on the characterization of the representative trace element particles, the potential health effects are discussed. Most of the trace element particles detected in this study were within a range of 0.01-1.0 microm in size, which has the longest atmospheric residence time (approximately 100 days). Increased chemical reactivity owing to the size of nanoparticles may be expected for most of the trace metal particles observed.
View details for DOI 10.1021/es035010p
View details for Web of Science ID 000220857400005
View details for PubMedID 15116832
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Radiation-induced nanostructures in an iron phosphate glass
RADIATION EFFECTS AND ION-BEAM PROCESSING OF MATERIALS
2004; 792: 177-182
View details for Web of Science ID 000189494300023
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Nficrostructure and chemistry of an aluminophosphate glass waste form under electron beam irradiation
SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XXVII
2004; 807: 121-126
View details for Web of Science ID 000225038400020
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Ion beam-induced amorphization of the pyrochlore structure-type: A review
RADIATION EFFECTS AND ION-BEAM PROCESSING OF MATERIALS
2004; 792: 37-48
View details for Web of Science ID 000189494300006
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Radiation effects in murataite ceramics
SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XXVII
2004; 807: 225-230
View details for Web of Science ID 000225038400037
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MAS NMR study on the microstructural changes of zeolite-NaY under neutron irradiation
RADIATION EFFECTS AND ION-BEAM PROCESSING OF MATERIALS
2004; 792: 417-422
View details for Web of Science ID 000189494300060
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Performance assessments of geologic repositories for high-level nuclear waste: Are they necessary or sufficient?
SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XXVIII
2004; 824: 511-520
View details for Web of Science ID 000224543500078
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Colloid transport of radionuclides: Yucca mountain performance assessment
SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XXVII
2004; 807: 653-658
View details for Web of Science ID 000225038400106
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Uncertainties in geochemical models of natural systems: Implications for performance assessments
SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XXVIII
2004; 824: 543-548
View details for Web of Science ID 000224543500081
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Yucca Mountain: Earth-science issues at a geologic repository for high-level nuclear waste
ANNUAL REVIEW OF EARTH AND PLANETARY SCIENCES
2004; 32: 363-401
View details for DOI 10.1146/annurev.earth.32.092203.122444
View details for Web of Science ID 000221752500014
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Effect of radiation on properties of confinement matrices for immobilization of actinide-bearing wastes
GEOLOGY OF ORE DEPOSITS
2003; 45 (6): 423-451
View details for Web of Science ID 000188123000001
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Ion-beam and electron-beam irradiation of synthetic britholite
JOURNAL OF NUCLEAR MATERIALS
2003; 322 (2-3): 180-188
View details for DOI 10.1016/S0022-3115(03)00327-1
View details for Web of Science ID 000186005600009
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Structural and magnetic characterization of CoxNi1-x nanoparticles in yttria-stabilized zirconia single crystals
JOURNAL OF APPLIED PHYSICS
2003; 94 (9): 5648-5651
View details for DOI 10.1063/1.1615299
View details for Web of Science ID 000186138600028
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Microstructural evolution and nanocrystal formation in Pb+-implanted ZrSiO4 single crystals
JOURNAL OF APPLIED PHYSICS
2003; 94 (9): 5695-5703
View details for DOI 10.1063/1.1618917
View details for Web of Science ID 000186138600036
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Nanoscale mineralogy of arsenic in a region of New Hampshire with elevated As-concentrations in the groundwater
AMERICAN MINERALOGIST
2003; 88 (11-12): 1844-1852
View details for Web of Science ID 000186824600002
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Radiation-induced amorphization of rare-earth titanate pyrochlores
PHYSICAL REVIEW B
2003; 68 (13)
View details for DOI 10.1103/PhysRevB.68.134107
View details for Web of Science ID 000186422400035
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Oxygen isotopic composition of nano-scale uraninite at the Oklo-Okelobondo natural fission reactors, Gabon
AMERICAN MINERALOGIST
2003; 88 (10): 1583-1590
View details for Web of Science ID 000185895500022
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REE mobility in groundwater proximate to the natural fission reactor at Bangombe (Gabon)
CHEMICAL GEOLOGY
2003; 198 (3-4): 289-304
View details for DOI 10.1016/S0009-2541(03)00035-4
View details for Web of Science ID 000183582400008
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Enthalpies of formation of U-, Th-, Ce-brannerite: implications for plutonium immobilization
JOURNAL OF NUCLEAR MATERIALS
2003; 320 (3): 231-244
View details for DOI 10.1016/S0022-3115(03)00186-7
View details for Web of Science ID 000184608100007
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Oxidation state of uranium in metamict and annealed zircon: near-infrared spectroscopic quantitative analysis
JOURNAL OF PHYSICS-CONDENSED MATTER
2003; 15 (20): 3445-3470
View details for Web of Science ID 000183656300012
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Radiation damage in zircon
AMERICAN MINERALOGIST
2003; 88 (5-6): 770-781
View details for Web of Science ID 000182835600006
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Size effects in the irradiation-induced crystalline-to-amorphous transformation
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS
2003; 207 (1): 28-35
View details for DOI 10.1016/S0168-583X(03)00519-6
View details for Web of Science ID 000183195800005
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Electron microscopy and optical spectroscopy study of xenon-implanted yttria-stabilized zirconia
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS
2003; 206: 1092-1096
View details for DOI 10.1016/S0168-583X(03)00917-0
View details for Web of Science ID 000183690500232
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The order-disorder transition in ion-irradiated pyrochlore
ACTA MATERIALIA
2003; 51 (5): 1493-1502
View details for DOI 10.1016/S1359-6454(02)00544-X
View details for Web of Science ID 000181677700024
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Application of high-angle annular dark field scanning transmission electron microscopy, scanning transmission electron microscopy-energy dispersive X-ray spectrometry, and energy-filtered transmission electron microscopy to the characterization of nanoparticles in the environment
ENVIRONMENTAL SCIENCE & TECHNOLOGY
2003; 37 (4): 786-791
Abstract
A major challenge to the development of a fundamental understanding of transport and retardation mechanisms of trace metal contaminants (<10 ppm) is their identification and characterization at the nanoscale. Atomic-scale techniques, such as conventional transmission electron microscopy, although powerful, are limited by the extremely small amounts of material that are examined. However, recent advances in electron microscopy provide a number of new analytical techniques that expand its application in environmental studies, particularly those concerning heavy metals on airborne particulates or water-borne colloids. High-angle annular dark field scanning transmission electron microscopy (HAADF-STEM), STEM-energy-dispersive X-ray spectrometry (EDX), and energy-filtered TEM (EFTEM) can be effectively used to identify and characterize nanoparticles. The image contrast in HAADF-STEM is strongly correlated to the atomic mass: heavier elements contribute to brighter contrast. Gold nanocrystals in pyrite and uranium nanocrystals in atmospheric aerosols have been identified by HAADF-STEM and STEM-EDX mapping and subsequently characterized by high-resolution TEM (HRTEM). EFTEM was used to identify U and Fe nanocrystals embedded in an aluminosilicate. A rare, As-bearing nanophase, westerveldite (FeAs), was identified by STEM-EDX and HRTEM. The combined use of these techniques greatly expands the effective application of electron microscopy in environmental studies, especially when applied to metals of very low concentrations. This paper describes examples of how these electron microbeam techniques can be used in combination to characterize a low concentration of heavy metals (a few ppm) on nanoscale particles.
View details for DOI 10.1021/es026053t
View details for Web of Science ID 000181067100019
View details for PubMedID 12636280
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The effect of ionizing radiation on uranophane
AMERICAN MINERALOGIST
2003; 88 (1): 159-166
View details for Web of Science ID 000180383600019
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Enthalpies of formation of cerium zirconate: (Ce,Zr)O-2 fiuorite and Ce2Zr2O7 Pyrochlore
PLUTONIUM FUTURES - THE SCIENCE
2003; 673: 286-287
View details for Web of Science ID 000184499100107
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Analytical electron microscopy study of electron radiation damage in iron phosphate glass waste forms
SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XXVI
2003; 757: 135-140
View details for Web of Science ID 000186634300016
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Radiation effects in zircon
ZIRCON
2003; 53: 387-425
View details for Web of Science ID 000189199900014
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Structure-configurational entropy and its effect on the thermodynamic stability of uranyl phases: With special application for geological disposal of nuclear waste
SCIENCE IN CHINA SERIES D-EARTH SCIENCES
2003; 46 (1): 39-49
View details for Web of Science ID 000181415400004
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Uraninite and fullerene in atmospheric particulates
ENVIRONMENTAL SCIENCE & TECHNOLOGY
2002; 36 (23): 4943-4947
Abstract
Particulates emitted from coal-burning power plants typically contain very small amounts of uranium (<10 ppm). Because of the extremely low concentrations, the form of the uranium has been unknown. Using a variety of advanced electron microscopy techniques, we have identified for the first time nanocrystals of uraninite, UO2+x, encapsulated in carbonaceous matter (< or = 50 nm) similar to fullerene. We have also identified, for the first time, closely associated fullerenes, C60. The "carbon-caged" nanocrystals of uraninite are protected from the immediate oxidation that would lead to increased mobility of uranium in the environment. Still, the presence of uranium in the very fine fraction of atmospheric particulates provides another pathway for radiation exposure.
View details for Web of Science ID 000179685000005
View details for PubMedID 12523404
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X-ray study of actinide host-phases formation
GEOCHIMICA ET COSMOCHIMICA ACTA
2002; 66 (15A): A866-A866
View details for Web of Science ID 000177423401692
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Ion-irradiation-induced amorphization of La2Zr2O7 pyrochlore
PHYSICAL REVIEW B
2002; 66 (5)
View details for DOI 10.1103/PhysRevB.66.054108
View details for Web of Science ID 000177873000053
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REE migration in groundwaters close to the natural fission reactor of Bangombe (Gabon)
GEOCHIMICA ET COSMOCHIMICA ACTA
2002; 66 (15A): A742-A742
View details for Web of Science ID 000177423401453
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Impact of the nuclear fuel cycle on the environment
GEOCHIMICA ET COSMOCHIMICA ACTA
2002; 66 (15A): A220-A220
View details for Web of Science ID 000177423400427
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Phase transformations during synthesis of actinide matrices
DOKLADY EARTH SCIENCES
2002; 385 (6): 671-675
View details for Web of Science ID 000178134000015
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Yucca Mountain: Should we delay? Response
SCIENCE
2002; 296 (5577): 2334-2335
View details for Web of Science ID 000176467200019
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Nanodomains of pyrochlore formed by Ti ion implantation in yttria-stabilized zirconia
APPLIED PHYSICS LETTERS
2002; 80 (23): 4327-4329
View details for DOI 10.1063/1.1482784
View details for Web of Science ID 000175904600013
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Ion irradiation-induced amorphization and nano-crystal formation in garnets
JOURNAL OF NUCLEAR MATERIALS
2002; 303 (2-3): 177-187
View details for Web of Science ID 000176504300012
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X-ray photoelectron spectroscopy study of irradiation-induced amorphization of Gd2Ti2O7 (vol 79, pg 1989, 2001)
APPLIED PHYSICS LETTERS
2002; 80 (19): 3650-3650
View details for DOI 10.1063/1.1472474
View details for Web of Science ID 000175464100062
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O and Pb isotopic analyses of uranium minerals by ion microprobe and U-Pb ages from the Cigar Lake deposit
CHEMICAL GEOLOGY
2002; 185 (3-4): 205-225
View details for Web of Science ID 000175645500004
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Ion irradiation effects in natural garnets: Comparison with zircon
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS
2002; 191: 600-605
View details for Web of Science ID 000176692300115
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Heavy ion irradiation effects of brannerite-type ceramics
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS
2002; 191: 565-570
View details for Web of Science ID 000176692300108
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Nuclear waste - Yucca Mountain
SCIENCE
2002; 296 (5568): 659-660
View details for Web of Science ID 000175281700027
View details for PubMedID 11976429
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Infrared spectra of Si-O overtones, hydrous species, and U ions in metamict zircon: radiation damage and recrystallization
JOURNAL OF PHYSICS-CONDENSED MATTER
2002; 14 (12): 3333-3352
View details for Web of Science ID 000175333200029
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X-ray photoelectron spectroscopy study of disordering in Gd-2(Ti1-xZrx)(2)O-7 pyrochlores
PHYSICAL REVIEW LETTERS
2002; 88 (10)
Abstract
The dramatic increases in ionic conductivity in Gd2(Ti1-xZrx)2O7 solid solution are related to disordering on the cation and anion lattices. Disordering in Gd2(Ti1-xZrx)2O7 was characterized using x-ray photoelectron spectroscopy (XPS). As Zr substitutes for Ti in Gd2Ti2O7 to form Gd2(Ti1-xZrx)2O7 (0.25 < x < or =0.75), the corresponding O 1s XPS spectrum merges into a single symmetric peak. This confirms that the cation antisite disorder occurs simultaneously with anion disorder. Furthermore, the O 1s XPS spectrum of Gd2Zr2O7 experimentally suggests the formation of a split vacancy.
View details for DOI 10.1103/PhysRevLett.88.105901
View details for Web of Science ID 000174342000045
View details for PubMedID 11909374
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Amorphization and recrystallization of the ABO(3) oxides
JOURNAL OF NUCLEAR MATERIALS
2002; 300 (2-3): 242-254
View details for Web of Science ID 000173903300013
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Structural alterations in titanate pyrochlores induced by ion irradiation: X ray photoelectron spectrum interpretation
SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XXV
2002; 713: 501-506
View details for Web of Science ID 000177857500059
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Radiation effects in crystalline oxide host phases for the immobilization of actinides
SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XXV
2002; 713: 443-454
View details for Web of Science ID 000177857500051
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In situ isotopic analysis of uraninite microstructures from the Oklo-Okelobondo natural fission reactors, Gabon
SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XXV
2002; 713: 849-856
View details for Web of Science ID 000177857500101
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Accommodation of uranium into the garnet structure
SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XXV
2002; 713: 477-480
View details for Web of Science ID 000177857500055
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Materials research in nuclear waste management: Reflections on twenty-five MRS symposia
SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XXV
2002; 713: 3-14
View details for Web of Science ID 000177857500001
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Ion irradiation effects in synthetic garnets incorporating actinides
SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XXV
2002; 713: 495-500
View details for Web of Science ID 000177857500058
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Heavy ion irradiation of zirconate pyrochlores
SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XXV
2002; 713: 507-512
View details for Web of Science ID 000177857500060
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Ion-induced amorphization of murataite
SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XXV
2002; 713: 455-460
View details for Web of Science ID 000177857500052
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Phosphates as nuclear waste forms
PHOSPHATES: GEOCHEMICAL, GEOBIOLOGICAL, AND MATERIALS IMPORTANCE
2002; 48: 673-699
View details for Web of Science ID 000180780600018
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The effects of radiation on the retention of strontium in zeolite-NaSrY
JOURNAL OF MATERIALS CHEMISTRY
2002; 12 (2): 233-238
View details for Web of Science ID 000173477300016
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Cesium ton implantation in single crystal yttria-stabilized zirconia (YSZ) and polycrystalline MgAl2O4-YSZ
SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XXV
2002; 713: 327-332
View details for Web of Science ID 000177857500035
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U6+ phases in the weathering zone of the Bangombe U-deposit: observed and predicted mineralogy
RADIOCHIMICA ACTA
2002; 90 (9-11): 761-769
View details for Web of Science ID 000180377300043
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An empirical method for calculating thermodynamic parameters for U(VI) phases, applications to performance assessment calculations
USE OF THERMODYNAMIC DATABASES IN PERFORMANCE ASSESSMENT, WORKSHOP PROCEEDINGS
2002: 93-102
View details for Web of Science ID 000178154500008
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Microanalysis of radiation damage across a zoned zircon crystal
SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XXV
2002; 713: 521-526
View details for Web of Science ID 000177857500062
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Nanoscale manipulation of pyrochlore: New nanocomposite ionic conductors
PHYSICAL REVIEW LETTERS
2001; 87 (14)
Abstract
The ionic conductivity of isometric pyrochlore, ideally A2B2O (7), is extremely sensitive to disordering of A- and B-site cations and oxygen anion vacancies. We report the first use of ion beam irradiation-induced disordering in Gd 2Ti 2O (7) to produce a strain-free, buried, disordered defect-fluorite layer approximately 12 nm thick within an ordered pyrochlore matrix. This approach provides a new means of creating nanoscale, mixed ionic-electronic conductors in pyrochlore ceramics, such as those required for solid-state electrochemical cells.
View details for DOI 10.1103/PhysRevLett.87.145901
View details for Web of Science ID 000171427500031
View details for PubMedID 11580662
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X-ray photoelectron spectroscopy study of irradiation-induced amorphizaton of Gd2Ti2O7
APPLIED PHYSICS LETTERS
2001; 79 (13): 1989-1991
View details for Web of Science ID 000171015200020
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Temperature effects on the radiation stability and ion exchange capacity of smectites
JOURNAL OF NUCLEAR MATERIALS
2001; 297 (3): 345-354
View details for Web of Science ID 000170843000014
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Radiation damage and nanocrystal formation in uranium-niobium titanates
JOURNAL OF NUCLEAR MATERIALS
2001; 297 (1): 89-96
View details for Web of Science ID 000170024500012
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The design and evaluation of nuclear-waste forms: Clues from mineralogy
CANADIAN MINERALOGIST
2001; 39: 697-715
View details for Web of Science ID 000170460000001
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Radiation resistance of fused titanium ceramic for actinide immobilization
ATOMIC ENERGY
2001; 90 (6): 487-494
View details for Web of Science ID 000172759600009
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Ion irradiation-induced amorphization of two GeO2 polymorphs
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS
2001; 175: 615-619
View details for Web of Science ID 000169389100113
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Irradiation-induced amorphization of Cd2Nb2O7 pyrochlore
PHYSICAL REVIEW B
2001; 63 (10)
View details for Web of Science ID 000167402100029
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Nuclear waste form glasses: The evaluation of very long-term behaviour
MATERIALS TECHNOLOGY
2001; 16 (1): 30-36
View details for Web of Science ID 000172580600007
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Effects of fission product incorporation on the microstructure of cubic zirconia
JOURNAL OF NUCLEAR MATERIALS
2001; 289 (1-2): 122-127
View details for Web of Science ID 000167546300019
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Radiation stability of actinide matrices
DOKLADY EARTH SCIENCES
2001; 377 (2): 175-177
View details for Web of Science ID 000167612200010
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Irradiation-induced amorphization: Effects of temperature, ion mass, cascade size, and dose rate
PHYSICAL REVIEW B
2001; 63 (2)
View details for Web of Science ID 000166382200016
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Effects of xenon implantation in spinel-zirconia/ceria composites
PROGRESS IN NUCLEAR ENERGY
2001; 38 (3-4): 295-300
View details for Web of Science ID 000167006300019
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The Okelobondo natural fission reactor, southeast Gabon: Geology, mineralogy, and retardation of nuclear-reaction products
GEOLOGICAL SOCIETY OF AMERICA BULLETIN
2001; 113 (1): 32-62
View details for Web of Science ID 000166440700003
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Memorial of Arthur Montgomery, 1909-1999
AMERICAN MINERALOGIST
2000; 85 (11-12): 1848-1850
View details for Web of Science ID 000165220800032
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Integrated experimental and computational methods for structure determination and characterization of a new, highly stable cesium silicotitanate phase, Cs2TiSi6O15 (SNL-A)
CHEMISTRY OF MATERIALS
2000; 12 (11): 3449-3458
View details for DOI 10.1021/cm000259g
View details for Web of Science ID 000165462800034
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Synthesis and characterization of a new microporous cesium silicotitanate (SNL-B) molecular sieve
MICROPOROUS AND MESOPOROUS MATERIALS
2000; 40 (1-3): 115-125
View details for Web of Science ID 000165320200011
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Plutonium immobilization and radiation effects
SCIENCE
2000; 289 (5487): 2051-2052
View details for Web of Science ID 000089430900019
View details for PubMedID 17799393
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Nano-scale glass formation in pyrochlore by heavy ion irradiation
JOURNAL OF NON-CRYSTALLINE SOLIDS
2000; 274 (1-3): 238-243
View details for Web of Science ID 000089298300033
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Irradiation-induced nanostructures
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING
2000; 286 (1): 72-80
View details for Web of Science ID 000088914700011
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Alpha-decay damage and recrystallization in zircon: evidence for an intermediate state from infrared spectroscopy
JOURNAL OF PHYSICS-CONDENSED MATTER
2000; 12 (24): 5189-5199
View details for Web of Science ID 000088129700012
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Ion irradiation of rare-earth- and yttrium-titanate-pyrochlores
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS
2000; 169: 135-140
View details for Web of Science ID 000088184200026
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Amorphization of cubic zirconia by caesium-ion implantation
PHILOSOPHICAL MAGAZINE LETTERS
2000; 80 (5): 341-347
View details for Web of Science ID 000086844400009
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Ion irradiation-induced amorphization of six zirconolite compositions
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS
2000; 166: 293-298
View details for Web of Science ID 000087422200051
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Annealing of alpha-decay damage in zircon: a Raman spectroscopic study
JOURNAL OF PHYSICS-CONDENSED MATTER
2000; 12 (13): 3131-3148
View details for Web of Science ID 000086415900026
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A comparison of radiation effects in crystalline ABO(4)-type phosphates and silicates
MINERALOGICAL MAGAZINE
2000; 64 (2): 185-194
View details for Web of Science ID 000087015800003
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Electron and ion irradiation of zeolites
JOURNAL OF NUCLEAR MATERIALS
2000; 278 (2-3): 233-241
View details for Web of Science ID 000085723300012
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Near-field behavior of Tc-99 during the oxidative alteration of spent nuclear fuel
JOURNAL OF NUCLEAR MATERIALS
2000; 278 (2-3): 225-232
View details for Web of Science ID 000085723300011
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XAS and XRD study of annealed Pu-238- and Pu-239-substituted zircons (Zr0.92Pu0.08SiO4)
JOURNAL OF NUCLEAR MATERIALS
2000; 278 (2-3): 212-224
View details for Web of Science ID 000085723300010
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Amorphization in zircon: evidence for direct impact damage
JOURNAL OF PHYSICS-CONDENSED MATTER
2000; 12 (11): 2401-2412
View details for Web of Science ID 000086146600007
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Ion irradiation effects in nonmetals: formation of nanocrystals and novel microstructures
MATERIALS RESEARCH INNOVATIONS
2000; 3 (4): 190-204
View details for Web of Science ID 000085908700003
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The effect of amorphization on the Cs ion exchange and retention capacity of zeolite-NaY
JOURNAL OF NUCLEAR MATERIALS
2000; 278 (1): 64-72
View details for Web of Science ID 000085069800008
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Reaction sintered glass: a durable matrix for spinel-forming nuclear waste compositions
JOURNAL OF NUCLEAR MATERIALS
2000; 278 (1): 73-84
View details for Web of Science ID 000085069800009
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Metamictization of zircon: Raman spectroscopic study
JOURNAL OF PHYSICS-CONDENSED MATTER
2000; 12 (8): 1915-1925
View details for Web of Science ID 000085923700038
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Zirconia ceramics for excess weapons plutonium waste
JOURNAL OF NUCLEAR MATERIALS
2000; 277 (2-3): 239-249
View details for Web of Science ID 000084960800014
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Micro-structures associated with uraninite alteration
JOURNAL OF NUCLEAR MATERIALS
2000; 277 (2-3): 204-210
View details for Web of Science ID 000084960800009
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The effect of H+ irradiation on the Cs-ion exchange capacity of zeolite-NaY
JOURNAL OF MATERIALS CHEMISTRY
2000; 10 (11): 2610-2616
View details for Web of Science ID 000090052000033
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Plutonium stabilization in zircon: Effects of self-radiation
PLUTONIUM FUTURES-THE SCIENCE
2000; 532: 18-19
View details for Web of Science ID 000167358800007
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An overview of the crystal chemistry, durability, and radiation damage effects of natural pyrochlore
SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XXIV
2000; 663: 921-934
View details for Web of Science ID 000179468500104
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Effects of cesium, iodine and strontium ion implantation on the microstructure of cubic zirconia
SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XXIV
2000; 663: 293-300
View details for Web of Science ID 000179468500034
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Gadolinium borosilicate glass-bonded Gd-silicate apatite: A glass-ceramic nuclear waste form for actinides
SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XXIV
2000; 663: 199-206
View details for Web of Science ID 000179468500024
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Radiation effects on materials in the near-field of a nuclear waste repository
SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XXIV
2000; 663: 883-891
View details for Web of Science ID 000179468500100
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Effects of fission product accumulation in cubic zirconia
PLUTONIUM FUTURES-THE SCIENCE
2000; 532: 95-97
View details for Web of Science ID 000167358800039
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Alteration products of uraninite from the Colorado Plateau
RADIOCHIMICA ACTA
2000; 88 (9-11): 739-749
View details for Web of Science ID 000166276300039
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Radiation effects in nuclear waste materials and their consequences
APPLIED MINERALOGY, VOLS 1 AND 2
2000: 87-87
View details for Web of Science ID 000089525700024
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Radiation effects in uranium-niobium titanates
PLUTONIUM FUTURES-THE SCIENCE
2000; 532: 403-405
View details for Web of Science ID 000167358800169
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Radiation resistance of gadolinium zirconate pyrochlore
PLUTONIUM FUTURES-THE SCIENCE
2000; 532: 15-17
View details for Web of Science ID 000167358800006
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Ceramic waste forms for excess weapons plutonium
ENVIRONMENTAL CHALLENGES OF NUCLEAR DISARMAMENT
2000; 29: 65-74
View details for Web of Science ID 000166322400007
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Radiation-induced amorphization
TRANSFORMATION PROCESSES IN MINERALS
2000; 39: 319-361
View details for Web of Science ID 000169436700012
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Radiation stability of gadolinium zirconate: A waste form for plutonium disposition
JOURNAL OF MATERIALS RESEARCH
1999; 14 (12): 4470-4473
View details for Web of Science ID 000084155000005
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Comparison of ion-beam irradiation effects in X2YO4 compounds
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
1999; 82 (12): 3321-3329
View details for Web of Science ID 000085763900007
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Radioactive waste - Less geology in the geological disposal of nuclear waste
SCIENCE
1999; 286 (5439): 415-?
View details for Web of Science ID 000083121200027
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Se-79: geochemical and crystallo-chemical retardation mechanisms
JOURNAL OF NUCLEAR MATERIALS
1999; 275 (1): 81-94
View details for Web of Science ID 000082699400010
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Performance assessments of nuclear waste repositories: A dialogue on their value and limitations
RISK ANALYSIS
1999; 19 (5): 933-958
Abstract
Performance Assessment (PA) is the use of mathematical models to simulate the long-term behavior of engineered and geologic barriers in a nuclear waste repository; methods of uncertainty analysis are used to assess effects of parametric and conceptual uncertainties associated with the model system upon the uncertainty in outcomes of the simulation. PA is required by the U.S. Environmental Protection Agency as part of its certification process for geologic repositories for nuclear waste. This paper is a dialogue to explore the value and limitations of PA. Two "skeptics" acknowledge the utility of PA in organizing the scientific investigations that are necessary for confident siting and licensing of a repository; however, they maintain that the PA process, at least as it is currently implemented, is an essentially unscientific process with shortcomings that may provide results of limited use in evaluating actual effects on public health and safety. Conceptual uncertainties in a PA analysis can be so great that results can be confidently applied only over short time ranges, the antithesis of the purpose behind long-term, geologic disposal. Two "proponents" of PA agree that performance assessment is unscientific, but only in the sense that PA is an engineering analysis that uses existing scientific knowledge to support public policy decisions, rather than an investigation intended to increase fundamental knowledge of nature; PA has different goals and constraints than a typical scientific study. The "proponents" describe an ideal, six-step process for conducting generalized PA, here called probabilistic systems analysis (PSA); they note that virtually all scientific content of a PA is introduced during the model-building steps of a PSA; they contend that a PA based on simple but scientifically acceptable mathematical models can provide useful and objective input to regulatory decision makers. The value of the results of any PA must lie between these two views and will depend on the level of knowledge of the site, the degree to which models capture actual physical and chemical processes, the time over which extrapolations are made, and the proper evaluation of health risks attending implementation of the repository. The challenge is in evaluating whether the quality of the PA matches the needs of decision makers charged with protecting the health and safety of the public.
View details for Web of Science ID 000083825000008
View details for PubMedID 10765440
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Refinement of the crystal structure of rutherfordine
CANADIAN MINERALOGIST
1999; 37: 929-938
View details for Web of Science ID 000083539400007
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Is "metamictization" of zircon a phase transition?
AMERICAN MINERALOGIST
1999; 84 (7-8): 1107-1116
View details for Web of Science ID 000081261100013
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Is a probabilistic performance assessment enough?
GROUND WATER
1999; 37 (4): 481-482
View details for Web of Science ID 000081268800001
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The Gibbs free energies and enthalpies of formation of U6+ phases: An empirical method of prediction
AMERICAN MINERALOGIST
1999; 84 (4): 650-664
View details for Web of Science ID 000079631300018
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Nuclear waste forms for actinides
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA
1999; 96 (7): 3432-3439
Abstract
The disposition of actinides, most recently 239Pu from dismantled nuclear weapons, requires effective containment of waste generated by the nuclear fuel cycle. Because actinides (e.g., 239Pu and 237Np) are long-lived, they have a major impact on risk assessments of geologic repositories. Thus, demonstrable, long-term chemical and mechanical durability are essential properties of waste forms for the immobilization of actinides. Mineralogic and geologic studies provide excellent candidate phases for immobilization and a unique database that cannot be duplicated by a purely materials science approach. The "mineralogic approach" is illustrated by a discussion of zircon as a phase for the immobilization of excess weapons plutonium.
View details for Web of Science ID 000079507900019
View details for PubMedID 10097054
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Effects of dose rate and temperature on the crystalline-to-metamict transformation in the ABO(4) orthosilicates
CANADIAN MINERALOGIST
1999; 37: 207-221
View details for Web of Science ID 000080605400020
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Vitrification of radioactive waste by reaction sintering under pressure
JOURNAL OF NUCLEAR MATERIALS
1999; 265 (1-2): 12-21
View details for Web of Science ID 000078356100002
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Formation of oriented particles in an amorphous host: ZnS nanocrystals in silicon
APPLIED PHYSICS LETTERS
1999; 74 (5): 697-699
View details for Web of Science ID 000078379600022
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Heavy-ion irradiation effects in the ABO(4) orthosilicates: Decomposition, amorphization, and recrystallization
PHYSICAL REVIEW B
1999; 59 (6): 3981-3992
View details for Web of Science ID 000078699400011
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Surface features and alteration products of natural zirconolite leached in silica-saturated solutions
SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XXII
1999; 556: 157-164
View details for Web of Science ID 000084437500022
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Pyrochlore-type phases for actinides and rare earth elements immobilization
SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XXII
1999; 556: 27-34
View details for Web of Science ID 000084437500004
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Solid solutions of Ce, U, and Th in zircon
ENVIRONMENTAL ISSUES AND WASTE MANAGEMENT TECHNOLOGIES IN THE CERAMIC AND NUCLEAR INDUSTRIES IV
1999; 93: 357-363
View details for Web of Science ID 000080430100042
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Distribution and solubility of radionuclides in waste forms for disposition of plutonium and spent nuclear fuels: Preliminary results
ENVIRONMENTAL ISSUES AND WASTE MANAGEMENT TECHNOLOGIES IN THE CERAMIC AND NUCLEAR INDUSTRIES IV
1999; 93: 409-419
View details for Web of Science ID 000080430100048
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Radiation effects in zircon, hafnon, and thorite: Implications for Pu disposal
MICROSTRUCTURAL PROCESSES IN IRRADIATED MATERIALS
1999; 540: 395-400
View details for Web of Science ID 000080728500061
-
The effect of temperature and damage energy on amorphization in zircon
MICROSTRUCTURAL PROCESSES IN IRRADIATED MATERIALS
1999; 540: 367-372
View details for Web of Science ID 000080728500056
-
Se-79: Geochemical and crystallo-chemical retardation mechanisms
SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XXII
1999; 556: 1115-1122
View details for Web of Science ID 000084437500138
-
Structural contributions to the third-law entropy of uranyl phases
SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XXII
1999; 556: 1017-1024
View details for Web of Science ID 000084437500126
-
Radioactivity and the 20th Century
REVIEWS IN MINERALOGY <D>
1999; 38: 1-21
View details for Web of Science ID 000207512900001
-
Zirconia - A ceramic for excess weapons plutonium wastes
SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XXII
1999; 556: 63-70
View details for Web of Science ID 000084437500009
-
Effect of microstructure and chemical bonding on the adhesion strength of a silicon/polymer interface for microelectronic packaging applications
III-V AND IV-IV MATERIALS AND PROCESSING CHALLENGES FOR HIGHLY INTEGRATED MICROELECTRONICS AND OPTOELECTRONICS
1999; 535: 165-170
View details for Web of Science ID 000082590400026
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Ion irradiation effects for two pyrochlore compositions: Gd2Ti2O7 and Gd2Zr2O7
MICROSTRUCTURAL PROCESSES IN IRRADIATED MATERIALS
1999; 540: 355-360
View details for Web of Science ID 000080728500054
-
Electron irradiation of zeolites
MICROSTRUCTURAL PROCESSES IN IRRADIATED MATERIALS
1999; 540: 361-366
View details for Web of Science ID 000080728500055
-
Ion irradiation-induced phase transformation of pyrochlore and zirconolite
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS
1999; 148 (1-4): 704-709
View details for Web of Science ID 000078575700132
-
The dissolution rate of chemically durable materials: Zircon
ENVIRONMENTAL ISSUES AND WASTE MANAGEMENT TECHNOLOGIES IN THE CERAMIC AND NUCLEAR INDUSTRIES IV
1999; 93: 297-304
View details for Web of Science ID 000080430100035
-
Rubicline, a new feldspar from San Piero in Campo, Elba, Italy
AMERICAN MINERALOGIST
1998; 83 (11-12): 1335-1339
View details for Web of Science ID 000077410500023
-
Cross-sectional transmission electron microscopy study of 1.5 MeV Kr+ irradiation-induced amorphization in alpha-quartz
JOURNAL OF APPLIED PHYSICS
1998; 84 (8): 4204-4208
View details for Web of Science ID 000076185100025
-
Amorphization of ceramic materials by ion beam irradiation
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING
1998; 253 (1-2): 106-113
View details for Web of Science ID 000076521100013
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A transient liquid-like phase in the displacement cascades of zircon, hafnon and thorite
NATURE
1998; 395 (6697): 56-58
View details for Web of Science ID 000075722200043
-
Ion beam-induced amorphization in MgO-Al2O3-SiO2. II. Empirical model
JOURNAL OF NON-CRYSTALLINE SOLIDS
1998; 238 (3): 214-224
View details for Web of Science ID 000075874700005
-
Ion beam-induced amorphization in MgO-Al2O3-SiO2. I. Experimental and theoretical basis
JOURNAL OF NON-CRYSTALLINE SOLIDS
1998; 238 (3): 198-213
View details for Web of Science ID 000075874700004
-
Radiation damage in zircon and monazite
GEOCHIMICA ET COSMOCHIMICA ACTA
1998; 62 (14): 2509-2520
View details for Web of Science ID 000076031100009
-
The role of pe, pH, and carbonate on the solubility of UO2 and uraninite under nominally reducing conditions
GEOCHIMICA ET COSMOCHIMICA ACTA
1998; 62 (13): 2223-2231
View details for Web of Science ID 000075649500001
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A method to predict free energies of formation of mineral phases in the U(VI)-SiO2-H2O system
JOURNAL OF ALLOYS AND COMPOUNDS
1998; 271: 189-193
View details for Web of Science ID 000074686200041
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Radiation effects in crystalline ceramics for the immobilization of high-level nuclear waste and plutonium
JOURNAL OF MATERIALS RESEARCH
1998; 13 (6): 1434-1484
View details for Web of Science ID 000074063800007
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Structural relations among schoepite, metaschoepite and "dehydrated schoepite"
CANADIAN MINERALOGIST
1998; 36: 831-845
View details for Web of Science ID 000076767200015
-
Ion irradiation-induced amorphization of CaA1(2)O(4)
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS
1998; 141 (1-4): 509-513
View details for Web of Science ID 000074979800087
-
Temperature dependence of Kr ion-induced amorphization of mica minerals
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS
1998; 141 (1-4): 501-508
View details for Web of Science ID 000074979800086
-
Effects of ionizing and displacive irradiation on several perovskite-structure oxides
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS
1998; 141 (1-4): 347-352
View details for Web of Science ID 000074979800057
-
Analytical electron microscopy study of surface layers formed on the French SON68 nuclear waste glass during vapor hydration at 200 degrees C
JOURNAL OF NUCLEAR MATERIALS
1998; 254 (2-3): 249-265
View details for Web of Science ID 000074007500017
-
The Hawley Medal for 1997 to Peter C. Burns, Mark L. Miller and Rodney C. Ewing
CANADIAN MINERALOGIST
1998; 36: 240-240
View details for Web of Science ID 000074466400018
-
Vitrification of high-level radioactive waste by sintering under pressure
SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XXI
1998; 506: 223-230
View details for Web of Science ID 000073286700028
-
Transmission electron microscopy study of radiation effects in materials for nuclear waste disposal
ELECTRON MICROSCOPY 1998, VOL 2
1998: 825-826
View details for Web of Science ID 000077019900406
-
The crystal chemistry of hexavalent uranium: Polyhedron geometries, bond-valence parameters, and polymerization of polyhedra
CANADIAN MINERALOGIST
1997; 35: 1551-1570
View details for Web of Science ID 000073275800018
-
Distinguishing among schoepite, [(UO2)(8)O-2(OH)(12)](H2O)(12), and related minerals by X-ray powder diffraction
POWDER DIFFRACTION
1997; 12 (4): 230-238
View details for Web of Science ID 000071060800004
-
The kinetics of alpha-decay-induced amorphization in zircon and apatite containing weapons-grade plutonium or other actinides
JOURNAL OF NUCLEAR MATERIALS
1997; 250 (2-3): 147-155
View details for Web of Science ID 000071346300008
-
Displacive radiation effects in the monazite- and zircon-structure orthophosphates
PHYSICAL REVIEW B
1997; 56 (21): 13805-13814
View details for Web of Science ID A1997YJ87900048
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The crystal structure of ianthinite, [U-2(4+)(UO2)(4)O-6(OH)(4)(H2O)(4)](H2O)(5): a possible phase for Pu4+ incorporation during the oxidation of spent nuclear fuel
JOURNAL OF NUCLEAR MATERIALS
1997; 249 (2-3): 199-206
View details for Web of Science ID A1997YC69700013
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Characterization and dissolution behavior of a becquerelite from Shinkolobwe, Zaire
GEOCHIMICA ET COSMOCHIMICA ACTA
1997; 61 (18): 3879-3884
View details for Web of Science ID A1997YC77400008
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Electron-irradiation-induced phase segregation in crystalline and amorphous apatite: A TEM study
AMERICAN MINERALOGIST
1997; 82 (9-10): 858-869
View details for Web of Science ID A1997XX50000003
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Mineral chemistry and oxygen isotopic analyses of uraninite, pitchblende and uranium alteration minerals from the Cigar Lake deposit, Saskatchewan, Canada
APPLIED GEOCHEMISTRY
1997; 12 (5): 549-565
View details for Web of Science ID A1997YF69900001
-
Radiation effects in glasses used for immobilization of high-level waste and plutonium disposition
JOURNAL OF MATERIALS RESEARCH
1997; 12 (8): 1946-1978
View details for Web of Science ID A1997XQ27800004
-
Electron-irradiation-induced nucleation and growth in amorphous LaPO4, ScPO4, and zircon
JOURNAL OF MATERIALS RESEARCH
1997; 12 (7): 1816-1827
View details for Web of Science ID A1997XJ19400023
-
Ion beam-irradiation induced structure transformation in alpha-AlMnSi
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS
1997; 127: 752-755
View details for Web of Science ID A1997XG60500170
-
Donathite discredited: A mixture of two spinels
NEUES JAHRBUCH FUR MINERALOGIE-MONATSHEFTE
1997: 163-174
View details for Web of Science ID A1997XF07300003
-
Ion-beam-induced amorphization of LaPO4 and ScPO4
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS
1997; 127: 160-165
View details for Web of Science ID A1997XG60500037
-
Ion irradiation-induced phase transformation in Al-Cu-Co-Ge decagonal quasicrystal
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS
1997; 127: 127-131
View details for Web of Science ID A1997XG60500029
-
Incorporation mechanisms of actinide elements into the structures of U6+ phases formed during the oxidation of spent nuclear fuel
JOURNAL OF NUCLEAR MATERIALS
1997; 245 (1): 1-9
View details for Web of Science ID A1997XB15500001
-
Clarkeite: New chemical and structural data
AMERICAN MINERALOGIST
1997; 82 (5-6): 607-619
View details for Web of Science ID A1997XE09000020
-
Amorphization of Al2SiO5 polymorphs under ion beam irradiation
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS
1997; 127: 186-190
View details for Web of Science ID A1997XG60500042
-
Interface-mediated amorphization of coesite by 200 keV electron irradiation
JOURNAL OF APPLIED PHYSICS
1997; 81 (6): 2570-2574
View details for Web of Science ID A1997WP16700017
-
Disposing of plutonium
SCIENCE
1997; 275 (5301): 737-737
View details for Web of Science ID A1997WG77700002
-
Ion irradiation-induced amorphization in the Al2O3-SiO2 system: A comparison with glass formation
JOURNAL OF APPLIED PHYSICS
1997; 81 (2): 587-593
View details for Web of Science ID A1997WD71600007
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Transuranium element incorporation into the beta-U3O8 uranyl sheet
SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XX
1997; 465: 581-588
View details for Web of Science ID A1997BJ28H00073
-
Uraninite: A 2 GA spent nuclear fuel from the natural fission reactor at Bangombe in Gabon, West Africa
SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XX
1997; 465: 1209-1218
View details for Web of Science ID A1997BJ28H00150
-
Ion irradiation-induced amorphization in the MgO-Al2O3-SiO2 system: A cascade quenching model
MICROSTRUCTURE EVOLUTION DURING IRRADIATION
1997; 439: 619-624
View details for Web of Science ID A1997BJ12F00092
-
Electron-irradiation-induced crystallization orthophosphates
MICROSTRUCTURE EVOLUTION DURING IRRADIATION
1997; 439: 697-702
View details for Web of Science ID A1997BJ12F00103
-
Transmission electron microscopy study of alpha-decay damage in aeschynite and britholite
SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XX
1997; 465: 649-656
View details for Web of Science ID A1997BJ28H00082
-
Uraninite-water interactions in an oxidizing environment
SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XX
1997; 465: 1201-1208
View details for Web of Science ID A1997BJ28H00149
-
Amorphization of ceramic materials by ion-beam-irradiation: Parallels to glass formation
MICROSTRUCTURE EVOLUTION DURING IRRADIATION
1997; 439: 583-594
View details for Web of Science ID A1997BJ12F00089
-
Mineralogical and microtextural characterization of ''gel-zircon'' from the Manibay uranium mine, Kazakhstan
SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XX
1997; 465: 1219-1226
View details for Web of Science ID A1997BJ28H00151
-
Description and classification of uranium oxide hydrate sheet anion topologies
JOURNAL OF MATERIALS RESEARCH
1996; 11 (12): 3048-3056
View details for Web of Science ID A1996VX28900016
-
Uraninite and UO2 in spent nuclear fuel: A comparison
JOURNAL OF NUCLEAR MATERIALS
1996; 238 (1): 121-130
View details for Web of Science ID A1996WC93900014
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The crystal structure of schoepite, [(UO2)(8)O-2(OH)(12)](H2O)(12)
CANADIAN MINERALOGIST
1996; 34: 1071-1088
View details for Web of Science ID A1996VV07000017
-
Geochemical alteration of pyrochlore group minerals: Betafite subgroup
AMERICAN MINERALOGIST
1996; 81 (9-10): 1237-1248
View details for Web of Science ID A1996VN94000022
-
Florencite-(La) with fissiogenic REEs from a natural fission reactor at Bangombe, Gabon
AMERICAN MINERALOGIST
1996; 81 (9-10): 1263-1269
View details for Web of Science ID A1996VN94000024
-
Temperature dependent microstructural modification in ion-irradiated Tl-type high temperature superconductors
PHYSICA C
1996; 267 (3-4): 243-253
View details for Web of Science ID A1996VE49700006
-
U6+ minerals and inorganic phases: A comparison and hierarchy of crystal structures
CANADIAN MINERALOGIST
1996; 34: 845-880
View details for Web of Science ID A1996VH62000014
-
Irradiation-induced amorphization of AlPO4
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS
1996; 116 (1-4): 126-130
View details for Web of Science ID A1996VG59200023
-
Electron-irradiation- and ion-beam-induced amorphization of coesite
PHYSICAL REVIEW B
1996; 54 (6): 3800-3808
View details for Web of Science ID A1996VD67700033
-
Ion beam induced amorphization of monazite
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS
1996; 116 (1-4): 220-224
View details for Web of Science ID A1996VG59200043
-
Phosphatian coffinite with rare earth elements and Ce-rich francoisite-(Nd) from sandstone beneath a natural fission reactor at Bangombe, Gabon
MINERALOGICAL MAGAZINE
1996; 60 (401): 665-669
View details for Web of Science ID A1996VA41900014
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Surface and grain-boundary amorphization: Thermodynamic melting of coesite below the glass transition temperature
PHYSICAL REVIEW B
1996; 53 (5): 2155-2158
View details for Web of Science ID A1996TV39300002
-
Description and classification of uranium oxide hydrate sheet topologies
SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XIX
1996; 412: 369-376
View details for Web of Science ID A1996BF31P00046
-
Schoepite and dehydrated schoepite
SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XIX
1996; 412: 361-368
View details for Web of Science ID A1996BF31P00045
-
Crystalline ceramics: Waste forms for the disposal of weapons plutonium
DISPOSAL OF WEAPON PLUTONIUM
1996; 4: 65-83
View details for Web of Science ID A1996BG96T00007
-
Aeschynite and euxenite structure-types as host phases for rare-earths and actinides from HLW
SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XIX
1996; 412: 377-384
View details for Web of Science ID A1996BF31P00047
-
A comparative study on ion-beam induced effects in spinel structure types
ION BEAM MODIFICATION OF MATERIALS
1996: 1073-1076
View details for Web of Science ID A1996BG29U00213
-
Clays at the natural nuclear reactor at Bangombe, Gabon: Migration of actinides
RADIOCHIMICA ACTA
1996; 74: 271-275
View details for Web of Science ID A1996VP90400046
-
Secondary phase formation and the microstructural evolution of surface layers during vapor phase alteration of the French SON68 nuclear waste glass at 200 degrees C
SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XIX
1996; 412: 197-204
View details for Web of Science ID A1996BF31P00024
-
On the roles of temperature and interfaces in irradiation and thermally induced solid state amorphization
THERMODYNAMICS AND KINETICS OF PHASE TRANSFORMATIONS
1996; 398: 233-238
View details for Web of Science ID A1996BG31K00034
-
STRUCTURAL DAMAGE IN SPINEL AFTER ION IRRADIATION
JOURNAL OF NUCLEAR MATERIALS
1995; 225: 318-323
View details for Web of Science ID A1995RT87300038
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GEOCHEMICAL ALTERATION OF PYROCHLORE GROUP MINERALS - PYROCHLORE SUBGROUP
AMERICAN MINERALOGIST
1995; 80 (7-8): 732-743
View details for Web of Science ID A1995RN60900010
-
RECOIL REFINEMENTS - IMPLICATIONS FOR THE AR-40/AR-39 DATING TECHNIQUE
GEOCHIMICA ET COSMOCHIMICA ACTA
1995; 59 (9): 1821-1834
View details for Web of Science ID A1995RA71500012
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MECHANISMS OF LEAD RELEASE FROM URANINITE IN THE NATURAL FISSION REACTORS IN GABON
GEOCHIMICA ET COSMOCHIMICA ACTA
1995; 59 (10): 1917-1931
View details for Web of Science ID A1995RB22800002
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ION-BEAM-INDUCED DISORDERING AND ONSET OF AMORPHIZATION IN SPINEL BY DEFECT ACCUMULATION
JOURNAL OF MATERIALS RESEARCH
1995; 10 (4): 981-985
View details for Web of Science ID A1995QN59100024
-
ZIRCON - A HOST-PHASE FOR THE DISPOSAL OF WEAPONS PLUTONIUM
JOURNAL OF MATERIALS RESEARCH
1995; 10 (2): 243-246
View details for Web of Science ID A1995QD44400004
-
Application of channeling techniques and high resolution transmission electron microscopy to ion-beam damaged zircon
MICROSTRUCTURE OF IRRADIATED MATERIALS
1995; 373: 371-376
View details for Web of Science ID A1995BD31C00055
-
ILLITE IN THE OKLO NATURAL FISSION REACTORS IN GABON - CONSIDERATIONS FOR CS CONTAINMENT
SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XVIII, PTS 1 AND 2
1995; 353: 1203-1210
View details for Web of Science ID A1995BD21K00147
-
PREDICTION OF UNKNOWN URANYL OXIDE HYDRATE STRUCTURE TYPES - COMPARISON OF CALCULATED AND MEASURED XRD POWDER PATTERNS
SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XVIII, PTS 1 AND 2
1995; 353: 653-660
View details for Web of Science ID A1995BD21K00082
-
TEMPERATURE DEPENDENCE OF AMORPHIZATION FOR ZIRCONOLITE AND PEROVSKITE IRRADIATED WITH 1 MEV KRYPTON IONS
SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XVIII, PTS 1 AND 2
1995; 353: 1413-1420
View details for Web of Science ID A1995BD21K00173
-
Effects of ion dose and irradiation temperature on the microstructure of three spinel compositions
MICROSTRUCTURE OF IRRADIATED MATERIALS
1995; 373: 407-412
View details for Web of Science ID A1995BD31C00061
-
CRICHTONITE STRUCTURE TYPE (AM21O38 AND A2M19O36) AS A HOST PHASE IN CRYSTALLINE WASTE FROM CERAMICS
SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XVIII, PTS 1 AND 2
1995; 353: 807-815
View details for Web of Science ID A1995BD21K00099
-
Ion-beam and electron-beam induced amorphization of berlinite (A1PO(4))
MICROSTRUCTURE OF IRRADIATED MATERIALS
1995; 373: 395-400
View details for Web of Science ID A1995BD31C00059
-
PRECIPITATION OF URANINITE IN CHLORITE-BEARING VEINS OF THE HYDROTHERMAL ALTERATION ZONE (ARGILE-DE-PILE) OF THE NATURAL NUCLEAR REACTOR AT BANGOMBE, REPUBLIC OF GABON
SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XVIII, PTS 1 AND 2
1995; 353: 1195-1202
View details for Web of Science ID A1995BD21K00146
-
Amorphization of complex ceramics by heavy-particle irradiations
MICROSTRUCTURE OF IRRADIATED MATERIALS
1995; 373: 347-358
View details for Web of Science ID A1995BD31C00052
-
MATERIALS SCIENCE OF RADIOACTIVE-WASTE FORMS
MRS BULLETIN
1994; 19 (12): 16-18
View details for Web of Science ID A1994PX40500003
-
RADIATION EFFECTS IN CERAMICS
JOURNAL OF NUCLEAR MATERIALS
1994; 216: 291-321
View details for Web of Science ID A1994PL67500016
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ENERGETICS OF RADIATION-DAMAGE IN NATURAL ZIRCON (ZRSIO4)
PHYSICS AND CHEMISTRY OF MINERALS
1994; 21 (3): 140-149
View details for Web of Science ID A1994NW99200003
-
THE METAMICT STATE - 1993 - THE CENTENNIAL
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS
1994; 91 (1-4): 22-29
View details for Web of Science ID A1994NR93500004
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THE RADIATION-INDUCED CRYSTALLINE-TO-AMORPHOUS TRANSITION IN ZIRCON
JOURNAL OF MATERIALS RESEARCH
1994; 9 (3): 688-698
View details for Web of Science ID A1994MZ03900022
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IN-SITU TEM OBSERVATION OF RADIATION-INDUCED AMORPHIZATION OF CRYSTALS WITH APATITE STRUCTURE
HYDROXYAPATITE AND RELATED MATERIALS
1994: 243-249
View details for Web of Science ID A1994BA62B00023
-
FORMATION OF SECONDARY URANIUM MINERALS IN THE KOONGARRA DEPOSIT, AUSTRALIA
SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XVII
1994; 333: 653-660
View details for Web of Science ID A1994BA13E00074
-
Quantitative analysis of displacement cascade damage in ion irradiated TlBa2CaCu2O7 superconductor by digital HRTEM
ELECTRON MICROSCOPY 1994, VOLS 2A AND 2B
1994: 957-958
View details for Web of Science ID A1994BE09Y00465
-
AMORPHIZATION AND DYNAMIC RECOVERY OF A2BO4 STRUCTURE TYPES DURING 1.5-MEV KRYPTON ION-BEAM IRRADIATION
CRYSTALLIZATION AND RELATED PHENOMENA IN AMORPHOUS MATERIALS
1994; 321: 405-410
View details for Web of Science ID A1994BA13A00059
-
AMORPHIZATION AND DYNAMIC RECOVERY OF A2BO4 STRUCTURE TYPES DURING 1.5 MEV KRYPTON ION-BEAM IRRADIATION
MATERIALS SYNTHESIS AND PROCESSING USING ION BEAMS
1994; 316: 247-252
View details for Web of Science ID A1994BA28H00038
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PETROGRAPHIC ANALYSIS OF SAMPLES FROM THE URANIUM DEPOSIT AT OKLO, REPUBLIC OF GABON
RADIOCHIMICA ACTA
1994; 66-7: 455-461
View details for Web of Science ID A1994QE24500068
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FORMATION, OXIDATION AND ALTERATION OF IANTHINITE
SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XVII
1994; 333: 625-630
View details for Web of Science ID A1994BA13E00070
-
Petrographic analysis of samples from the uranium deposit at Oklo, Republic of Gabon
CHEMISTRY AND MIGRATION BEHAVIOUR OF ACTINIDES AND FISSION PRODUCTS IN THE GEOSPHERE
1994: 565-571
View details for Web of Science ID A1994BF47K00083
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OXIDATION OF URANINITE - DOES TETRAGONAL U3O7 OCCUR IN NATURE
JOURNAL OF NUCLEAR MATERIALS
1993; 207: 177-191
View details for Web of Science ID A1993ML00100017
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THE STRUCTURE OF APERIODIC, METAMICT (CA,TH)ZRTI2O7 (ZIRCONOLITE) - AN EXAFS STUDY OF THE ZR-SITES, TH-SITES AND U-SITES
JOURNAL OF MATERIALS RESEARCH
1993; 8 (8): 1983-1995
View details for Web of Science ID A1993LR03900029
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HRTEM STUDY OF DISPLACEMENT CASCADE DAMAGE IN KRYPTON-ION-IRRADIATED SILICATE OLIVINE
ULTRAMICROSCOPY
1993; 51 (1-4): 339-347
View details for Web of Science ID A1993LN79100031
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METAMICT AND CHEMICALLY ALTERED VESUVIANITE
CANADIAN MINERALOGIST
1993; 31: 357-369
View details for Web of Science ID A1993LR47400009
-
ION IRRADIATION-INDUCED NANO-SCALE POLYCRYSTALLIZATION OF INTERMETALLIC AND CERAMIC MATERIALS
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS
1993; 80-1: 1109-1113
View details for Web of Science ID A1993LK38100079
-
CRYSTAL-CHEMISTRY OF SAMARSKITE
AMERICAN MINERALOGIST
1993; 78 (3-4): 419-424
View details for Web of Science ID A1993KY02300018
-
MINERALOGY
GEOTIMES
1993; 38 (2): 31-32
View details for Web of Science ID A1993KL38800034
-
IMAGE SIMULATION OF PARTIALLY AMORPHOUS MATERIALS
ULTRAMICROSCOPY
1993; 48 (1-2): 203-237
View details for Web of Science ID A1993KM78800018
-
THE AMORPHIZATION OF COMPLEX SILICATES BY ION-BEAM IRRADIATION
JOURNAL OF MATERIALS RESEARCH
1992; 7 (11): 3080-3102
View details for Web of Science ID A1992JX92200022
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THEMATIC ISSUE ON NUCLEAR WASTE - PREFACE
JOURNAL OF NUCLEAR MATERIALS
1992; 190: R7-R10
View details for Web of Science ID A1992JQ09200001
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DISSOLUTION AND ALTERATION OF URANINITE UNDER REDUCING CONDITIONS
JOURNAL OF NUCLEAR MATERIALS
1992; 190: 157-173
View details for Web of Science ID A1992JQ09200015
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THE CORROSION OF URANINITE UNDER OXIDIZING CONDITIONS
JOURNAL OF NUCLEAR MATERIALS
1992; 190: 133-156
View details for Web of Science ID A1992JQ09200014
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ALTERATION OF URANIUM MINERALS IN THE KOONGARRA DEPOSIT, AUSTRALIA - UNWEATHERED ZONE
JOURNAL OF NUCLEAR MATERIALS
1992; 190: 174-187
View details for Web of Science ID A1992JQ09200016
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STRUCTURAL FORMULA OF URANINITE
JOURNAL OF NUCLEAR MATERIALS
1992; 190: 128-132
View details for Web of Science ID A1992JQ09200013
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EARTH MATERIALS
MRS BULLETIN
1992; 17 (5): 19-20
View details for Web of Science ID A1992HU96800001
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ION-BEAM-INDUCED AMORPHIZATION OF COMPLEX CERAMIC MATERIALS MINERALS
MRS BULLETIN
1992; 17 (5): 38-44
View details for Web of Science ID A1992HU96800004
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DETAILED INSITU STUDY OF ION BEAM-INDUCED AMORPHIZATION OF ZIRCON
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS
1992; 65 (1-4): 324-329
View details for Web of Science ID A1992HN33200056
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AMORPHIZATION OF ZIRCONOLITE - ALPHA-DECAY EVENT DAMAGE VERSUS KRYPTON ION IRRADIATION
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS
1992; 65 (1-4): 319-323
View details for Web of Science ID A1992HN33200055
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GEOCHEMICAL ALTERATION OF PYROCHLORE GROUP MINERALS - MICROLITE SUBGROUP
AMERICAN MINERALOGIST
1992; 77 (1-2): 179-188
View details for Web of Science ID A1992HE61600020
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COMPARISON OF INSITU AND LABORATORY CORROSION EXPERIMENTS WITH BOROSILICATE NUCLEAR WASTE GLASS
SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XV
1992; 257: 127-134
View details for Web of Science ID A1992BW94K00015
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COFFINITIZATION - A MECHANISM FOR THE ALTERATION OF UO2 UNDER REDUCING CONDITIONS
SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XV
1992; 257: 497-504
View details for Web of Science ID A1992BW94K00060
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WEATHERING OF NATURAL URANYL OXIDE HYDRATES - SCHOEPITE POLYTYPES AND DEHYDRATION EFFECTS
RADIOCHIMICA ACTA
1992; 58-9: 433-443
View details for Web of Science ID A1992KD61300035
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STORED ENERGY IN NATURAL ZIRCONOLITE AND ITS SYNTHETIC COUNTERPART AFTER ALPHA-RECOIL SELF-IRRADIATION DAMAGE
JOURNAL OF NUCLEAR MATERIALS
1991; 185 (2): 202-207
View details for Web of Science ID A1991GN28400008
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X-RAY-POWDER DIFFRACTION STUDY OF ANNEALED URANINITE
JOURNAL OF NUCLEAR MATERIALS
1991; 185 (1): 66-77
View details for Web of Science ID A1991GH10000008
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ALPHA-DECAY EVENT DAMAGE IN ZIRCON
AMERICAN MINERALOGIST
1991; 76 (9-10): 1510-1532
View details for Web of Science ID A1991GL39700008
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INSITU TEM STUDY OF ION-BEAM-INDUCED AMORPHIZATION OF COMPLEX SILICATE STRUCTURES
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS
1991; 59: 395-400
View details for Web of Science ID A1991FZ02900085
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ACCUMULATION OF STRUCTURAL DEFECTS IN ION-IRRADIATED CA2ND8(SIO4)6O2
JOURNAL OF MATERIALS RESEARCH
1991; 6 (6): 1334-1345
View details for Web of Science ID A1991FQ05200024
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ALPHA-DECAY DAMAGE IN TITANITE
AMERICAN MINERALOGIST
1991; 76 (3-4): 370-396
View details for Web of Science ID A1991FN24100006
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ALPHA-RECOIL DAMAGE IN TITANITE (CATISIO5) - DIRECT OBSERVATION AND ANNEALING STUDY USING HIGH-RESOLUTION TRANSMISSION ELECTRON-MICROSCOPY
JOURNAL OF MATERIALS RESEARCH
1991; 6 (3): 560-564
View details for Web of Science ID A1991FA76900017
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INTERNATIONAL UNION OF MATERIALS RESEARCH SOCIETIES ESTABLISHED
MRS BULLETIN
1991; 16 (2): 33-33
View details for Web of Science ID A1991EZ84100012
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HARDNESS AND ELASTIC-MODULUS OF ZIRCON AS A FUNCTION OF HEAVY-PARTICLE IRRADIATION DOSE .1. INSITU ALPHA-DECAY EVENT DAMAGE
RADIATION EFFECTS AND DEFECTS IN SOLIDS
1991; 118 (4): 393-403
View details for Web of Science ID A1991HG96500008
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HIGH-TEMPERATURE ANNEALING OF NATURAL UO2+X
SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XIV
1991; 212: 235-240
View details for Web of Science ID A1991BT69T00026
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HIGH-LEVEL NUCLEAR WASTE IMMOBILIZATION WITH CERAMICS
CERAMICS INTERNATIONAL
1991; 17 (5): 287-293
View details for Web of Science ID A1991GH93200004
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ALTERATION OF NATURAL UO2 UNDER OXIDIZING CONDITIONS FROM SHINKOLOBWE, KATANGA, ZAIRE - A NATURAL ANALOG FOR THE CORROSION OF SPENT FUEL
RADIOCHIMICA ACTA
1991; 52-3: 395-401
View details for Web of Science ID A1991FC39800015
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PB-IMPLANTED SRTIO3 ANALYZED USING RUTHERFORD BACKSCATTERING AND SURFACE SENSITIVE EXAFS XANES SPECTROSCOPY
JOURNAL OF NON-CRYSTALLINE SOLIDS
1990; 122 (2): 121-132
View details for Web of Science ID A1990DU68700002
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CHEMICAL CORROSION OF HIGHLY RADIOACTIVE BOROSILICATE NUCLEAR WASTE GLASS UNDER SIMULATED REPOSITORY CONDITIONS
JOURNAL OF MATERIALS RESEARCH
1990; 5 (5): 1130-1146
View details for Web of Science ID A1990DD72600030
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ANNEALING OF ALPHA-RECOIL DAMAGE IN NATURAL TITANITE, CATISIO5
HIGH RESOLUTION ELECTRON MICROSCOPY OF DEFECTS IN MATERIALS
1990; 183: 297-300
View details for Web of Science ID A1990BT12Y00037
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COMPARISON OF SURFACE-LAYERS FORMED ON SYNTHETIC BASALTIC GLASS, FRENCH R7T7 AND HMI BOROSILICATE NUCLEAR WASTE FORM GLASSES - MATERIALS INTERFACE INTERACTIONS TESTS, WASTE ISOLATION PILOT-PLANT
SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XIII
1990; 176: 355-362
View details for Web of Science ID A1990BR23T00039
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APPLICATION OF VARIOUS XAFS TECHNIQUES TO THE INVESTIGATION OF STRUCTURALLY DAMAGED MATERIALS
PHYSICA B-CONDENSED MATTER
1989; 158 (1-3): 498-500
View details for Web of Science ID A1989AE26500185
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METAMICT MINERALS - NATURAL ANALOGS FOR RADIATION-DAMAGE EFFECTS IN CERAMIC NUCLEAR WASTE FORMS
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS
1988; 32 (1-4): 487-497
View details for Web of Science ID A1988N937400090
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PREFERENTIAL LEACHING AND NATURAL ANNEALING OF ALPHA-RECOIL TRACKS IN METAMICT BETAFITE AND SAMARSKITE
JOURNAL OF MATERIALS RESEARCH
1988; 3 (2): 357-368
View details for Web of Science ID A1988P411400021
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ALPHA-DECAY DAMAGE IN MINERALS OF THE PYROCHLORE GROUP
PHYSICS AND CHEMISTRY OF MINERALS
1988; 16 (1): 2-20
View details for Web of Science ID A1988Q471800001
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ALPHA-DECAY INDUCED FRACTURING IN ZIRCON - THE TRANSITION FROM THE CRYSTALLINE TO THE METAMICT STATE
SCIENCE
1987; 236 (4808): 1556-1559
Abstract
A natural single crystal of zircon, ZrSiO(4,) from Sri Lanka exhibited zonation due to alpha-decay damage. The zones vary in thickness on a scale from one to hundreds of micrometers. The uranium and thorium concentrations vary from zone to zone such that the alpha-decay dose is between 0.2 x 10(16) and 0.8 x 10(16) alpha-events per milligram (0.15 to 0.60 displacement per atom). The transition from the crystalline to the aperiodic metamict state occurs over this dose range. Differential expansion of individual layers due to variations in their alpha-decay dose caused a systematic pattern of fractures that do not propagate across aperiodic layers. High-resolution transmission electron microscopy revealed a systematic change in the microstructure from a periodic atomic array to an aperiodic array with increasing alpha-decay dose. At doses greater than 0.8 x 10(16) alpha-events per milligram there is no evidence for long-range order. This type of damage will accumulate in actinide-bearing, ceramic nuclear waste forms. The systematic pattern of fractures would occur in crystalline phases that are zoned with respect to actinide radionuclides.
View details for Web of Science ID A1987H781800025
View details for PubMedID 17835739
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Alpha-recoil damage in zirconolite (CaZrTi2O7)
JOURNAL OF MATERIALS RESEARCH
1986; 1 (4): 564-576
View details for DOI 10.1557/JMR.1986.0564
View details for Web of Science ID 000208995100008
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THERMAL RECRYSTALLIZATION OF ALPHA-RECOIL DAMAGED MINERALS OF THE PYROCHLORE STRUCTURE TYPE
JOURNAL OF NUCLEAR MATERIALS
1986; 139 (2): 113-120
View details for Web of Science ID A1986D195800006
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JAHNS,R.H. MEMORIAL ISSUE - THE MINERALOGY, PETROLOGY, AND GEOCHEMISTRY OF GRANITIC PEGMATITES AND RELATED GRANITIC-ROCKS - INTRODUCTION
AMERICAN MINERALOGIST
1986; 71 (3-4): 233-238
View details for Web of Science ID A1986C098000001
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MEMORIAL OF JAHNS,RICHARD,HENRY MARCH 10, 1915 DECEMBER 31, 1983
AMERICAN MINERALOGIST
1986; 71 (3-4): 652-654
View details for Web of Science ID A1986C098000032
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MINERALOGY AND RADIATION EFFECTS OF MICROLITE FROM THE HARDING PEGMATITE, TAOS COUNTY, NEW-MEXICO
AMERICAN MINERALOGIST
1986; 71 (3-4): 569-588
View details for Web of Science ID A1986C098000024
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ALTERATION OF BASALT GLASSES - IMPLICATIONS FOR MODELING THE LONG-TERM STABILITY OF NUCLEAR WASTE GLASSES
NATURE
1985; 314 (6008): 252-255
View details for Web of Science ID A1985ADT9900040
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TI-SITE GEOMETRY IN METAMICT, ANNEALED AND SYNTHETIC COMPLEX TI-NB-TA OXIDES BY X-RAY ABSORPTION-SPECTROSCOPY
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS
1984; 1 (2-3): 587-594
View details for Web of Science ID A1984SP31100067
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ALTERATION EFFECTS AND LEACH RATES OF BASALTIC GLASSES - IMPLICATIONS FOR THE LONG-TERM STABILITY OF NUCLEAR WASTE FORM BOROSILICATE GLASSES
JOURNAL OF NON-CRYSTALLINE SOLIDS
1984; 67 (1-3): 305-321
View details for Web of Science ID A1984TN77500021
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ALPHA-RECOIL DAMAGE IN NATURAL ZIRCONOLITE (CAZRTI2O7)
JOURNAL OF NUCLEAR MATERIALS
1983; 119 (1): 102-109
View details for Web of Science ID A1983RZ59300012
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THE HARDING PEGMATITE - A SUMMARY OF RECENT RESEARCH
AMERICAN MINERALOGIST
1982; 67 (1-2): 182-183
View details for Web of Science ID A1982NY23800031
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RADIATION-DAMAGE IN NATURAL MATERIALS - ITS IMPLICATIONS FOR RADIOACTIVE-WASTE FORMS
BULLETIN OF THE AMERICAN PHYSICAL SOCIETY
1981; 26 (3): 401-401
View details for Web of Science ID A1981LE30501295
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SOLUTION-GELATION METHOD FOR PREPARING POLYCRYSTALLINE ZIRCON
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
1981; 64 (11): C149-C149
View details for Web of Science ID A1981MR91600015
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AMORPHOUS STRUCTURE OF METAMICT MINERALS OBSERVED BY TEM
NATURE
1981; 293 (5832): 449-450
View details for Web of Science ID A1981MJ81500036
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DIFFERENTIAL THERMAL-ANALYSIS OF SOME IRRADIATED MATERIALS - DISCUSSION
AMERICAN MINERALOGIST
1979; 64 (9-10): 1131-1132
View details for Web of Science ID A1979HT49800026
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METAMICT STATE - RADIATION-DAMAGE IN CRYSTALLINE MATERIALS
AMERICAN CERAMIC SOCIETY BULLETIN
1979; 58 (3): 326-326
View details for Web of Science ID A1979GR68200125
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CONTRIBUTIONS TO THE MINERAL CHEMISTRY OF HAWAIIAN ROCKS .7. BARIAN-TITANIAN BIOTITES IN NEPHELINITES FROM OAHU, HAWAII
AMERICAN MINERALOGIST
1979; 64 (1-2): 156-159
View details for Web of Science ID A1979GN08500019
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CRYSTAL-STRUCTURES OF THSIO4 POLYMORPHS - HUTTONITE AND THORITE
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE
1978; 34 (APR): 1074-1079
View details for Web of Science ID A1978EZ47300005
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ROWLANDITE FROM BARRINGER HILL RARE-EARTH PEGMATITE DISTRICT, LLANO AND BURNET COUNTIES, TEXAS
AMERICAN MINERALOGIST
1978; 63 (7-8): 754-756
View details for Web of Science ID A1978FN50000016
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EUXENITE FROM AMPANGABE, MADAGASCAR
CANADIAN MINERALOGIST
1977; 15: 92-96
View details for Web of Science ID 000208513000014
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DARAPSKITE, NA3(NO3)(SO4)H2O, A NEW OCCURRENCE, IN TEXAS
MINERALOGICAL MAGAZINE
1977; 41 (320): 548-550
View details for Web of Science ID A1977ED23800021
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METAMICT COLUMBITE REEXAMINED
MINERALOGICAL MAGAZINE
1976; 40 (316): 898-899
View details for Web of Science ID A1976CN73000014
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METAMICT MINERAL ALTERATION - IMPLICATION FOR RADIOACTIVE-WASTE DISPOSAL
SCIENCE
1976; 192 (4246): 1336-1337
Abstract
Pervasive alteration is a common feature of metamict minerals. Previous studies of metamict niobium-tantalum-titanium oxides and electron microprobe analyses of altered areas in metamict yttrialite document the leaching of uranium, thorium, and rare earth elements. These data suggest that glasses may not provide a stable medium for radioactive waste disposal.
View details for Web of Science ID A1976BU52900019
View details for PubMedID 17739840
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CRYSTAL-STRUCTURES OF THSIO4 POLYMORPHS, THORITE AND HUTTONITE
TRANSACTIONS-AMERICAN GEOPHYSICAL UNION
1975; 56 (12): 1076-1076
View details for Web of Science ID A1975AW55100828
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CRYSTAL-CHEMISTRY OF COMPLEX NIOBIUM AND TANTALUM OXIDES .4. METAMICT STATE - DISCUSSION
AMERICAN MINERALOGIST
1975; 60 (7-8): 728-733
View details for Web of Science ID A1975AN45200027